• Journal of Semiconductors
  • Vol. 42, Issue 5, 050301 (2021)
Wei Pan1, Yunfei Han1, Zhenguo Wang1, Qun Luo1..., Changqi Ma1 and Liming Ding2|Show fewer author(s)
Author Affiliations
  • 1Pintable Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics (CAS), Suzhou 215123, China
  • 2Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China
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    DOI: 10.1088/1674-4926/42/5/050301 Cite this Article
    Wei Pan, Yunfei Han, Zhenguo Wang, Qun Luo, Changqi Ma, Liming Ding. Over 1 cm2 flexible organic solar cells[J]. Journal of Semiconductors, 2021, 42(5): 050301 Copy Citation Text show less
    (Color online) Transparency and sheet resistance of the transparent conducting electrodes (reproduced with copyright permission from SPIE publisher)[6].
    Fig. 1. (Color online) Transparency and sheet resistance of the transparent conducting electrodes (reproduced with copyright permission from SPIE publisher)[6].
    (Color online) (a) Photographs of the large-area flexible OSCs. (b) J–V characteristics and (c) EQE spectra of the large-area flexible solar cells with PET/Ag/Cu grid electrodes. (d) J–V characteristics and (e) EQE spectra of the large-area flexible solar cells with PET/ITO electrodes (reproduced with copyright permission from Wiley-VCH)[16].
    Fig. 2. (Color online) (a) Photographs of the large-area flexible OSCs. (b) J–V characteristics and (c) EQE spectra of the large-area flexible solar cells with PET/Ag/Cu grid electrodes. (d) J–V characteristics and (e) EQE spectra of the large-area flexible solar cells with PET/ITO electrodes (reproduced with copyright permission from Wiley-VCH)[16].
    (Color online) (a) Sketch of spin coating and slot-die coating. (b) The small-area rigid device and large-area flexible device. (c) The chemical structures of PTB7-Th, PC71BM, and COi8DFIC. (d) Optical microscopy and SEM images of the PET/silver-grid substrate. (e) Comparison of this work with reported PCEs for flexible devices made by slot-die coating (reproduced with copyright permission from Wiley-VCH)[4].
    Fig. 3. (Color online) (a) Sketch of spin coating and slot-die coating. (b) The small-area rigid device and large-area flexible device. (c) The chemical structures of PTB7-Th, PC71BM, and COi8DFIC. (d) Optical microscopy and SEM images of the PET/silver-grid substrate. (e) Comparison of this work with reported PCEs for flexible devices made by slot-die coating (reproduced with copyright permission from Wiley-VCH)[4].
    (Color online) (a) Schematic diagram for the high-speed gravure printing process used to print silver nanowire electrodes. (b) Efficiency distribution diagram for the devices with PET/AgNWs-GV, PET/AgNWs-SP, and glass/ITO electrodes (reproduced with copyright permission from Wiley-VCH)[3].
    Fig. 4. (Color online) (a) Schematic diagram for the high-speed gravure printing process used to print silver nanowire electrodes. (b) Efficiency distribution diagram for the devices with PET/AgNWs-GV, PET/AgNWs-SP, and glass/ITO electrodes (reproduced with copyright permission from Wiley-VCH)[3].
    (Color online) The PCEs for small-area OSCs[1, 2, 28–35], large-area OSCs (>1 cm2)[3, 10, 11, 16, 36–41], and flexible OSC modules[4, 27, 37, 38, 42–47].
    Fig. 5. (Color online) The PCEs for small-area OSCs[1, 2, 2835], large-area OSCs (>1 cm2)[3, 10, 11, 16, 3641], and flexible OSC modules[4, 27, 37, 38, 4247].
    YearArea (cm2) PCE (%)ElectrodeDevice structureFabrication techniqueRef.
    20051.21PEDOT:PSSPEDOT:PSS/α-NPD/C60/BCP/Mg:Al Spin coating[36]
    2007101.6ITOPET/ITO/PEDOT:PSS/P3HT:PCBM/AlDoctor blading[37]
    200912.7ITOPET/ITO/ZnO/P3HT:PCBM/PEDOT:PSS/SilverScreen printing[38]
    201041.93Ag gridPEN/Ag grid/HC-PEDOT/P3HT:PCBM/LiF/AlSpin coating[39]
    20131.211.36Ag gridPET/Ag grid/PH1000/PEDOT:PSS-4083/P3HT:PCBB-C8/LiF/AlSpin coating[11]
    20141.215.85Ag gridPET/Ag grid/PH1000/ZnO/PFN/PTB7:PC71BM/MoO3/Ag Spin coating[10]
    201547.09AgPET/Ag/PFN/PTB7-Th:PC71BM/MoO3/Ag/MoO3Spin coating[34]
    20171.258.28Ag gridPET/Ag grid/PTB7-Th:p-DTS(FBTTH2)2:PC71BM/MoO3/Ag Slot-die[40]
    20182.037.6Ag/TiOxAg/TiOx/ZnO/PTB7-Th:ITIC/PEDOT:PSS Doctor blading[41]
    2019112.26Ag/Cu gridPET/Ag/Cu grid/E100/ZnO/PBDB-TF:IT-4F/MoO3/Al Spin coating[16]
    2020113.6Ag NWsPET/Ag NWs/ZnO/PM6:Y6/MoO3/Al Spin coating[3]
    Table 1. The performance data for large-area flexible OSCs (> 1 cm2) (Fig. 5).
    YearArea (cm2) PCE (%)ElectrodeDevice structureFabrication techniqueRef.
    200516.80.04PEDOT:PSSPET/PEDOT:PSS/MDMO-PPV:PCBM/AlDoctor blading[42]
    200717.11.5ITOPET/ITO/PEDOT:PSS/P3HT:PCBM/AlDoctor blading[37]
    2008532.52ITOPET/ITO/ PEDOT:PSS/P3HT:PCBM/ LiF/AlSpin coating[43]
    20091202.1ITOPET/ITO/ZnO/P3HT:PCBM/PEDOT:PSS/SilverScreen printing[38]
    2013661.6Ag gridPET/Ag grid/PEDOT:PSS/ZnO/P3HT:PCBM/PEDOT:PSS/Ag gridSlot-die[44]
    201483Ag gridPET/Ag grid/PEDOT/ZnO/PDTSTTz-4:PCBM/PEDOT/AgSlot-die[45]
    2016354.2FTOPET/FTO/PBTZT-stat-BDTT-8:PCBM/PEDOT:PSS/AgSlot-die[46]
    201710.56.5AgPES/Ag/PEI/P3HT:ICBA/PEI:m-PEDOT:PSS/PTB7-Th:PCBM/PEDOT:PSS/Ag gridSpin coating[47]
    2019158.9ITOPET/ITO/ZnO/active layer (PTB7-Th: PC71BM or PBDB-T: ITIC)/MoO3/Ag Slot-die[27]
    20202510.09Ag gridPET/Ag grid/ZnO/PTB7-Th:COi8DFIC:PC71BM/MoO3/Ag Slot-die[4]
    Table 2. The performance data for flexible OSC modules (Fig. 5).