• Journal of Radiation Research and Radiation Processing
  • Vol. 42, Issue 1, 010204 (2024)
Zifang GUO1, Yang ZHANG2, Yifan LI1, Zijian LIN1, Chunyu LIU2, Peng LIN2, and Mingzhang LIN1、*
Author Affiliations
  • 1School of Nuclear Science and Technology, University of Science and Technology of China, Hefei 230026, China
  • 2China Nuclear Power Technology Research Institute Co., Ltd., Shenzhen 518028, China
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    DOI: 10.11889/j.1000-3436.2023-0088 Cite this Article
    Zifang GUO, Yang ZHANG, Yifan LI, Zijian LIN, Chunyu LIU, Peng LIN, Mingzhang LIN. γ-Radiolysis of the aqueous ammonia solution saturated by N2[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(1): 010204 Copy Citation Text show less
    Residual ammonia concentrations and pH values under different N2 pressures at 25˚C
    Fig. 1. Residual ammonia concentrations and pH values under different N2 pressures at 25˚C
    Concentrations of nitrogen oxides and H2 under different N2 pressures at 25 ℃
    Fig. 2. Concentrations of nitrogen oxides and H2 under different N2 pressures at 25 ℃
    Residual ammonia concentrations and pH values under different Vg/Vl ratios at 25 ℃
    Fig. 3. Residual ammonia concentrations and pH values under different Vg/Vl ratios at 25 ℃
    Concentrations of nitrogen oxides and H2 under different Vg/Vl ratios at 25 ℃
    Fig. 4. Concentrations of nitrogen oxides and H2 under different Vg/Vl ratios at 25 ℃
    Residual ammonia concentrations and pH values under different temperatures
    Fig. 5. Residual ammonia concentrations and pH values under different temperatures
    Concentrations of nitrogen oxides formed by the radiolysis of ammonia solution under different temperatures
    Fig. 6. Concentrations of nitrogen oxides formed by the radiolysis of ammonia solution under different temperatures
    (a) Initial ammonia concentration 30 mg/L, absorbed dose rate 0.5 Gy/s, absorbed dose 14.4 kGy, validation of the radiolysis model at different temperatures; (b) at 300 ℃, neutron 2 500 Gy/s, γ 1 500 Gy/s, residual ammonia concentration during the radiolysis process of aqueous ammonia solutions with different initial concentrations
    Fig. 7. (a) Initial ammonia concentration 30 mg/L, absorbed dose rate 0.5 Gy/s, absorbed dose 14.4 kGy, validation of the radiolysis model at different temperatures; (b) at 300 ℃, neutron 2 500 Gy/s, γ 1 500 Gy/s, residual ammonia concentration during the radiolysis process of aqueous ammonia solutions with different initial concentrations
    序号No.反应方程式 Reaction反应速率常数 Reaction rate constant
    1NH3 + •OH → •NH2 + H2O9.7×107
    2·NH2 + •H → NH31.0×1011
    3·NH2 + eaq- → NH3 + OH-1.0×1011
    4·NH2 + HO2• → NH3 + O21.0×1011
    5·NH2 + •OH → NH2OH9.5×109
    6·NH2 + H2O2 → •NHOH + H2O9.0×107
    7·NH2 + •NO → N2 + H2O1.0×109
    8·NHOH + •H → NH2OH1.0×109
    9·NHOH + eaq- → NH2OH + OH-1.0×1010
    10·NHOH + •NHOH → N2 + H2O + H2O1.0×107
    11·NHOH + HO2•→ NH2OH + O21.0×109
    12·NO + •OH → HNO22.0×1010
    13NH2OH + •OH → •NHOH + H2O9.5×109
    14NH2OH + eaq- → •NH2 + OH- + H2O9.2×108
    15HNO2 + •H → •NO + H2O4.5×108
    16HNO2 + NH2OH → N2O + H2O + H2O1.0×109
    17N2O + •H → N2 + •OH2.1×106
    18N2O + eaq- → N2 + •OH + OH-9.6×109
    19·NH2 + •NH2 → N2H42.2×109
    20NH3 + •H → NH4+ + eaq-6.7×105
    21NH4+ + eaq- → NH3 + •H1.5×106
    22NH4+ + OH- → NH3 + H2O3.3×1010
    23aNH3 + H2O → NH4+ + OH-9.7×103
    24·NH2 + O2 → •NO + H2O1.2×108
    25NH4+ + HO2- → NH3 + H2O21.0×1011
    26H+ + NH3 → NH4+ + H2O4.3×1010
    27aNH4+ + H2O → H+ + NH34.5×10-1
    28N2H4 + OH → •N2H3 + NH34.5×109
    29N2H4 + •NH2 → •N2H3 + NH31.2×107
    30·N2H3 + •N2H3 → N2 + NH3 + NH31.0×1010
    31·N2H3 + O2 → •N2H2 + HO2·3.8×108
    32·N2H4 + HO2•→ •N2H3 + H2O27.0×106
    33·N2H2 + H2O2 → N2 + H2O + H2O6.0×101
    34·N2H2 + •N2H2 → N2H4 + N22.0×104
    35N2H4 + •H → H2 + •N2H33.0×101
    36 aN2H4 + H2O → •NH2 + •NH2 + H2O1.8×10-6
    37 a·OH* + H2O → •OH + H2O1.0×106
    38·OH* + N2 → •NH + •NO1.0×1011
    39·NH + H2 → NH31.0×1011
    Table 1. Elementary reactions between nitrogen-containing species during the radiolysis of ammonia solutions at 25 oC
    Zifang GUO, Yang ZHANG, Yifan LI, Zijian LIN, Chunyu LIU, Peng LIN, Mingzhang LIN. γ-Radiolysis of the aqueous ammonia solution saturated by N2[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(1): 010204
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