Author Affiliations
1 School of Energy and Environment, Southeast University, Nanjing, Jiangsu 210096, China2 Key Laboratory for Power Machinery and Engineering of Ministry of Education, Shanghai Jiao Tong University, Shanghai 200240, Chinashow less
Fig. 1. Simulated absorbance of different gases near 1.5 μm wavelength (T=300 K, p=9.5 kPa, L=1.6×104 m). (a) 6528.9 cm-1; (b) 6548.7 cm-1; (c) 6568.4 cm-1; (d) 6596.4 cm-1; (e) 6600.2 cm-1; (f) 6612.7 cm-1; (g) 6678.5 cm-1
Fig. 2. Simulated absorbance of different gases in range of 6520-6532 cm-1 (T=300 K, p=9.5 kPa, L=1.6×104 m)
Fig. 3. Simulated absorbance of different gases near 6521.97 cm-1 (T=300 K, p=9.5 kPa, L=1.6×104 m)
Fig. 4. Schematic of laser mode matching
Fig. 5. Transmitted cavity mode signal
Fig. 6. Schematic of CRDS experimental system
Fig. 7. Experimental gas path
Fig. 8. Acquisition and fitting of ring-down curve
Fig. 9. Absorption lines of NH3, CO2 and H2O in atmosphere in range of 6520-6530 cm-1 (T=300 K, p=9.5 kPa, L=1.6×104 m). (a) Experimental measurement data; (b) simulation results in HITRAN database
Fig. 10. Absorption coefficient of 55 sampling points obtained by measurement
Fig. 11. Absorption results of 6521.97 cm-1 NH3 and 6522.04 cm-1 H2O spectral lines after baseline deduction
Fig. 12. (a) Voigt multi-peak fitting results of NH3 and H2O absorbance; (b) fitting residual
Fig. 13. (a) NH3 concentration obtained by a continuous measurement for 400 s in outdoor environment; (b) Allan deviation
Mean value /μs | Maximum value /μs | Minimum value /μs | Standard deviation /μs |
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96.2640 | 98.3090 | 93.7180 | 0.6518 |
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Table 1. Cavity ring-down time obtained after acquisition and measurement for 1000 times
Test gas | Condition | Measured mole fraction | Sensitivity |
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NH3 | indoor | 2.0×10-7 | 4.10×10-10 | NH3 | outdoor | 1.2×10-7 | 3.90×10-10 | CO2 | indoor | 7.6×10-4 | 2.39×10-6 | CO2 | outdoor | 3.9×10-4 | 2.35×10-6 |
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Table 2. Measurement results of NH3 and CO2 concentrations under different conditions