In this research, the highly efficient external cavity feedback technology based on volume Bragg grating (VBG) is studied. By using the structure of a fast axis collimating lens, the beam transformation system, a slow axis collimating lens, and VBG, the divergence angle of the fast and slow axes of the diode laser incident on the VBG is reduced effectively, and the feedback efficiency of the external cavity is improved. Combined with beam combining technology, fiber coupling technology, and precision temperature control technology, a high-power and narrow-linewidth diode laser pump source of kilowatt class is realized for alkali metal vapor laser pumping. The core diameter of the optical fiber is 1000 µm, the numerical aperture is 0.22, the output power from the fiber is 1013 W, the fiber coupling efficiency exceeds 89%, and the external cavity efficiency exceeds 91%. The central wavelength is 852.052 nm (in air), which is tunable from 851.956 nm to 852.152 nm, and the spectral linewidth is 0.167 nm. Research results can be used for cesium alkali metal vapor laser pumping.