The present study is to investigate the temporal variation patterns through the dataset of spectral reflectance of maize leaf using a fitting method. In the field experiment, 1 261 pieces of spectral reflectance of maize leaves at different leaf positions were measured every day during its life cycle. After signal/noise analysis, the visible and near infrared (VNIR) band (400～960 nm) was selected in this study. The spectral reflectance was fitted using a spectral scatter diagram (SSD) method. Seven fitting coefficients were employed to denote the temporal variation patterns of maize leaf, which can also be fitted by bi-variate quadratic functions. The comparison of the fitted results with the original measurement data shows that the fitting results are reasonably good, where for 98.7% leaves r is larger than 0.99, and for 80.9% leaves RMSE is less than 0.001 5. All the fitted spectral reflectance is compared with the original measurement data, where r is 0.997 8, and RMSE is 0.0105. The results show that this method is particularly suitable for presenting the temporal variation patterns of the spectral reflectance of maize leaves.