Thermal-stable mixed-cation lead halide perovskite solar cells

Shuai Gu; Pengchen Zhu; Renxing Lin; Mingyao Tang; Shining Zhu; Jia Zhu

doi:10.3788/COL201715.093501

Journals >Chinese Optics Letters >Volume 15 >Issue 9 >Page 093501 > Article

Chinese Optics Letters
Vol. 15, Issue 9, 093501 (2017)

Thermal-stable mixed-cation lead halide perovskite solar cells | Editors' Pick

Shuai Gu, Pengchen Zhu, Renxing Lin, Mingyao Tang, Shining Zhu, and Jia Zhu^*

Author Affiliations

National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences and School of Physics, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China

show less

DOI: 10.3788/COL201715.093501 Cite this Article Set citation alerts

Shuai Gu, Pengchen Zhu, Renxing Lin, Mingyao Tang, Shining Zhu, Jia Zhu. Thermal-stable mixed-cation lead halide perovskite solar cells[J]. Chinese Optics Letters, 2017, 15(9): 093501 Copy Citation Text

EndNote(RIS)

BibTex

Plain Text

show less

(Color online) (a) XRD patterns of MA1-xCsxPbI3 films (x=0–0.30). (b) Absorption spectra of MA1-xCsxPbI3 films (x=0–0.30).

Fig. 1. (Color online) (a) XRD patterns of

{MA}_{1 - x} {Cs}_{x} {PbI}_{3}

films (

x = 0 - 0.30

). (b) Absorption spectra of

{MA}_{1 - x} {Cs}_{x} {PbI}_{3}

films (

x = 0 - 0.30

Download full size | View in the Article

(a)–(e) Top-view SEM images of MA1-xCsxPbI3 films for x=0, 0.05, 0.10, 0.15, 0.20, and 0.30. Scale bars are all 250 nm. (g) Cross-section SEM images of a solar cell. The scale bar is 1 μm.

Fig. 2. (a)–(e) Top-view SEM images of

{MA}_{1 - x} {Cs}_{x} {PbI}_{3}

films for

x = 0

, 0.05, 0.10, 0.15, 0.20, and 0.30. Scale bars are all 250 nm. (g) Cross-section SEM images of a solar cell. The scale bar is 1 μm.

Download full size | View in the Article

Fig. 3. (Color online) (a) Best performances of PV devices incorporating

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

and

{MAPbI}_{3}

, respectively. (b) EQE spectra of

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

and

{MAPbI}_{3}

-based devices. (c) and (d) PCE distributions of

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

and

{MAPbI}_{3}

-based devices.

Download full size | View in the Article

Fig. 4. (Color online) XRD patterns and absorption spectra of

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

and

{MAPbI}_{3}

films before and after thermal treatment. (a) and (b) XRD patterns of

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

and

{MAPbI}_{3}

films before and after being heated at 150°C for 20 min, respectively. (c) and (d) Absorption spectra of

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

and

{MAPbI}_{3}

films before and after being heated at 150°C for 3 h, respectively. For comparison, the insets in (c) and (d) are the photographs of

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

and

{MAPbI}_{3}

films before (the left) and after (the right) being heated at 150°C for 3 h.

Download full size | View in the Article

Fig. 5. (Color online) Thermal stability of devices under a heat stress test at 140°C. (a) Normalized

V_{oc}

, (b) normalized

J_{sc}

, (c) normalized FF, and (d) normalized PCE. Insets in (a) are the photographs of devices with

{MA}_{0.85} {Cs}_{0.15} {PbI}_{3}

(right) and

{MAPbI}_{3}

(left) after being heated at 140°C for 80 min.

Download full size | View in the Article

Shuai Gu, Pengchen Zhu, Renxing Lin, Mingyao Tang, Shining Zhu, Jia Zhu. Thermal-stable mixed-cation lead halide perovskite solar cells[J]. Chinese Optics Letters, 2017, 15(9): 093501

Download Citation

EndNote(RIS)

BibTex

Plain Text

Set citation alerts for the article

Tools

Set citation alerts for the article

Save the article for my favorites

Paper Information