• Laser & Optoelectronics Progress
  • Vol. 59, Issue 15, 1516013 (2022)
Zhousu Xu1、†,*, Jiazhi Xia1、†, Xiaofeng Liu2, and Jianrong Qiu3
Author Affiliations
  • 1Institute of Intelligent Optoelectronic Technology, Zhejiang University of Technology, Hangzhou 310023, Zhejiang , China
  • 2School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, Zhejiang , China
  • 3College of Optical Science and Engineering, Zhejiang University, Hangzhou 310027, Zhejiang , China
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    DOI: 10.3788/LOP202259.1516013 Cite this Article Set citation alerts
    Zhousu Xu, Jiazhi Xia, Xiaofeng Liu, Jianrong Qiu. Research Progress in Modulation of Optical Properties and Applications of CsPbX3 Perovskite Quantum Dot Doped Glasses[J]. Laser & Optoelectronics Progress, 2022, 59(15): 1516013 Copy Citation Text show less
    Influence of the molar ratio of SiO2 to B2O3 on crystallization and optical properties of CsPbI3 quantum dots glass. (a) Raman spectra and (b) XRD patterns of CsPbI3 quantum dots; (c) absorption spectra and (d) photoluminescence spectra of quantum dots at different B2O3 contents (samples were marked as SiBx-y, x is the molar ratio of B2O3, and y is the heat treatment temperature) [27]
    Fig. 1. Influence of the molar ratio of SiO2 to B2O3 on crystallization and optical properties of CsPbI3 quantum dots glass. (a) Raman spectra and (b) XRD patterns of CsPbI3 quantum dots; (c) absorption spectra and (d) photoluminescence spectra of quantum dots at different B2O3 contents (samples were marked as SiBx-y, x is the molar ratio of B2O3, and y is the heat treatment temperature) [27]
    Influence of ZnO contents on crystallization and optical properties of CsPbI3 quantum dots glass. (a) FT-IR spectra[28]; (b) XRD patterns[28]; (c) PL spectra[28]; (d) PL quantum yield[28] (samples were marked as ZnOx-y-z, x is ZnO molar ratio, y is heat treatment temperature, and z is heat treatment time). Influence of Al2O3 contents on optical properties of CsPbBr3 quantum dots glass. (e) Excitation spectra[30]; (f) PL spectra[30] (samples were marked as Al2O3-x, x is Al2O3 molar ratio)
    Fig. 2. Influence of ZnO contents on crystallization and optical properties of CsPbI3 quantum dots glass. (a) FT-IR spectra[28]; (b) XRD patterns[28]; (c) PL spectra[28]; (d) PL quantum yield[28] (samples were marked as ZnOx-y-z, x is ZnO molar ratio, y is heat treatment temperature, and z is heat treatment time). Influence of Al2O3 contents on optical properties of CsPbBr3 quantum dots glass. (e) Excitation spectra[30]; (f) PL spectra[30] (samples were marked as Al2O3-x, x is Al2O3 molar ratio)
    Effect of different metal oxides (SrO, CaO, and MgO) on crystallization and optical properties of CsPbBr3 quantum dots glass. (a) XRD patterns; (b) TEM image; (c) PL spectra; (d) PL delay carves (S1, S2, and S3 represent samples doped with SrO, CaO, and MgO, respectively) [31]
    Fig. 3. Effect of different metal oxides (SrO, CaO, and MgO) on crystallization and optical properties of CsPbBr3 quantum dots glass. (a) XRD patterns; (b) TEM image; (c) PL spectra; (d) PL delay carves (S1, S2, and S3 represent samples doped with SrO, CaO, and MgO, respectively) [31]
    Influence of CaF2 contents on crystallization and optical properties of CsPbBr3 quantum dots glass. (a) FT-IR spectra [32]; (b) Raman spectra[32]; (c) XRD patterns[32]; (d) images of CsPbBr3 quantum dot glass at different heat treatment temperatures and different doping concentrations of CaF2 under UV lamp[32]; (e) absorption spectra[32]; (f) PL spectra of CsPbBr3 quantum dots[32]; (g) quantum yields curves of CsPbBr3 quantum dots under different heat treatment temperature and different CaF2 contents[32] (samples were marked as CPBx-y-z,x is CaF2 doping molar ratio, y is heat treatment temperature, and z is heat treatment time); (h) XRD patterns of the perovskite QDs glasses [33]
    Fig. 4. Influence of CaF2 contents on crystallization and optical properties of CsPbBr3 quantum dots glass. (a) FT-IR spectra [32]; (b) Raman spectra[32]; (c) XRD patterns[32]; (d) images of CsPbBr3 quantum dot glass at different heat treatment temperatures and different doping concentrations of CaF2 under UV lamp[32]; (e) absorption spectra[32]; (f) PL spectra of CsPbBr3 quantum dots[32]; (g) quantum yields curves of CsPbBr3 quantum dots under different heat treatment temperature and different CaF2 contents[32] (samples were marked as CPBx-y-z,x is CaF2 doping molar ratio, y is heat treatment temperature, and z is heat treatment time); (h) XRD patterns of the perovskite QDs glasses [33]
    Effect of AgO contents on crystallization and optical properties of CsPbBr3 quantum dots glass. (a) XRD patterns[34]; (b) TEM image[34]; (c) PL spectra[34]; (d) PL delay spectra[34] (samples were marked as CPBAx-y, x is the molar ratio of AgO doping, and y is the heat treatment temperature). Effect of Ag2O contents on CsPbBr3 quantum dots glass. (e) XRD patterns[35]; (f) infrared spectra[35]; (g) absorption spectra[35]; (h) PL spectra[35] (samples were marked as Gx,x is the AgO doping molar ratio)
    Fig. 5. Effect of AgO contents on crystallization and optical properties of CsPbBr3 quantum dots glass. (a) XRD patterns[34]; (b) TEM image[34]; (c) PL spectra[34]; (d) PL delay spectra[34] (samples were marked as CPBAx-y, x is the molar ratio of AgO doping, and y is the heat treatment temperature). Effect of Ag2O contents on CsPbBr3 quantum dots glass. (e) XRD patterns[35]; (f) infrared spectra[35]; (g) absorption spectra[35]; (h) PL spectra[35] (samples were marked as Gx,x is the AgO doping molar ratio)
    Effect of Dy3+ contents on optical properties of CsPbBr3 quantum dots glass. (a) PL spectra[37]; (b) CIE color coordinates of glass in different temperature[37] (illustration is glass sample picture excited in 365 nm) (samples were marked as BSx, x is the molar ratio of Dy3+ doping). Effect of Tb3+ contents on optical properties of CsPbBr3 quantum dots glass. (c) PL spectra[38]; (d) PL delay spectrum[38]; (e) fluorescence images during temperature rise[39]. Influence of Eu3+/Tm3+ co-doping on CsPbBr3 quantum dots glass. (f) PL spectra of samples excited at 375 nm[40]; (g) digital images[40]; (h) corresponding CIE color coordinates[40]
    Fig. 6. Effect of Dy3+ contents on optical properties of CsPbBr3 quantum dots glass. (a) PL spectra[37]; (b) CIE color coordinates of glass in different temperature[37] (illustration is glass sample picture excited in 365 nm) (samples were marked as BSx, x is the molar ratio of Dy3+ doping). Effect of Tb3+ contents on optical properties of CsPbBr3 quantum dots glass. (c) PL spectra[38]; (d) PL delay spectrum[38]; (e) fluorescence images during temperature rise[39]. Influence of Eu3+/Tm3+ co-doping on CsPbBr3 quantum dots glass. (f) PL spectra of samples excited at 375 nm[40]; (g) digital images[40]; (h) corresponding CIE color coordinates[40]
    Effect of K+ contents on optical properties of CsPbBr3 quantum dots glass. (a) PL spectra[41]; (b) thermal stability cycles images[41]. Effect of Rb+ contents on optical properties of CsPbBr3 quantum dots glass. (c) PL spectra[42]; (d) absorption spectra[42](x is Rb+ doping ratio). Effect of Sn2+ contents on optical properties of CsPbBr3 quantum dots glass. (e) PL spectra[43]; (f) PL quantum yield curves[43] (x is Sn2+ doping ratio). Effect of Cd2+ contents on crystallization and optical properties of CsPbBr3 quantum dots glass. (g) XRD patterns[44]; (h) PL spectra[44]
    Fig. 7. Effect of K+ contents on optical properties of CsPbBr3 quantum dots glass. (a) PL spectra[41]; (b) thermal stability cycles images[41]. Effect of Rb+ contents on optical properties of CsPbBr3 quantum dots glass. (c) PL spectra[42]; (d) absorption spectra[42](x is Rb+ doping ratio). Effect of Sn2+ contents on optical properties of CsPbBr3 quantum dots glass. (e) PL spectra[43]; (f) PL quantum yield curves[43] (x is Sn2+ doping ratio). Effect of Cd2+ contents on crystallization and optical properties of CsPbBr3 quantum dots glass. (g) XRD patterns[44]; (h) PL spectra[44]
    Laser induced crystallization of CsPbX3 quantum dots. (a) Schematic diagram of direct photolithography of color perovskite nanocrystals and patterns[45]; (b)-(d) multi-pattern based on CsPbBr3-xIx nanocrystals[45]; (e) demonstration of optical information storage application[47]
    Fig. 8. Laser induced crystallization of CsPbX3 quantum dots. (a) Schematic diagram of direct photolithography of color perovskite nanocrystals and patterns[45]; (b)-(d) multi-pattern based on CsPbBr3-xIx nanocrystals[45]; (e) demonstration of optical information storage application[47]
    X ray imaging. (a) Schematic of experimental setup; (b)-(d) X ray image of sample[49]
    Fig. 9. X ray imaging. (a) Schematic of experimental setup; (b)-(d) X ray image of sample[49]
    White LED is prepared by blue InGaN chip, Ce3+∶YAG phosphor, and Gd3+ doped CsPbBrI2 quantum dot glass. (a) PL spectra and corresponding images; (b) CIE coordinates and WLED device photographs; (c) schematic diagram of WLED structure and fluorescence images of glass powder under an UV lamp[53]
    Fig. 10. White LED is prepared by blue InGaN chip, Ce3+∶YAG phosphor, and Gd3+ doped CsPbBrI2 quantum dot glass. (a) PL spectra and corresponding images; (b) CIE coordinates and WLED device photographs; (c) schematic diagram of WLED structure and fluorescence images of glass powder under an UV lamp[53]
    Zhousu Xu, Jiazhi Xia, Xiaofeng Liu, Jianrong Qiu. Research Progress in Modulation of Optical Properties and Applications of CsPbX3 Perovskite Quantum Dot Doped Glasses[J]. Laser & Optoelectronics Progress, 2022, 59(15): 1516013
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