• Journal of Inorganic Materials
  • Vol. 40, Issue 3, 323 (2025)
Shuang MU1,2, Qin MA1,2, Yu ZHANG1,2, Xu SHEN1,2..., Jinshan YANG1,2,* and Shaoming DONG1,2,*|Show fewer author(s)
Author Affiliations
  • 11. State Key Laboratory of High Performance Ceramics & Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
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    DOI: 10.15541/jim20240148 Cite this Article
    Shuang MU, Qin MA, Yu ZHANG, Xu SHEN, Jinshan YANG, Shaoming DONG. Oxidation Behavior of Yb2Si2O7 Modified SiC/SiC Mini-composites [J]. Journal of Inorganic Materials, 2025, 40(3): 323 Copy Citation Text show less

    Abstract

    Silicon-carbide-fiber-reinforced silicon-carbide-ceramic-based matrix (SiC/SiC) composites possess excellent properties such as low density, high strength and high temperature resistance, showing a potential application for structural components in the aerospace field, but their oxidation behavior remains largely unknown. In this study, Yb2Si2O7 modified SiC/SiC (SiC/SiC-Yb2Si2O7) mini-composites were prepared by introducing Yb2Si2O7 as anti-oxidation phase into SiC fiber bundles via Sol-Gel and depositing SiC matrix by chemical vapor deposition (CVD). Influence of Yb2Si2O7 on microstructure, mechanical property and oxidation behavior of SiC/SiC mini-composites was investigated. The results showed that after oxidation in air at 1200 and 1400 ℃ for 50 h, the tensile strength retentions of SiC/SiC mini-composites were 77% and 69%, respectively, and the fracture morphology exhibited flat. The Yb2Si2O7 introduced by Sol-Gel partially distributed in layers, contributing to the toughening of the material. On the fracture surface, there was interlayer debonding, which extended energy dissipation mechanism of SiC/SiC mini-composites. Tensile strength of SiC/SiC-Yb2Si2O7 mini-composites at room temperature was 484 MPa. After oxidation in air at 1200 and 1400 ℃ for 50 h, the tensile strengths decreased to 425 and 374 MPa, resulting in retention rates of 88% and 77%, respectively. It displayed typical non-brittle fracture characteristics. The interface oxygen content of SiC/SiC mini-composites at the fracture surface was higher than that of SiC/SiC-Yb2Si2O7 mini-composites, indicating that introduction of Yb2Si2O7 could alleviate oxygen diffusion towards the interface, and therefore improve the oxidation resistance of SiC/SiC-Yb2Si2O7 mini-composites.
    $\frac{w_{i}-w_{0}}{w_{0}}=\sqrt{k t}$

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    Shuang MU, Qin MA, Yu ZHANG, Xu SHEN, Jinshan YANG, Shaoming DONG. Oxidation Behavior of Yb2Si2O7 Modified SiC/SiC Mini-composites [J]. Journal of Inorganic Materials, 2025, 40(3): 323
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