• Opto-Electronic Science
  • Vol. 1, Issue 11, 220014 (2022)
Dezhi Tan*, Ke Sun, Zengling Li, Beibei Xu, and Jianrong Qiu**
Author Affiliations
  • [in Chinese]
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    DOI: 10.29026/oes.2022.220014 Cite this Article
    Dezhi Tan, Ke Sun, Zengling Li, Beibei Xu, Jianrong Qiu. Photo-processing of perovskites: current research status and challenges[J]. Opto-Electronic Science, 2022, 1(11): 220014 Copy Citation Text show less
    Schematic overview of the current research on the photo-processing of perovskites.
    Fig. 1. Schematic overview of the current research on the photo-processing of perovskites.
    (a) Optical absorption spectra (dash curves) and PL spectra (solid curves) of CsPbX3 perovskite NCs with various halide compositions. SEM images of perovskite films produced by (b) thermal annealing, (c) nanosecond laser writing, and (d) nanosecond laser writing with addition of carbon quantum dots. Scale bar, 500 nm. (e) Optical images and PL mapping of a CsPbBr3 perovskite array during the erasing–recovery processes excited by UV light. Scale bars: 100 μm. Figure reproduced with permission from: (a) ref.43, Elsevier; (b–d) ref.69, John Wiley and Sons; ref.75, Springer Nature.
    Fig. 2. (a) Optical absorption spectra (dash curves) and PL spectra (solid curves) of CsPbX3 perovskite NCs with various halide compositions. SEM images of perovskite films produced by (b) thermal annealing, (c) nanosecond laser writing, and (d) nanosecond laser writing with addition of carbon quantum dots. Scale bar, 500 nm. (e) Optical images and PL mapping of a CsPbBr3 perovskite array during the erasing–recovery processes excited by UV light. Scale bars: 100 μm. Figure reproduced with permission from: (a) ref.43, Elsevier; (b–d) ref.69, John Wiley and Sons; ref.75, Springer Nature.
    (a) Mechanism of UV light induced patterning of perovskite NCs. (b) Patterning of various perovskite NCs. SEM images of the CsPbBr3 microlenses (c) and surface gratings (d). Figure reproduced with permission from: (a, b) ref.42, under a Creative Commons AttributionLicense 4.0; (c, d) ref.53, John Wiley and Sons.
    Fig. 3. (a) Mechanism of UV light induced patterning of perovskite NCs. (b) Patterning of various perovskite NCs. SEM images of the CsPbBr3 microlenses (c) and surface gratings (d). Figure reproduced with permission from: (a, b) ref.42, under a Creative Commons AttributionLicense 4.0; (c, d) ref.53, John Wiley and Sons.
    (a) Schematic of ultrafast laser–induced liquid nanophase separation and generation of CsPb(Br1−xIx)3 perovskite NCs. (b) PL mappings and spectra of CsPb(Br1−xIx)3 perovskite NCs. Scale bar: 10 μm. (c) PL mappings and spectra of perovskite NCs in the Cl−-Br−-I− codoped glass. Figure reproduced with permission from ref.33, American Association for the Advancement of Science.
    Fig. 4. (a) Schematic of ultrafast laser–induced liquid nanophase separation and generation of CsPb(Br1−xIx)3 perovskite NCs. (b) PL mappings and spectra of CsPb(Br1−xIx)3 perovskite NCs. Scale bar: 10 μm. (c) PL mappings and spectra of perovskite NCs in the Cl-Br-I codoped glass. Figure reproduced with permission from ref.33, American Association for the Advancement of Science.
    (a) Schematic diagram of laser induced phase transition from CsPb2Br5 to CsPbBr3 inside a CsPb2Br5 microplatelet. (b) PL spectra of CsPbBr3 generated by laser irradiation with various times (65 s per time). (c) The integral PL intensity as a function of the excitation intensity. (d) Schematic diagram of the strong cavity mode spontaneous emission of the laser-written CsPbBr3 in the CsPb2Br5 microplatelet. Figure reproduced with permission from ref.97, American Chemical Society.
    Fig. 5. (a) Schematic diagram of laser induced phase transition from CsPb2Br5 to CsPbBr3 inside a CsPb2Br5 microplatelet. (b) PL spectra of CsPbBr3 generated by laser irradiation with various times (65 s per time). (c) The integral PL intensity as a function of the excitation intensity. (d) Schematic diagram of the strong cavity mode spontaneous emission of the laser-written CsPbBr3 in the CsPb2Br5 microplatelet. Figure reproduced with permission from ref.97, American Chemical Society.
    (a–d) Light induced shape evolution of CsPbBr3 nanostructures with an increase in irradiation. (e) Schematic of light-induced ligand removal mechanism and assembly of CsPbBr3 nanocubes. (f) High-angle annular dark-field scanning transmission electron microscopy image of assembled nanostructures. (g) Cubic and (h) spindle perovskite superlattices. Figure reproduced with permission from: ref.102, American Chemical Society; ref.105, John Wiley and Sons.
    Fig. 6. (ad) Light induced shape evolution of CsPbBr3 nanostructures with an increase in irradiation. (e) Schematic of light-induced ligand removal mechanism and assembly of CsPbBr3 nanocubes. (f) High-angle annular dark-field scanning transmission electron microscopy image of assembled nanostructures. (g) Cubic and (h) spindle perovskite superlattices. Figure reproduced with permission from: ref.102, American Chemical Society; ref.105, John Wiley and Sons.
    (a) SEM images of a CsPbBr3 nanowire with laser-patterned nanogratings. (b) A schematically nanowire laser with vertically emitting light from its upper face. (c) PL image of the nanowire laser. (d) Photodetector arrays based on laser-written perovskites. Figure reproduced with permission from: (a−c) ref.51, American Chemical Society; ref.70, John Wiley and Sons.
    Fig. 7. (a) SEM images of a CsPbBr3 nanowire with laser-patterned nanogratings. (b) A schematically nanowire laser with vertically emitting light from its upper face. (c) PL image of the nanowire laser. (d) Photodetector arrays based on laser-written perovskites. Figure reproduced with permission from: (a−c) ref.51, American Chemical Society; ref.70, John Wiley and Sons.
    (a) Schematic illustration of micro-LED devices with laser-written perovskite NCs inside a glass. (b) A dynamic holographic display. (c) PL mapping of the 3D perovskite dots in glass. (d) PL mapping of a perovskite pattern with tunable emission wavelength. Figure reproduced with permission from ref.33, American Association for the Advancement of Science.
    Fig. 8. (a) Schematic illustration of micro-LED devices with laser-written perovskite NCs inside a glass. (b) A dynamic holographic display. (c) PL mapping of the 3D perovskite dots in glass. (d) PL mapping of a perovskite pattern with tunable emission wavelength. Figure reproduced with permission from ref.33, American Association for the Advancement of Science.
    Dezhi Tan, Ke Sun, Zengling Li, Beibei Xu, Jianrong Qiu. Photo-processing of perovskites: current research status and challenges[J]. Opto-Electronic Science, 2022, 1(11): 220014
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