• Journal of Inorganic Materials
  • Vol. 34, Issue 8, 885 (2019)
Li-Yan ZHANG1, Hong LI2, Li-Li HU1, and Ya-Jie WANG1、3
Author Affiliations
  • 1Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201815, China
  • 2Nippon Electric Glass, Shelby, North Carolina 28150, USA
  • 3University of Chinese Academy of Sciences, Beijing 100049, China
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    DOI: 10.15541/jim20180514 Cite this Article
    Li-Yan ZHANG, Hong LI, Li-Li HU, Ya-Jie WANG. Structure Modeling of Genes in Glass: Composition-structure-property Approach[J]. Journal of Inorganic Materials, 2019, 34(8): 885 Copy Citation Text show less
    Raman spectra of BL glass and SiO2 modified glasses, comparing the measured and the simulated spectra (a) along with the corresponding error in detail curve fitting results for BL glass (b), and the fitting detail of gridlines (c) in Fig.1(a)
    1. Raman spectra of BL glass and SiO2 modified glasses, comparing the measured and the simulated spectra (a) along with the corresponding error in detail curve fitting results for BL glass (b), and the fitting detail of gridlines (c) in Fig.1(a)
    Effect of SiO2、B2O3 and La2O3 on Raman spectra of BL glass
    2. Effect of SiO2、B2O3 and La2O3 on Raman spectra of BL glass
    C-P and S-P Raman models of chemical stability
    3. C-P and S-P Raman models of chemical stability
    Predicted and experimental results of the chemical stability for the modified BL glass based on S-P modeling
    4. Predicted and experimental results of the chemical stability for the modified BL glass based on S-P modeling
    Simulator designed special structural group distributions (Ai) in the glass to meet required properties
    5. Simulator designed special structural group distributions (Ai) in the glass to meet required properties
    Designed results of C-P model
    6. Designed results of C-P model
    Linear estimated values for Tg, Stark splitting and emission cross section
    7. Linear estimated values for Tg, Stark splitting and emission cross section
    SampleWL/(mg•cm-2)ndn2/(×10-13, esu)α300 ℃/(×10-6, K-1)Tg/℃
    BL1.291.504661.0512.51493.1
    S10.891.505740.9912.75471.9
    S21.071.506500.9912.56471.6
    S31.301.506000.9812.62482.7
    S41.111.505540.9912.27486.1
    B10.651.507341.0012.53471.1
    B21.041.507080.9912.58472.8
    B30.671.508410.9912.48476.8
    B41.111.508141.0112.04492.2
    L10.791.508360.9912.80466.5
    L20.701.510011.0312.48476.8
    L30.651.511651.0612.60480.4
    L40.691.513321.0812.32484.4
    Table 1. Number of glass samples and their properties
    No.A1A2A3A4A5A6A7A8A9A10A11
    BL3.629.06.98.213.51.915.38.76.34.32.5
    S14.427.68.19.213.10.014.29.17.74.32.4
    S23.336.86.66.314.20.012.59.35.14.21.9
    S34.228.17.67.414.90.013.010.57.54.82.0
    S43.419.210.46.813.03.118.88.09.35.22.7
    B13.727.67.87.413.42.812.710.25.97.21.1
    B23.729.06.78.013.61.815.38.66.44.22.6
    B33.629.110.74.616.32.815.410.85.16.90.9
    B43.528.48.03.516.42.317.87.45.75.01.7
    L13.727.17.48.812.32.513.511.15.85.81.9
    L23.727.47.48.512.32.412.811.55.76.51.7
    L33.827.17.49.311.22.416.210.06.34.22.2
    L45.023.59.49.311.02.713.711.46.16.71.4
    Table 2. Integral area of Raman bands derived from the Raman curve fitting (A=Area)
    n2/(×10-13, esu)WL/(mg•cm-2)Tg/℃CTE/(×10-6, K-1)SiO2/wt%B2O3/wt%La2O3/wt%RO*/wt%R2O*/wt%Al2O3/wt%P2O5/wt%Obj
    1.0290.90486.912.182.162.810.9113.5910.7411.5859.170.99
    1.0230.92486.712.281.932.961.0813.6110.7711.6059.270.99
    1.0270.88487.012.261.893.041.2713.5910.7411.5859.150.98
    1.0240.94488.012.212.052.970.8913.6010.7511.5959.210.98
    1.0270.90487.412.222.192.951.0813.5710.7311.5659.090.98
    1.0270.93486.012.282.032.781.2113.6210.7711.6059.300.98
    Table 3. Compositions and properties of the glass predicted by C-S-P model
    SampleYb3+ (ICP)/(×1020, ions•cm-3)σemi/pm2Tg/℃Starksplitting
    PS02.400.50477639
    PS22.380.48441651
    PS52.460.50462769
    PS102.320.53503786
    PS202.170.57509814
    Table 4. Properties of PS glass
    Li-Yan ZHANG, Hong LI, Li-Li HU, Ya-Jie WANG. Structure Modeling of Genes in Glass: Composition-structure-property Approach[J]. Journal of Inorganic Materials, 2019, 34(8): 885
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