• Opto-Electronic Engineering
  • Vol. 49, Issue 1, 210326-1 (2022)
Qing Yang1、2, Yang Cheng1、2, Zheng Fang1、2, Jialiang Zhang2、3, Xun Hou2、3, and Feng Chen2、3、*
Author Affiliations
  • 1School of Mechanical Engineering, Xi’an Jiaotong University, Xi’an, Shaanxi 710049, China
  • 2State Key Laboratory for Manufacturing System Engineering, Xi’an Jiaotong University, Xi’an, Shaanxi 710049, China
  • 3Shaanxi Key Laboratory of Photonics Technology for Information, School of Electronics & Information Engineering, Xi’an Jiaotong University, Xi’an, Shaanxi 710049, China
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    DOI: 10.12086/oee.2022.210326 Cite this Article
    Qing Yang, Yang Cheng, Zheng Fang, Jialiang Zhang, Xun Hou, Feng Chen. The preparation and applications of bio-inspired slippery surface by femtosecond laser micro-nano manufacturing[J]. Opto-Electronic Engineering, 2022, 49(1): 210326-1 Copy Citation Text show less
    The surface structure and slippery property of Nepenthes. (a) The optical photos of Nepenthes [2]; (b) The scanning electron microscopy images of the Nepenthes [2]; (c) The preparation process of slippery surface inspired by Nepenthes [2]; (d) The mobility of hexane on slippery surface [1]
    Fig. 1. The surface structure and slippery property of Nepenthes. (a) The optical photos of Nepenthes [2]; (b) The scanning electron microscopy images of the Nepenthes [2]; (c) The preparation process of slippery surface inspired by Nepenthes [2]; (d) The mobility of hexane on slippery surface [1]
    The micro-nano manufacturing of femtosecond laser on all kinds of materials. (a) The micro-nano rough structure on glass fabricated by femtosecond laser to realize underwater superpolymphobicity [36]; (b) The color aluminum due to femtosecond laser-induced nano-periodic structure [37]
    Fig. 2. The micro-nano manufacturing of femtosecond laser on all kinds of materials. (a) The micro-nano rough structure on glass fabricated by femtosecond laser to realize underwater superpolymphobicity [36]; (b) The color aluminum due to femtosecond laser-induced nano-periodic structure [37]
    The high precision machining of femtosecond laser. (a) The comparison of holes fabricated by nanosecond laser and femtosecond laser [40] ; (b) The “micro-bull” created by femtosecond laser two-photon absorption [41]; (c) The femtosecond laser directly writes the 10 nm characteristic size on the silicon wafer surface [42]
    Fig. 3. The high precision machining of femtosecond laser. (a) The comparison of holes fabricated by nanosecond laser and femtosecond laser [40] ; (b) The “micro-bull” created by femtosecond laser two-photon absorption [41]; (c) The femtosecond laser directly writes the 10 nm characteristic size on the silicon wafer surface [42]
    The high controllability of femtosecond laser on micro-nano manufacturing field. (a) The bio-inspired compound eyes [38] , (b) the coil [48] , and (c) the nanograting structure fabricated by femtosecond laser [49]
    Fig. 4. The high controllability of femtosecond laser on micro-nano manufacturing field. (a) The bio-inspired compound eyes [38] , (b) the coil [48] , and (c) the nanograting structure fabricated by femtosecond laser [49]
    The femtosecond laser fabricates the slippery surface on PA6 and the stability testing[50]. (a) The fabrication process, surface structure, and the lyophobicity testing of slippery surface on PA6; (b) The stability measurement of slippery surface on PA6
    Fig. 5. The femtosecond laser fabricates the slippery surface on PA6 and the stability testing[50]. (a) The fabrication process, surface structure, and the lyophobicity testing of slippery surface on PA6; (b) The stability measurement of slippery surface on PA6
    The patterned slippery surface and anisotropic slippery surface. (a) The fabrication process of patterned slippery surface, the scanning electron microscopy images of surface ablated by laser, and the array arrangement of droplets on patterned slippery surface[52] ; (b) The fabrication process of patterned slippery surface and the directional movement of bubble on patterned slippery surface[53]
    Fig. 6. The patterned slippery surface and anisotropic slippery surface. (a) The fabrication process of patterned slippery surface, the scanning electron microscopy images of surface ablated by laser, and the array arrangement of droplets on patterned slippery surface[52] ; (b) The fabrication process of patterned slippery surface and the directional movement of bubble on patterned slippery surface[53]
    The fabrication of transparent slippery surface on glass via femtosecond laser patterning and wet etching[54]. (a), (b) The scanning electron microscopy images of glass after lase ablation and wet etching; (c) Transmittance of wet etched glasses with microvoid separation distances of 10 µm and 40 µm after wet etching; (d) Transmittance of lubricant oil infused glasses with microvoid separation distances of 10 µm and 40 µm; (e) Transmittance curves for etched samples with different microvoid separation distances in the visible light range (400 nm~800 nm); (f) Transmittance curves for silicone oil infused samples with different microvoid separation distances in the visible light range (400 nm~800 nm); (g) The slippery property of DI water on slippery surface
    Fig. 7. The fabrication of transparent slippery surface on glass via femtosecond laser patterning and wet etching[54]. (a), (b) The scanning electron microscopy images of glass after lase ablation and wet etching; (c) Transmittance of wet etched glasses with microvoid separation distances of 10 µm and 40 µm after wet etching; (d) Transmittance of lubricant oil infused glasses with microvoid separation distances of 10 µm and 40 µm; (e) Transmittance curves for etched samples with different microvoid separation distances in the visible light range (400 nm~800 nm); (f) Transmittance curves for silicone oil infused samples with different microvoid separation distances in the visible light range (400 nm~800 nm); (g) The slippery property of DI water on slippery surface
    The slippery surface fabricated by femtosecond laser on metal. (a) Different surfaces prepared by femtosecond laser on different materials and the lyophobicity of different liquids. (Plain: untreated surface; LIPSS: laser induced periodic surface structures; MS: multi-scale structure; LIPSS-LIS: laser induced periodic surface after lubricant oil infusing; MS-LIS: multi-scale structure surface after lubricant oil infusing) [59] ; (b) The illustration of vibration-induced loss of lubricant infused into LIPSS and MS topographies [59] ; (c) The preparation of micro-nano porous structure on stainless steel by femtosecond laser in alcohol environment and its lyophobicity [60]
    Fig. 8. The slippery surface fabricated by femtosecond laser on metal. (a) Different surfaces prepared by femtosecond laser on different materials and the lyophobicity of different liquids. (Plain: untreated surface; LIPSS: laser induced periodic surface structures; MS: multi-scale structure; LIPSS-LIS: laser induced periodic surface after lubricant oil infusing; MS-LIS: multi-scale structure surface after lubricant oil infusing) [59] ; (b) The illustration of vibration-induced loss of lubricant infused into LIPSS and MS topographies [59] ; (c) The preparation of micro-nano porous structure on stainless steel by femtosecond laser in alcohol environment and its lyophobicity [60]
    The fabrication of slippery surface on NiTi alloy by femtosecond laser[58]. (a) Microfabrication system based on the femtosecond Bessel laser beam. (b) Simulation result of the NiTi alloy surface treated with a single pulse train of the femtosecond Bessel laser and (c), (d) surface morphology of the NiTi alloy after being processed by the femtosecond Bessel laser; (e) The fabrication process of SLIPS; (f) The slipper property of water on NiTi SLIPS
    Fig. 9. The fabrication of slippery surface on NiTi alloy by femtosecond laser[58]. (a) Microfabrication system based on the femtosecond Bessel laser beam. (b) Simulation result of the NiTi alloy surface treated with a single pulse train of the femtosecond Bessel laser and (c), (d) surface morphology of the NiTi alloy after being processed by the femtosecond Bessel laser; (e) The fabrication process of SLIPS; (f) The slipper property of water on NiTi SLIPS
    Applications of slippery surface in droplet manipulation. (a) Femtosecond laser fabricated anisotropic structure on epoxy resin surface for droplet manipulation by magnetic field [12] ; (b) Droplet control platform with self-actuation and electrobraking inspired by cactus and nepenthes [71]
    Fig. 10. Applications of slippery surface in droplet manipulation. (a) Femtosecond laser fabricated anisotropic structure on epoxy resin surface for droplet manipulation by magnetic field [12] ; (b) Droplet control platform with self-actuation and electrobraking inspired by cactus and nepenthes [71]
    Voltage reversibly control liquids on slippery surface between sliding and pining[72]. (a) Strategy for preparing slippery surface controlled by voltage; (b) Surface morphologies for micropillar-arrayed zinc oxide before and after infusing the paraffin; (c) The scanning electron microscopy images of silver nanowire heater and digital picture of transparent heater; (d) Different motion states of droplet under voltage on and off
    Fig. 11. Voltage reversibly control liquids on slippery surface between sliding and pining[72]. (a) Strategy for preparing slippery surface controlled by voltage; (b) Surface morphologies for micropillar-arrayed zinc oxide before and after infusing the paraffin; (c) The scanning electron microscopy images of silver nanowire heater and digital picture of transparent heater; (d) Different motion states of droplet under voltage on and off
    Femtosecond laser construct different structures on titanium and the adhesion of biofilm on slippery surface[85]. Differently structured titanium samples constructed by femtosecond laser: (a) laser-generated spikes, (b) grooves, (c) ripples, and (d) unstructured titanium; (e) Biofilm formation screening on titanium slippery surface made of different structure and lubricant combinations
    Fig. 12. Femtosecond laser construct different structures on titanium and the adhesion of biofilm on slippery surface[85]. Differently structured titanium samples constructed by femtosecond laser: (a) laser-generated spikes, (b) grooves, (c) ripples, and (d) unstructured titanium; (e) Biofilm formation screening on titanium slippery surface made of different structure and lubricant combinations
    Lubricant infused directly engraved nano microstructures for mechanically durable endoscope lens with anti-biofouling and anti-fogging properties[86]. (a) The fabrication process of the anti-biofouling and anti-fogging endoscope lens; (b) The surface morphologies of glass after femtosecond laser ablation; (c) The transmittances of surface with different structure; (d) The confocal microscopy images of protein (albumin and fibrinogen) adsorptions on bare and slippery surface; (e) The sequential images of blood spray attachment to untreated glass and the slippery surface
    Fig. 13. Lubricant infused directly engraved nano microstructures for mechanically durable endoscope lens with anti-biofouling and anti-fogging properties[86]. (a) The fabrication process of the anti-biofouling and anti-fogging endoscope lens; (b) The surface morphologies of glass after femtosecond laser ablation; (c) The transmittances of surface with different structure; (d) The confocal microscopy images of protein (albumin and fibrinogen) adsorptions on bare and slippery surface; (e) The sequential images of blood spray attachment to untreated glass and the slippery surface
    The hemocompatibility of NiTi alloy slippery surface[58]. (a) The fluorescence distributions of bovine fibrinogen on untreated surface, porous surface, and slippery surface; (b) The growth conditions of E. coli and S. aureus on NiTi alloy with different structures; (c) Anticoagulant sheep blood move on the untreated surface and slippery surface
    Fig. 14. The hemocompatibility of NiTi alloy slippery surface[58]. (a) The fluorescence distributions of bovine fibrinogen on untreated surface, porous surface, and slippery surface; (b) The growth conditions of E. coli and S. aureus on NiTi alloy with different structures; (c) Anticoagulant sheep blood move on the untreated surface and slippery surface
    Application of slippery surface in food antifouling. (a) The fabrication process of slippery surface and contaminant coverage on different surfaces [92] ; (b) Surface morphologies of food-grade plastic after femtosecond laser ablation [92] ; (c) Movement of honey and tomato sauce on untreated surface and slippery surface [59] ; (d) The dripping behavior of different samples after honey sipping cycles [59]
    Fig. 15. Application of slippery surface in food antifouling. (a) The fabrication process of slippery surface and contaminant coverage on different surfaces [92] ; (b) Surface morphologies of food-grade plastic after femtosecond laser ablation [92] ; (c) Movement of honey and tomato sauce on untreated surface and slippery surface [59] ; (d) The dripping behavior of different samples after honey sipping cycles [59]
    Surface morphology and polarization curves of different samples[93]. Surface morphology of different samples: surface sprayed with SiO2 nanoparticles (a) intrinsic morphology and (b) morphology with silicone oil infusion; surface processed by laser ablation and spraying with nanoparticles (c) intrinsic morphology and (d) morphology with silicone oil infusion; (e) Polarization curves of different samples (Bare: intrinsic surface; Bare-SiO2: surface sprayed with silica nanoparticles; LST-SiO2: laser ablated and nanoparticle sprayed surface; Bare-SiO2-oil: surface injected with lubricant after sprayed with SiO2 nanoparticles; LST-SiO2-oil: surface processed by lubricant infusion after laser ablation and nanoparticle spraying)
    Fig. 16. Surface morphology and polarization curves of different samples[93]. Surface morphology of different samples: surface sprayed with SiO2 nanoparticles (a) intrinsic morphology and (b) morphology with silicone oil infusion; surface processed by laser ablation and spraying with nanoparticles (c) intrinsic morphology and (d) morphology with silicone oil infusion; (e) Polarization curves of different samples (Bare: intrinsic surface; Bare-SiO2: surface sprayed with silica nanoparticles; LST-SiO2: laser ablated and nanoparticle sprayed surface; Bare-SiO2-oil: surface injected with lubricant after sprayed with SiO2 nanoparticles; LST-SiO2-oil: surface processed by lubricant infusion after laser ablation and nanoparticle spraying)
    材料聚合物硬脆透明材料金属
    方法激光直写激光直写;飞秒激光+湿法刻蚀短脉冲激光脉冲整形;飞秒激光+酒精辅助
    应用液滴阵列化;液滴、气泡运输; 食品包装防污 透明防污窗口;光学传感; 生物镜头自清洁 海洋、食品防污;海洋减阻; 生物抗凝;防腐 防冰
    参考文献12, 50, 51, 52, 53, 71, 7254, 8659, 60, 58, 85, 92, 93
    Table 1. Overview of SLIPS on different materials by laser processing
    Qing Yang, Yang Cheng, Zheng Fang, Jialiang Zhang, Xun Hou, Feng Chen. The preparation and applications of bio-inspired slippery surface by femtosecond laser micro-nano manufacturing[J]. Opto-Electronic Engineering, 2022, 49(1): 210326-1
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