• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 3, 814 (2022)
Ying-ying LI1、*, Zhi-qing ZHANG1、1; *;, Xiao-hong WU2、2;, and Hsitien Shen Andy1、1; *;
Author Affiliations
  • 11. Gemmological Institute, China University of Geosciences (Wuhan), Wuhan 430074, China
  • 22. Technical Center for Industrial Product and Raw Material Inspection and Testing Shanghai Customs, Shanghai 200135, China
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    DOI: 10.3964/j.issn.1000-0593(2022)03-0814-07 Cite this Article
    Ying-ying LI, Zhi-qing ZHANG, Xiao-hong WU, Hsitien Shen Andy. Photoluminescence in Indonesian Fossil Resins[J]. Spectroscopy and Spectral Analysis, 2022, 42(3): 814 Copy Citation Text show less
    The blue appearance of IN-5 when under a strong white light. It was divided into three parts: white inclusions (Part Ⅰ), dark inclusions (Part Ⅱ) and basal body (Part Ⅲ)
    Fig. 1. The blue appearance of IN-5 when under a strong white light. It was divided into three parts: white inclusions (Part Ⅰ), dark inclusions (Part Ⅱ) and basal body (Part Ⅲ)
    Images of the inclusion details(a): The fluid-like white inclusions; (b), (c): The crumb-like white inclusions; (d): The flat-shaped inclusions with spongiform structures; (e): The fried-egg-like dark inclusions with white rims; (f): Cavity-like white inclusion with flower-like structure; (g): The isolated dark and white inclusions in the basal body; (h): Fluorescence of Part Ⅰ—Ⅲ in IN-3 under a 365 nm ultraviolet light; (i): Bright greenish-yellow phosphorescence from IN-4 fragment excited by a 365 nm ultraviolet light
    Fig. 2. Images of the inclusion details
    (a): The fluid-like white inclusions; (b), (c): The crumb-like white inclusions; (d): The flat-shaped inclusions with spongiform structures; (e): The fried-egg-like dark inclusions with white rims; (f): Cavity-like white inclusion with flower-like structure; (g): The isolated dark and white inclusions in the basal body; (h): Fluorescence of Part Ⅰ—Ⅲ in IN-3 under a 365 nm ultraviolet light; (i): Bright greenish-yellow phosphorescence from IN-4 fragment excited by a 365 nm ultraviolet light
    FTIR spectra of IN-3, IN-5, and IN-6
    Fig. 3. FTIR spectra of IN-3, IN-5, and IN-6
    3D fluorescent patterns of three parts from IN-5 sample[(a): Part Ⅰ; (b): Part Ⅱ; (c): Part Ⅲ] and bar graph of the ratio of the emission intensity at 446 and 388 nm (d)
    Fig. 4. 3D fluorescent patterns of three parts from IN-5 sample
    [(a): Part Ⅰ; (b): Part Ⅱ; (c): Part Ⅲ] and bar graph of the ratio of the emission intensity at 446 and 388 nm (d)
    Phosphorescence curves and the full width at half maximum (FWHM) in three parts. (a) IN-1 emits stronger phosphorescence by the duration of 365 nm excitation increasing; (b)—(f) Phosphorescence curves and the FWHM of three parts in IN-2—IN-6, respectively
    Fig. 5. Phosphorescence curves and the full width at half maximum (FWHM) in three parts. (a) IN-1 emits stronger phosphorescence by the duration of 365 nm excitation increasing; (b)—(f) Phosphorescence curves and the FWHM of three parts in IN-2—IN-6, respectively
    波长/nmτ1τ2R2
    IN-1 Part Ⅲ基底421
    537
    4.45
    18.13
    63.41
    129.78
    0.993
    0.998
    IN-2 Part Ⅰ白色包体4325.1557.600.979
    IN-2 Part Ⅲ基底54112.53110.480.991
    IN-3 Part Ⅰ白色包体437
    530
    4.85
    9.97
    45.26
    85.37
    0.984
    0.934
    IN-3 Part Ⅱ暗色包体53615.65105.590.993
    IN-3 Part Ⅲ基底519
    548
    10.73
    21.18
    131.46
    155.80
    0.996
    0.997
    IN-4 Part Ⅰ白色包体4325.0549.570.986
    IN-4 Part Ⅲ基底424
    548
    4.47
    19.53
    51.85
    132.83
    0.991
    0.996
    IN-5 Part Ⅰ白色包体4324.6244.820.990
    IN-5 Part Ⅱ暗色包体53610.5396.740.988
    IN-5 Part Ⅲ基底54113.03122.680.996
    IN-6 Part Ⅰ白色包体4164.8750.560.982
    IN-6 Part Ⅱ暗色包体53613.32109.310.996
    IN-6 Part Ⅲ基底430
    532
    5.43
    15.8
    61.01
    151.88
    0.988
    0.994
    Table 1. List of the calculated phosphorescence lifetimes of Parts Ⅰ to Ⅲ, and each R-squared (R2)
    Ying-ying LI, Zhi-qing ZHANG, Xiao-hong WU, Hsitien Shen Andy. Photoluminescence in Indonesian Fossil Resins[J]. Spectroscopy and Spectral Analysis, 2022, 42(3): 814
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