• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 5, 1628 (2022)
Pei SHI1、1;, Zhi-wei JIN1、1;, Fen WANG1、1; *;, Hong-jie LUO1、1; 2;, Jian-feng ZHU1、1;, Guo-zhen YE3、3;, and Yu-feng ZHANG4、4;
Author Affiliations
  • 11. School of Material Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China
  • 33. Zhejiang Xiaoshan Institute of Song Dynasty Porcelain, Hangzhou 311200, China
  • 44. Henan Songgong Ru Porcelain Ltd., Ruzhou 467599, China
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    DOI: 10.3964/j.issn.1000-0593(2022)05-1628-06 Cite this Article
    Pei SHI, Zhi-wei JIN, Fen WANG, Hong-jie LUO, Jian-feng ZHU, Guo-zhen YE, Yu-feng ZHANG. Influence Mechanism of the Iron-Rich Raw Material on the Iron-Based Crystalline Glazes[J]. Spectroscopy and Spectral Analysis, 2022, 42(5): 1628 Copy Citation Text show less
    Appearances of iron-rich raw materials(a): Qingshitou; (b): Hongshitou; (c): Zijintu
    Fig. 1. Appearances of iron-rich raw materials
    (a): Qingshitou; (b): Hongshitou; (c): Zijintu
    Optical micrographs of iron-rich raw materials(a), (b): Qingshitou; (c), (d): Hongshitou; (e), (f): Zijintu
    Fig. 2. Optical micrographs of iron-rich raw materials
    (a), (b): Qingshitou; (c), (d): Hongshitou; (e), (f): Zijintu
    XRD patterns of iron-rich raw materials
    Fig. 3. XRD patterns of iron-rich raw materials
    Raman spectra of color-causing mineralsin raw materials a: Qingshitou; b: Hongshitou; c, d: Zijintu
    Fig. 4. Raman spectra of color-causing mineralsin raw materials
    a: Qingshitou; b: Hongshitou; c, d: Zijintu
    Microstructures of glaze surfaces fired from iron-rich raw materials(a), (b): Qingshitou glaze; (c), (d): Hongshitou glaze; (e), (f): Zijintu glaze
    Fig. 5. Microstructures of glaze surfaces fired from iron-rich raw materials
    (a), (b): Qingshitou glaze; (c), (d): Hongshitou glaze; (e), (f): Zijintu glaze
    SEM images and EDS spectra of crystals in the Qingshitou and Zijintu glazes(a), (b): Qingshitou glaze; (c): Zijintu glaze
    Fig. 6. SEM images and EDS spectra of crystals in the Qingshitou and Zijintu glazes
    (a), (b): Qingshitou glaze; (c): Zijintu glaze
    Raman spectra of crystals in the Qingshitou and Zijintu glazesa: Dendrite; b: Flower-like crystla; c: Rod-like crystla
    Fig. 7. Raman spectra of crystals in the Qingshitou and Zijintu glazes
    a: Dendrite; b: Flower-like crystla; c: Rod-like crystla
    Schematic diagram of the crystal formation process in the Qingshitou and Zijintu glazes(a): Qingshitou glaze; (b): Zijintu glaze
    Fig. 8. Schematic diagram of the crystal formation process in the Qingshitou and Zijintu glazes
    (a): Qingshitou glaze; (b): Zijintu glaze
    SampleSiO2Al2O3Fe2O3TiO2CaOMgOK2ONa2OP2O5ZnO
    Qingshitou64.6511.591.520.298.851.568.170.210.731.61
    Hongshitou61.3612.925.600.826.221.643.1800.230
    Zijintu70.2214.895.370.700.420.972.6400.080
    Table 1. The chemical compositions of iron-rich raw materials (Wt%)
    Pei SHI, Zhi-wei JIN, Fen WANG, Hong-jie LUO, Jian-feng ZHU, Guo-zhen YE, Yu-feng ZHANG. Influence Mechanism of the Iron-Rich Raw Material on the Iron-Based Crystalline Glazes[J]. Spectroscopy and Spectral Analysis, 2022, 42(5): 1628
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