• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 10, 3106 (2021)
Liu-fang NI1、*, Jing YU1、1;, Xin-ping WANG1、1;, Jun WANG1、1;, Xiao-xia CAO2、2;, Shi-lin CAO1、1; *;, and Xiao-juan MA1、1; *;
Author Affiliations
  • 11. College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108, China
  • 22. School of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou 350108, China
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    DOI: 10.3964/j.issn.1000-0593(2021)10-3106-05 Cite this Article
    Liu-fang NI, Jing YU, Xin-ping WANG, Jun WANG, Xiao-xia CAO, Shi-lin CAO, Xiao-juan MA. Studies on the Effects of Sodium Hydroxide on Hydrogen Bonding of Water and Ionic Liquid/H2O Systems by ATR-IR Analyses[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3106 Copy Citation Text show less
    ATR-IR spectra of NaOH solutions with different concentrations
    Fig. 1. ATR-IR spectra of NaOH solutions with different concentrations
    Deconvolution spectra of NaOH solutions (a) and the second derivative spectra of NaOH solutions (b)
    Fig. 2. Deconvolution spectra of NaOH solutions (a) and the second derivative spectra of NaOH solutions (b)
    ATR-IR spectra of H2O, EmimAc and EmimAc/H2O(a): Local figure of 3 800~2 700 cm-1;(b): Local figure of 1 800~1 000 cm-1
    Fig. 3. ATR-IR spectra of H2O, EmimAc and EmimAc/H2O
    (a): Local figure of 3 800~2 700 cm-1;(b): Local figure of 1 800~1 000 cm-1
    ATR-IR spectra of H2O, EmimAc and EmimAc/H2O(a): Local figure of 3 800~2 700 cm-1;(b): Local figure of 1 800~900 cm-1
    Fig. 4. ATR-IR spectra of H2O, EmimAc and EmimAc/H2O
    (a): Local figure of 3 800~2 700 cm-1;(b): Local figure of 1 800~900 cm-1
    波数/cm-1归属
    701咪唑环面外不对称弯曲振动咪唑啉型的振动模式
    761咪唑环HCCH基团的不对称弯曲振动以及NC(H)N基团的弯曲振动
    805咪唑环HCCH基团的不对称弯曲振动以及NC(H)N基团的弯曲振动
    900CCH基团的弯曲振动
    957CC基团的伸缩振动
    1 001C—N—C基团的对称伸缩振动
    1 047CCH基团的剪切
    1 089C—C基团的伸缩振动模式
    1 173(N)CH2, CH3(N)CN基团的面内不对称伸缩振动以及CC基团的拉伸振动OAc中C=O的振动引起的咪唑环上C—H基团的面内变形振动
    1 258醋酸根中C—CH3基团的伸缩振动不饱和C以及芳香环骨架的伸缩振动, 表明咪唑环结构的存在
    1 327—CH2—基团的卷积振动
    1 378咪唑环的面内不对称伸缩振动, CH2(N)基团的不对称弯曲振动, CC, CH2(N)及CH3(N)CN基团的不对称伸缩振动
    1 427与—CH2—基团相连的—COOH基团的面内弯曲振动
    1 560C=O基团的拉伸振动
    2 976N-甲基的伸缩振动烷基的伸缩振动, 咪唑环上C—H基团伸缩振动
    3 049C2—H基团的拉伸振动
    3 144C4, 5—H基团的拉伸振动
    Table 1. Assignments of the bands in the ATR-IR spectra of EmimAc
    Liu-fang NI, Jing YU, Xin-ping WANG, Jun WANG, Xiao-xia CAO, Shi-lin CAO, Xiao-juan MA. Studies on the Effects of Sodium Hydroxide on Hydrogen Bonding of Water and Ionic Liquid/H2O Systems by ATR-IR Analyses[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3106
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