X-Ray Fluorescence Spectroscopy Combined With SEM-EDS Analysis to Glaze Composition of Glazed Tiles in Yuan Dynasty

Ruo-yu SHI; Rui WEN; Xiang GAO; Wen-xuan WANG; Li-ge BAO; Xue-feng ZHAO; Zi-xuan LI; Kun CAO; Wei XIAO; Yu-long LI

doi:10.3964/j.issn.1000-0593(2021)12-3808-07

Journals >Spectroscopy and Spectral Analysis >Volume 41 >Issue 12 >Page 3808 > Article

Spectroscopy and Spectral Analysis
Vol. 41, Issue 12, 3808 (2021)

X-Ray Fluorescence Spectroscopy Combined With SEM-EDS Analysis to Glaze Composition of Glazed Tiles in Yuan Dynasty

Ruo-yu SHI^1、*, Rui WEN^{1、1; *;}, Xiang GAO^2、2;, Wen-xuan WANG^1、1;, Li-ge BAO^3、3;, Xue-feng ZHAO^4、4;, Zi-xuan LI^1、1;, Kun CAO^1、1;, Wei XIAO^1、1;, and Yu-long LI^1、1;

Author Affiliations

¹1. Key Laboratory of Cultural Heritage Research and Conservation (Northwest University), School of Cultural Heritage (Northwest University), Xi’an 710127, China

²2. School of Chemistry and Materials Science, Northwest University, Xi’an 710075, China

³3. Yuan Shangdu Cultural Heritage Administration, Xilingol League 027200, China

⁴4. Management Office of Yuan Zhongdu Heritage Protection Zone, Zhangjiakou 076450, China

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DOI: 10.3964/j.issn.1000-0593(2021)12-3808-07 Cite this Article

Ruo-yu SHI, Rui WEN, Xiang GAO, Wen-xuan WANG, Li-ge BAO, Xue-feng ZHAO, Zi-xuan LI, Kun CAO, Wei XIAO, Yu-long LI. X-Ray Fluorescence Spectroscopy Combined With SEM-EDS Analysis to Glaze Composition of Glazed Tiles in Yuan Dynasty[J]. Spectroscopy and Spectral Analysis, 2021, 41(12): 3808 Copy Citation Text

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Fig. 1. Sample YSDG-005 at site of Yuan Shangdu

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Fig. 2. Sample YZDY-011 at site of Yuan Zhongdu

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Fig. 3. Sample YSDB-003 at site of Yuan Shangdu

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Fig. 4. Sample YSDG-002 at site of Yuan Shangdu

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Fig. 5. Composition of PbO-SiO₂-K₂O in turquoise glazes during Jin to Ming Dynasty

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Fig. 6. Rate of Pb/Si in green glaze during Tang, Period Song and Yuan

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Fig. 7. Rate of Pb/Si in yellow glaze during Yuan, Ming and Qing Dynasty

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Fig. 8. Micro structures of the glazes in Yuan Dynasty

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样品编号	釉色	Na₂O	MgO	Al₂O₃	SiO₂	K₂O	CaO	TiO₂	MnO	Fe₂O₃	CuO	PbO
YSDB-001	蓝	2.18	0.49	4.66	40.89	5.95	8.05	0.09	0.02	1.12	4.31	32.71
YSDB-002	蓝	2.55	0.45	8.24	38.95	7.35	8.28	0.39	0.03	2.17	2.77	29.24
YSDB-003	蓝	1.94	0.44	4.83	42.06	5.94	6.03	0.12	0.01	0.98	4.29	33.79
YSDG-001	绿	0.00	0.39	4.74	31.35	0.39	1.09	0.09	0.03	1.05	2.80	57.58
YSDG-002	绿	0.00	0.34	5.36	34.60	0.93	2.13	0.17	0.01	1.01	2.51	52.50
YSDG-003	绿	0.63	0.35	5.00	41.57	0.67	1.27	0.09	0.04	0.88	2.36	46.70
YSDG-004	绿	0.74	0.41	4.06	31.56	0.68	1.30	0.07	0.02	0.94	2.83	57.33
YSDG-005	绿	0.00	0.40	3.86	32.65	0.10	1.28	0.08	0.00	0.82	2.95	57.80
YSDG-006	绿	0.86	0.40	4.51	33.37	0.85	1.16	0.04	0.01	0.95	2.90	54.86
YSDG-007	绿	0.00	0.39	4.64	30.38	0.63	2.09	0.13	0.00	0.97	0.74	60.02
YSDG-008	绿	0.00	0.40	4.35	30.97	0.28	2.26	0.10	0.02	0.89	0.91	59.80
YSDG-009	绿	0.75	0.42	4.71	28.14	0.34	2.29	0.19	0.02	0.95	0.86	61.30
YZDG-001	绿	0.02	0.07	0.52	33.41	0.03	0.32	0.04	0.01	0.72	1.74	59.19
YZDG-002	绿	0.02	0.52	1.02	33.98	0.05	0.52	0.04	0.02	0.31	1.53	57.89
YZDG-003	绿	0.99	1.11	1.02	34.18	0.03	0.34	0.08	0.03	0.32	1.00	55.94
YZDG-004	绿	0.02	1.99	2.54	36.48	0.04	1.42	0.13	0.01	0.55	1.51	52.07
YZDG-005	绿	2.94	1.10	5.01	35.86	0.04	1.13	0.11	0.02	0.42	1.24	50.07
YZDG-006	绿	2.23	2.07	4.54	40.44	0.02	1.39	0.25	0.02	0.96	1.36	44.70
YZDG-007	绿	0.02	1.87	2.16	37.41	0.07	0.77	0.06	0.02	0.28	1.38	51.46
YZDG-008	绿	1.12	2.06	3.71	41.39	0.02	0.72	0.07	0.02	0.47	1.15	46.37
YZDG-009	绿	0.02	1.67	2.63	38.16	0.04	0.95	0.14	0.02	0.68	1.40	51.78
YZDG-010	绿	0.19	1.28	4.56	34.08	0.07	1.68	0.18	0.01	0.71	1.30	53.75
YZDG-011	绿	1.03	3.35	3.01	33.17	0.03	1.92	0.12	0.00	0.62	1.20	51.89
YZDG-012	绿	0.37	5.64	2.48	30.73	0.02	1.31	0.13	0.01	0.64	1.50	54.44
YZDG-013	绿	2.05	0.02	2.31	35.14	0.00	1.68	0.14	0.02	0.52	1.60	54.42
YZDY-001	黄	1.50	0.82	0.99	36.92	0.10	0.41	0.08	0.00	3.39	0.18	52.43
YZDY-002	黄	3.31	1.87	2.30	34.79	0.07	0.27	0.10	0.01	2.62	0≸04	50.91
YZDY-003	黄	4.44	2.35	1.38	33.32	0.04	0.25	0.07	0.01	3.00	0.06	51.18
YZDY-004	黄	0.28	2.63	3.00	37.24	0.10	1.02	0.08	0.00	2.98	0.08	50.28
YZDY-005	黄	0.02	2.16	2.84	37.29	0.13	1.54	0.13	0.02	3.15	0.09	49.49
YZDY-006	黄	0.46	2.33	1.63	36.16	0.04	0.70	0.07	0.01	2.96	0.10	53.02

Table 1. Major and minor chemical composition of glazes in Yuan Dynasty/Wt%

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编号	Na₂O	MgO	Al₂O₃	SiO₂	K₂O	CaO	Fe₂O₃	CuO	PbO
YSDB-002	3.3	3.67	10.78	25.86	7.19	22.28	0.74	2.82	1.04
YSDG-005	1.54	1.32	3.82	5.34	2.16	85.02	1.14	0.38	0.30
YZDG-003	0.78	1.17	2.80	5.80	2.25	85.93	0.29	0.13	0.86
YZDY-006	1.54	2.08	3.21	5.46	2.72	82.38	1.60	0.19	0.82

Table 2. EDS results of the slips of samples in Yuan Dynasty/Wt%

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