• Journal of Inorganic Materials
  • Vol. 35, Issue 5, 541 (2020)
Fan WU1, Ziyan ZHAO1, Bangxin LI1, Fan DONG2, and Ying ZHOU1、*
Author Affiliations
  • 1The Center of New Energy Materials and Technology, School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China
  • 2Chongqing Key Laboratory Catalysis and New Environmental Materials, College of Environment and Resources, Chongqing Technology and Business University, Chongqing 40067, China
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    DOI: 10.15541/jim20190281 Cite this Article
    Fan WU, Ziyan ZHAO, Bangxin LI, Fan DONG, Ying ZHOU. Interfacial Oxygen Vacancy of Bi2O2CO3/PPy and its Visible-light Photocatalytic NO Oxidation Mechanism[J]. Journal of Inorganic Materials, 2020, 35(5): 541 Copy Citation Text show less
    XRD patterns of (a) BOC and BOC/PPy(0.75%), and XRD pattern of (b) PPy
    1. XRD patterns of (a) BOC and BOC/PPy(0.75%), and XRD pattern of (b) PPy
    (a) DRIFTS spectra of PPy, BOC and BOC/PPy(0.75%); (b) UV-Vis spectra and of BOC and BOC/PPy(0.75%) with insert showing the enlarged spectra from 350 nm to 800 nm
    2. (a) DRIFTS spectra of PPy, BOC and BOC/PPy(0.75%); (b) UV-Vis spectra and of BOC and BOC/PPy(0.75%) with insert showing the enlarged spectra from 350 nm to 800 nm
    SEM images of (a) BOC and (b) BOC/PPy(0.75%); HRTEM images of (c) BOC and (d) BOC/PPy(0.75%)
    3. SEM images of (a) BOC and (b) BOC/PPy(0.75%); HRTEM images of (c) BOC and (d) BOC/PPy(0.75%)
    XPS spectra of BOC and BOC/PPy(0.75%)
    4. XPS spectra of BOC and BOC/PPy(0.75%)
    ESR spectra of BOC and BOC/PPy(0.75%) in the darkness
    5. ESR spectra of BOC and BOC/PPy(0.75%) in the darkness
    (a) EIS measurements and (b) photocurrent of BOC and BOC/PPy(0.75%)
    6. (a) EIS measurements and (b) photocurrent of BOC and BOC/PPy(0.75%)
    NO oxidation of BOC and BOC/PPy(0.75%) composites under visible light irradiation (>420 nm)
    7. NO oxidation of BOC and BOC/PPy(0.75%) composites under visible light irradiation (>420 nm)
    Influence of influent gas relative humidity on the photocatalytic NO oxidation of BOC/PPy(0.75%)
    8. Influence of influent gas relative humidity on the photocatalytic NO oxidation of BOC/PPy(0.75%)
    In situ DRIFTS of (a) NO adsorption and (b) photocatalytic reaction during the visible light irradiation on BOC/PPy(0.75%)
    9. In situ DRIFTS of (a) NO adsorption and (b) photocatalytic reaction during the visible light irradiation on BOC/PPy(0.75%)
    ESR spectra of (a) •O2- and (b) •OH of BOC and BOC/PPy(0.75%)
    10. ESR spectra of (a) •O2- and (b) •OH of BOC and BOC/PPy(0.75%)
    Ultroviolet Photoelectron Spectrum of BOC
    11. Ultroviolet Photoelectron Spectrum of BOC
    Radical generation processes of BOC/PPy(0.75%)
    12. Radical generation processes of BOC/PPy(0.75%)
    Wavenumber/cm-1AssignmentRef.
    1262Monodentate nitrate[38]
    1248Bridge nitrate[39]
    1183Nitrite[40]
    1159NO-[40]
    1091Nitrite[41]
    1032, 1010Bidentate nitrate[38, 40]
    984Bridge nitrate[42]
    Table 1. Assignments of adsorption peaks in IR spectra during NO adsorption and photocatalytic oxidation
    Fan WU, Ziyan ZHAO, Bangxin LI, Fan DONG, Ying ZHOU. Interfacial Oxygen Vacancy of Bi2O2CO3/PPy and its Visible-light Photocatalytic NO Oxidation Mechanism[J]. Journal of Inorganic Materials, 2020, 35(5): 541
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