• Journal of Inorganic Materials
  • Vol. 36, Issue 6, 659 (2021)
Jun FAN1, Xue JIANG2, Yi JIAO2、*, Yusheng CHEN1, Jianli WANG1、*, and Yaoqiang CHEN1、2
Author Affiliations
  • 11. College of Chemistry, Sichuan University, Chengdu 610064, China
  • 22. Institute of New Energy and Low-Carbon Technology, Sichuan University, Chengdu 610064, China
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    DOI: 10.15541/jim20200357 Cite this Article
    Jun FAN, Xue JIANG, Yi JIAO, Yusheng CHEN, Jianli WANG, Yaoqiang CHEN. Effect of Different Alkali-assisted Deposition Precipitation Methods on the Durability of Three-way Catalysts[J]. Journal of Inorganic Materials, 2021, 36(6): 659 Copy Citation Text show less
    XRD patterns of fresh and aged samples (a) and the comparison of their relative intensities of Pt (111) based on the strongest peak of support (b)
    1. XRD patterns of fresh and aged samples (a) and the comparison of their relative intensities of Pt (111) based on the strongest peak of support (b)
    Pt dispersion of samples measured by CO-chemisorption method (a) and FT-IR spectra of CO absorbed on the fresh (b) and aged (c) samples
    2. Pt dispersion of samples measured by CO-chemisorption method (a) and FT-IR spectra of CO absorbed on the fresh (b) and aged (c) samples
    XPS spectra of O1s (a, d), Ce3d (b, e) and Pt4f (c, f) for fresh (a-c) and aged (d-f) samples
    3. XPS spectra of O1s (a, d), Ce3d (b, e) and Pt4f (c, f) for fresh (a-c) and aged (d-f) samples
    H2-TPR profiles of the fresh (a) and aged (b) samples
    4. H2-TPR profiles of the fresh (a) and aged (b) samples
    Conversion curves of CO, NO, C3H8 and C3H6 over the fresh (a-d) and aged (e-h) samples, respectively
    5. Conversion curves of CO, NO, C3H8 and C3H6 over the fresh (a-d) and aged (e-h) samples, respectively
    SamplesSurface area/(m2•g-1)Pore volume/(mL•g-1)Average poreradius/nm
    IM600.237.5
    UDP630.227.5
    ADP610.237.7
    IM-a490.249.4
    UDP-a500.227.6
    ADP-a530.257.7
    CZLP640.258.7
    Table 1.

    Textural and structural parameters of the support and samples

    SamplePt0/Pt ratioPt2+/Pt ratioPt4+/Pt ratioOads/O ratioCe3+/Ce ratio
    IM00.8710.1290.3540.217
    UDP00.8510.1490.3740.240
    ADP00.8310.1690.3240.201
    IM-a0.3020.69800.3290.195
    UDP-a0.4210.57900.3500.187
    ADP-a0.2340.76600.3360.214
    Table 2.

    Surface elemental state ratio derived from by XPS

    SampleCONOC3H8C3H6
    T50/℃ΔT /℃T50/℃ΔT/℃T50/℃ΔT/℃T50/℃ΔT/℃
    IM174-260-269-234-
    UDP142-259-273-228-
    ADP187-277-284-254-
    IM-a21541304443124327844
    UDP-a22987313543285528759
    ADP-a20316294173062227218
    Table 3.

    Light-off (T50) temperature and ΔT for three-way catalytic reactions over catalysts

    Jun FAN, Xue JIANG, Yi JIAO, Yusheng CHEN, Jianli WANG, Yaoqiang CHEN. Effect of Different Alkali-assisted Deposition Precipitation Methods on the Durability of Three-way Catalysts[J]. Journal of Inorganic Materials, 2021, 36(6): 659
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