• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 1, 236 (2022)
Zhi-jun YANG*, Meng-ai MAO1;, Yi-cong HUANG1;, and Jia-wei ZHANG1;
Author Affiliations
  • 1. School of Earth Sciences and Engineering, Sun Yat-sen University, Guangzhou 510275, China
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    DOI: 10.3964/j.issn.1000-0593(2022)01-0236-07 Cite this Article
    Zhi-jun YANG, Meng-ai MAO, Yi-cong HUANG, Jia-wei ZHANG. Study on the Surface Morphology and Its Vibrational Spectra of Diamond From the Western Yangtze Craton[J]. Spectroscopy and Spectral Analysis, 2022, 42(1): 236 Copy Citation Text show less
    Surface morphology of diamonds from the Western Yangtze craton(a): Triangular growth lamella; (b): Shield sheet; (c): Serrated grwoth pattern; (d): Peak cluster triangular hill;(e): Spiral growth pattern; (f): Inverted triangle pit; (g): Hexagon pit; (h): Quadrilateral pit;(i): Closed halo; (j): Fascicular halo; (k): Drop mound; (l): Small melting pit;(m): Erosion ditch; (n): Erosion channel; (o): Plastic deformation slip line; (p): Imbricate etch figure;(q): Collision trace; (r): Scratch
    Fig. 1. Surface morphology of diamonds from the Western Yangtze craton
    (a): Triangular growth lamella; (b): Shield sheet; (c): Serrated grwoth pattern; (d): Peak cluster triangular hill;(e): Spiral growth pattern; (f): Inverted triangle pit; (g): Hexagon pit; (h): Quadrilateral pit;(i): Closed halo; (j): Fascicular halo; (k): Drop mound; (l): Small melting pit;(m): Erosion ditch; (n): Erosion channel; (o): Plastic deformation slip line; (p): Imbricate etch figure;(q): Collision trace; (r): Scratch
    Micro-FTIR spectra of the diamonds with different surface morphology(a): Triangular lamella 1(001)-a; (b): Shield sheet 17(024)-a; (c): Shield sheet 45(305)-a; (d): Serrated growth pattern 15(021)-a;(e): Peak cluster triangular hill 6(007)-b; (f): Spiral growth pattern 15(021)-b; (g): Inverted triangle pit 16(023)-c;(h): Hexagon pit 16(023)-b; (i): Hexagon pit 16(023)-a; (j): Quadrilateral pit 6(007)-a: (k): Halo 13(017)-a;(l): Drop mound 35(204)-b;(m): Melting pit 41(301)-a; (n): Slip line 18(025)-a; (o): Imbricate etch figure 3(004)-a;(p): Imbricate etch figure 35(204)-a; (q): Triangular conical hill 24(056)-a
    Fig. 2. Micro-FTIR spectra of the diamonds with different surface morphology
    (a): Triangular lamella 1(001)-a; (b): Shield sheet 17(024)-a; (c): Shield sheet 45(305)-a; (d): Serrated growth pattern 15(021)-a;(e): Peak cluster triangular hill 6(007)-b; (f): Spiral growth pattern 15(021)-b; (g): Inverted triangle pit 16(023)-c;(h): Hexagon pit 16(023)-b; (i): Hexagon pit 16(023)-a; (j): Quadrilateral pit 6(007)-a: (k): Halo 13(017)-a;(l): Drop mound 35(204)-b;(m): Melting pit 41(301)-a; (n): Slip line 18(025)-a; (o): Imbricate etch figure 3(004)-a;(p): Imbricate etch figure 35(204)-a; (q): Triangular conical hill 24(056)-a
    Conversion rate change curve of total nitrogen (a) and B-center nitrogen (b) in diamonds with different surface morphology
    Fig. 3. Conversion rate change curve of total nitrogen (a) and B-center nitrogen (b) in diamonds with different surface morphology
    Related concentration of sp3(C—H) (a) and its relationship with B-center nitrogen (b) in dianonds with different surface morphology
    Fig. 4. Related concentration of sp3(C—H) (a) and its relationship with B-center nitrogen (b) in dianonds with different surface morphology
    Variation curve of FWHM mean value of Raman eigenpeak of diamonds with different surface morphology
    Fig. 5. Variation curve of FWHM mean value of Raman eigenpeak of diamonds with different surface morphology
    表面形貌样品编号有效光径
    d/cm
    氮含量/(μg·g-1)NB/NT
    (B%)
    氮的存在形式
    NANBNT
    三角形生长片层1(001)-a0.203 881.3425.17106.5123.63片晶N NA NB
    螺旋生长纹15(021)-b0.060 0491.807.05498.8631.50片晶N NA NB
    盾形薄片45(305)-a0.055 6527.496.55534.0432.40片晶N NA NB
    盾形薄片17(024)-a0.057 2513.27239.13752.4031.78片晶N NA NB
    锯齿状熔蚀边缘15(021)-a0.087 1353.65101.81455.4722.35片晶N NA NB
    峰丛状生长丘6(007)-b0.187 1149.1822.01171.1940.70片晶N NA NB
    倒三角凹坑16(023)-c0.143 2222.810222.810片晶N NA
    六边形凹坑16(023)-a0.119 5277.960277.960片晶N NA
    六边形凹坑16(023)-b0.121 7267.150267.150片晶N NA
    四边形凹坑6(007)-a0.166 6157.7919.60177.3841.27片晶N NA NB
    三角锥状丘24(056)-a0.206 934.4424.3458.7732.88片晶N NA NB
    滴状丘35(204)-b0.208 160.4724.4884.9555.58片晶N NA NB
    滑移线18(025)-a0.210 981.39081.390NA
    晕线13(017)-a0.194 6022.9022.90100.00NB
    熔蚀坑41(301)-a0.090 1293.5410.60304.1447.94片晶N NA NB
    叠瓦状3(004)-a0.096 9341.590341.590片晶N NA
    叠瓦状35(204)-a0.211078.7924.82103.6152.73片晶N NA NB
    Table 1. Concentration of A-center, B-center and total nitrogen in diamonds with different surface morphology
    表面形貌、 样品编号有效光径
    d/cm
    sp2(C—H)sp3(C—H)
    A3 107A/dA2 850A/dA2 920A/d(A/d)
    三角形生长片层1(001)-a0.203 80.1120.5490.0820.4030.1190.5840.987
    螺旋生长纹15(021)-b0.060 00.0821.37400000.000
    盾形薄片45(305)-a0.055 60.0270.6700.0140.3570.0200.4880.846
    盾形薄片17(024)-a0.057 20.0250.4340.0110.2000.0180.3200.520
    锯齿状边缘熔蚀15(021)-a0.087 10.0320.367000.0330.3840.384
    峰丛状生长丘6(007)-b0.187 10.2411.286000.1730.9240.924
    倒三角凹坑16(023)-c0.143 2000.0130.0910.0250.1770.267
    六边形凹坑16(023)-a0.119 5000.0090.0740.0190.1600.235
    六边形凹坑16(023)-b0.121 7000.0160.1340.0310.2540.388
    四边形凹坑6(007)-a0.166 60.3672.2050.3181.9100.3251.9543.863
    三角锥状丘24(056)-a0.206 90.1520.7350.0610.2930.0840.4060.699
    滴状丘35(204)-b0.208 10.2611.2550.0380.1830.0630.3010.484
    滑移线18(025)-a0.210 9000.0440.2090.0680.3220.531
    晕线13(017)-a0.194 60.2261.1590.1380.7110.2121.0891.800
    熔蚀坑41(301)-a0.090 10.3123.4600.2612.9030.2843.1496.052
    叠瓦状3(004)-a0.096 9000.0120.1220.0210.2200.342
    叠瓦状35(204)-a0.211 00.2391.131000.0240.1120.112
    Table 2. Concentration of hydrogen in diamonds with different surface morphology
    表面形貌拉曼位移
    /cm-1
    半高宽
    /cm-1
    积分面积
    /(a.u)
    三角形生长片层1 329.7
    1 329.6
    7.356 6
    5.415 8
    281 935.9
    783 430.6
    螺旋生长纹1 329.85.467 81 166 337.2
    盾形薄片1 329.4
    1 329.7
    5.254 9
    5.214 2
    1 096 576.4
    881 288.7
    锯齿状熔蚀边缘1 329.6
    1 329.7
    5.442 4
    5.318 6
    808 815.1
    2 201 656.7
    峰丛状三角形生长丘1 329.95.571 01 780 502.8
    倒三角形凹坑1 329.3
    1 329.1
    5.551 6
    5.473 2
    864 060.1
    1 047 242.0
    六边形凹坑1 329.6
    1 329.9
    1 330.2
    5.721 9
    5.508 7
    5.410 2
    973 113.3
    938 316.5
    948 774.1
    四边形凹坑1 329.95.482 2739 825.1
    三角锥状丘1 330.65.156 81 345 742.4
    滴状丘1 329.55.586 811 774 582.0
    滑移线1 329.8
    1 329.4
    5.497 1
    5.270 1
    1 667 486.9
    1 020 489.3
    晕线1 329.85.184 11 890 941.2
    熔蚀沟1 330.15.275 8601 549.0
    熔蚀坑1 329.75.595 91 395 854.2
    Table 3. FWHM value and integral area of ~1 332.5 cm-1 Raman shift of diamonds with different surface morphology
    Zhi-jun YANG, Meng-ai MAO, Yi-cong HUANG, Jia-wei ZHANG. Study on the Surface Morphology and Its Vibrational Spectra of Diamond From the Western Yangtze Craton[J]. Spectroscopy and Spectral Analysis, 2022, 42(1): 236
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