• Chinese Journal of Lasers
  • Vol. 46, Issue 12, 1211001 (2019)
Zhirong Zhang1、2、3、**, Tao Pang1、*, Pengshuai Sun1, Hua Xia1, Zhe Li1、3, Runqing Yu1、3, Xiaojuan Cui1, and Shu Chimin4
Author Affiliations
  • 1Anhui Provincial Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics,Chinese Academy of Sciences, Hefei, Anhui 230031, China
  • 2Key Laboratory of Environmental Optics & Technology, Anhui Institute of Optics and Fine Mechanics,Chinese Academy of Sciences, Hefei, Anhui 230031, China;
  • 3School of Environment Science and Optoelectronic Technology, University of Science and Technology of China,Hefei, Anhui 230061, China
  • 4Department of Safety Health and Environmental Engineering, Taiwan Yunlin University of Science and Technology,Yunlin, Taiwan 64002, China
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    DOI: 10.3788/CJL201946.1211001 Cite this Article Set citation alerts
    Zhirong Zhang, Tao Pang, Pengshuai Sun, Hua Xia, Zhe Li, Runqing Yu, Xiaojuan Cui, Shu Chimin. Measurement of Carbon Isotope of Methane and Analysis of Its Genesis Type Using Laser Absorption Spectroscopy[J]. Chinese Journal of Lasers, 2019, 46(12): 1211001 Copy Citation Text show less
    Schematic of Beer-lambert law. (a) Gas absorption diagram; (b) signal diagram after gas absorption
    Fig. 1. Schematic of Beer-lambert law. (a) Gas absorption diagram; (b) signal diagram after gas absorption
    Spectral line intensities of methane carbon isotope at different wavelengths in HITRAN database. (a) 13CH4; (b) 12CH4
    Fig. 2. Spectral line intensities of methane carbon isotope at different wavelengths in HITRAN database. (a) 13CH4; (b) 12CH4
    Results of CH4 spectral simulations at 1658 nm
    Fig. 3. Results of CH4 spectral simulations at 1658 nm
    Schematic of experimental setup
    Fig. 4. Schematic of experimental setup
    Flow chart of control process and fuzzy adaptive PID closed-cycle control algorithm
    Fig. 5. Flow chart of control process and fuzzy adaptive PID closed-cycle control algorithm
    Photo of test-field equipment (right photo shows sampling rubber balls)
    Fig. 6. Photo of test-field equipment (right photo shows sampling rubber balls)
    Signal spectra of methane isotopic gas samples using proposed system. (a) Direct-absorption signals; (b) second harmonic signals(2f)
    Fig. 7. Signal spectra of methane isotopic gas samples using proposed system. (a) Direct-absorption signals; (b) second harmonic signals(2f)
    Measurement distribution values of methane concentration and carbon isotopic abundance of coal mine samples. Dotted square line stands for distribution values of methane concentrations at different sampling positions of coal mine; dotted star line stands for distribution values of methane carbon isotope abundances at different sampling positions of coal mine
    Fig. 8. Measurement distribution values of methane concentration and carbon isotopic abundance of coal mine samples. Dotted square line stands for distribution values of methane concentrations at different sampling positions of coal mine; dotted star line stands for distribution values of methane carbon isotope abundances at different sampling positions of coal mine
    MoleculeWavelength /nmWavenumber /cm-1Intensity /(cm·molecule-1)Elow /cm-1
    1658.629866029.072687.794×10-2262.8787
    13CH41658.625356029.089087.802×10-2262.8797
    1658.620186029.107871.283×10-2162.8811
    12CH41658.772646028.553732.692×10-23104.7728
    Table 1. Selected spectral data of methane in 1658.4-1659.6 nm
    NumberSampling positionNumberSampling position
    SM-15# U-type borehole height in 912 air waySM-64# fire prevention observation points in 7133 air way
    SM-2Bedding hole in 912 air waySM-750 groups of 1# holes in 1# extraction way of east-wing of No. 3 mining area
    SM-31#-1 fire prevention observation points in 7135 retain roadwaysSM-842 groups of 1# holes in 1# extraction way of east-wing of No. 3 mining area
    SM-41#-2 fire prevention observation points in 7135 retain roadwaysSM-943 groups of 1 # holes in 2# extraction way of east-wing of No. 3 mining area
    SM-536# bedding hole in west 7135 air waySM-1035 groups of 1# holes in 2# extraction way of east-wing of No. 3 mining area
    Table 2. List of sampling positions
    Zhirong Zhang, Tao Pang, Pengshuai Sun, Hua Xia, Zhe Li, Runqing Yu, Xiaojuan Cui, Shu Chimin. Measurement of Carbon Isotope of Methane and Analysis of Its Genesis Type Using Laser Absorption Spectroscopy[J]. Chinese Journal of Lasers, 2019, 46(12): 1211001
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