• Spectroscopy and Spectral Analysis
  • Vol. 40, Issue 12, 3795 (2020)
Xiao-xu YAN1,1,*, Pei-lian WANG1,1, and Su-wei YUE1,1
Author Affiliations
  • 1[in Chinese]
  • 11. School of Jewelry, Guangzhou College South China University of Technology, Guangzhou 510800, China
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    DOI: 10.3964/j.issn.1000-0593(2020)12-3795-06 Cite this Article
    Xiao-xu YAN, Pei-lian WANG, Su-wei YUE. Spectroscopic Characteristics and Coloring Mechanism of Greenish-Yellow Beryl Under Heating Treatment[J]. Spectroscopy and Spectral Analysis, 2020, 40(12): 3795 Copy Citation Text show less
    Character of yellowish green beryl samples after heating-treatment at reducing condition
    Fig. 1. Character of yellowish green beryl samples after heating-treatment at reducing condition
    Character of greenish yellow beryl samples after heating-treatment of oxidizing condition
    Fig. 2. Character of greenish yellow beryl samples after heating-treatment of oxidizing condition
    Comparison of IR spectra between natural and heated Beryl samples(a): Natural sample b1; (b): Heated sample b5 (light-blue); (c): Heated sample b10 (light-blue)
    Fig. 3. Comparison of IR spectra between natural and heated Beryl samples
    (a): Natural sample b1; (b): Heated sample b5 (light-blue); (c): Heated sample b10 (light-blue)
    Comparison of UV-Vis spectra between natural and heated beryl samples(a): b4; (b): b5; (c): b6; (d): b8; (e): b9; (f): 10
    Fig. 4. Comparison of UV-Vis spectra between natural and heated beryl samples
    (a): b4; (b): b5; (c): b6; (d): b8; (e): b9; (f): 10
    Comparison of EPR spectra between natural and heated beryl samples(a): The original spectrum of EPR; (b): The partial enlarged spectrum between 2 500~4 000 H (Gauss)
    Fig. 5. Comparison of EPR spectra between natural and heated beryl samples
    (a): The original spectrum of EPR; (b): The partial enlarged spectrum between 2 500~4 000 H (Gauss)
    波数归属标准绿柱石
    特征[10]
    b1(天然)b5(还原)b10(氧化)
    1 219(s)1 218(s)1 218(s)νas(Si—O—Si)1 195, 1 015,
    950, 800,
    740, 680,
    650
    1 080(m)1 068(w)1 071(w)ν(Si—O)
    1 021(w)1 019(w)1 019(w)νs(O—Si—O)
    975(s)970(s)967(s)νas(O—Si—O)
    820(m-s)820(m)818(m)
    760(m)753(s)751(s)νs(Si—O—Si)
    691(s)694(m)695(m)
    654(w)654(sh)652(sh)γ(O—Be—O)
    598(m)600(m)600(m)
    535(s)536(m)536(m)δ(Si—O)振动与δ(M—O)
    496(w)495(w)494(w)振动及二者耦合振动
    463(m)462(m)460(m)
    Table 1. Representation and arrangement of IR spectra of beryl samples
    Xiao-xu YAN, Pei-lian WANG, Su-wei YUE. Spectroscopic Characteristics and Coloring Mechanism of Greenish-Yellow Beryl Under Heating Treatment[J]. Spectroscopy and Spectral Analysis, 2020, 40(12): 3795
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