• Journal of Inorganic Materials
  • Vol. 36, Issue 5, 527 (2020)
Yanning ZHENG1,2, Junrong JI3, Xueling LIANG1, Zhengjie LAI1..., Qifan CHENG1 and Dankui LIAO1,2,*|Show fewer author(s)
Author Affiliations
  • 11. School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
  • 22. Guangxi Cooperative Innovation Centre for Calcium-based Materials (GCICCM), Guangxi Engineering Academy for Calcium Carbonate Industry, Guangxi University, Nanning 530004, China
  • 33. Guangxi Cooperative Innovation Centre for Calcium-based Materials (GCICCM), Chongzuo South Cement Co. LTD, Chongzuo 532201, China
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    DOI: 10.15541/jim20200396 Cite this Article
    Yanning ZHENG, Junrong JI, Xueling LIANG, Zhengjie LAI, Qifan CHENG, Dankui LIAO. Performance of Nitrogen-doped Hollow Carbon Spheres as Oxidase Mimic[J]. Journal of Inorganic Materials, 2020, 36(5): 527 Copy Citation Text show less
    Morphologies and element mappings of N-HCSs
    1. Morphologies and element mappings of N-HCSs
    SEM images of (a) N-HCS and (b) N-HCS-1, and TEM images of (c) CaCO3@PDA and (d) N-HCS
    2. SEM images of (a) N-HCS and (b) N-HCS-1, and TEM images of (c) CaCO3@PDA and (d) N-HCS
    (a) XPS full spectra of N-HCS and N-HCS-1; N1s spectra of (b) N-HCS and (c) N-HCS-1; (d) N species contents of N-HCS and N-HCS-1
    3. (a) XPS full spectra of N-HCS and N-HCS-1; N1s spectra of (b) N-HCS and (c) N-HCS-1; (d) N species contents of N-HCS and N-HCS-1
    (a) Nitrogen absorption-desorption isotherm curves of N-HCS and N-HCS-1, (b) HK model corresponding pore size distribution curves of N-HCS and N-HCS-1
    4. (a) Nitrogen absorption-desorption isotherm curves of N-HCS and N-HCS-1, (b) HK model corresponding pore size distribution curves of N-HCS and N-HCS-1
    (a) UV-Vis absorption spectra of different systems, and effects of (b) catalyst concentration, (c) pH and (d) temperature on the oxidase-like activity of N-HCSs
    5. (a) UV-Vis absorption spectra of different systems, and effects of (b) catalyst concentration, (c) pH and (d) temperature on the oxidase-like activity of N-HCSs
    Steady-state kinetic assay of N-HCS and N-HCS-1
    6. Steady-state kinetic assay of N-HCS and N-HCS-1
    (a) Absorption spectra of the solution containing TMB and N-HCS and N-HCS-1 under N2-saturated conditions, and effect of scavengers (b) IPA, (c) CAT and (d) SOD on the catalytic oxidation of TMB by the N-HCS and N-HCS-1
    7. (a) Absorption spectra of the solution containing TMB and N-HCS and N-HCS-1 under N2-saturated conditions, and effect of scavengers (b) IPA, (c) CAT and (d) SOD on the catalytic oxidation of TMB by the N-HCS and N-HCS-1
    (a) ESR spectra and (b) catalytic mechanism diagram for the oxidase-like activity of the N-HCSs
    8. (a) ESR spectra and (b) catalytic mechanism diagram for the oxidase-like activity of the N-HCSs
    SampleSpecfic suface/(m2•g-1)Vt/(cm3•g-1)Vm/(cm3•g-1)Sm/(m2•g-1)(Sm/St)/%
    LangmuirBET
    N-HCS685.6490.10.6510.109230.5145.49
    N-HCS-1730.0518.40.7320.111228.1644.01
    Table 1. Pore structure parameters of N-HCS and N-HCS-1
    CatalystSubstrateKm/(mmol•L-1)Vmax/(×10-8, mol•L-1•s-1)Ref.
    N-PCSTMB0.0955.20[4]
    His@AuNCsTMB0.0416.21[31]
    Pt Au DNPsTMB0.222.82[32]
    Acr+-MesTMB0.1292.68[33]
    N-HCSTMB0.10494.69This work
    N-HCS-1TMB0.08255.98This work
    Table 2. Comparison of the Km and Vmax between N-HCSs and other oxidase-like
    Yanning ZHENG, Junrong JI, Xueling LIANG, Zhengjie LAI, Qifan CHENG, Dankui LIAO. Performance of Nitrogen-doped Hollow Carbon Spheres as Oxidase Mimic[J]. Journal of Inorganic Materials, 2020, 36(5): 527
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