• Laser & Optoelectronics Progress
  • Vol. 59, Issue 5, 0530005 (2022)
Yekun Liu1、1、">, Xiaojian Hao1、*, Yanwei Yang1、1、2、2、">">, and Peng Sun1、1、">
Author Affiliations
  • 1Science and Technology on Electronic Test and Measurement Laboratory, North University of China, Taiyuan , Shanxi 030051, China
  • 2Department of Physics, Luliang University, Lüliang, Shanxi 033000, China
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    DOI: 10.3788/LOP202259.0530005 Cite this Article Set citation alerts
    Yekun Liu, Xiaojian Hao, Yanwei Yang, Peng Sun. Analysis of Ba Content in Soil Based on Cavity Confinement LIBS Combined with Multivariate Regression[J]. Laser & Optoelectronics Progress, 2022, 59(5): 0530005 Copy Citation Text show less
    Cavity confinement LIBS experimental device diagram
    Fig. 1. Cavity confinement LIBS experimental device diagram
    Comparison diagram of Ba element spectra under traditional LIBS and CC-LIBS
    Fig. 2. Comparison diagram of Ba element spectra under traditional LIBS and CC-LIBS
    Spectral intensity of Ba Ⅱ 495.709 nm change with delay time under two LIBS conditions
    Fig. 3. Spectral intensity of Ba Ⅱ 495.709 nm change with delay time under two LIBS conditions
    SNR of Ba element under different conditions
    Fig. 4. SNR of Ba element under different conditions
    Calibration curves of Ba element by spectral line intensity integration method. (a) LIBS; (b) CC-LIBS
    Fig. 5. Calibration curves of Ba element by spectral line intensity integration method. (a) LIBS; (b) CC-LIBS
    Cumulative contribution rate of principal components
    Fig. 6. Cumulative contribution rate of principal components
    Calibration curves of Ba element with multivariate analysis method. (a) PCR; (b) ANN
    Fig. 7. Calibration curves of Ba element with multivariate analysis method. (a) PCR; (b) ANN
    Sample numberContent of Ba element /(mg·kg-1
    11100
    2750
    3450
    4800
    5500
    6400
    7350
    8200
    9160
    Table 1. Contents of Ba element in soil samples
    MethodsSample numberReal Ba contents

    Predicted

    Ba contents

    Rc2Relative Ba error /%Mean relative error /%

    Spectral line

    intensity

    integral

    4800990.300.6323.7847.52
    6400595.7748.94
    8200339.6969.85

    CC-LIBS and

    spectral line intensity integral

    4800923.460.8415.4323.44
    6400485.0921.27
    8200267.2433.62
    Table 2. Prediction results of Ba element content in soil samples by spectral line integration method
    CodintionδLOD /(mg·kg-1
    Traditional LIBS5.00664.73
    CC-LIBS9.84538.76
    Table 3. LOD of Ba element in soil samples
    MethodSample numberReal Ba contents

    Predicted

    Ba contents

    Rc2Relative Ba error /%Rp2Mean Relative error /%
    CC-LIBS+PCR4800819.410.9412.420.7349.93
    6400432.848.21
    8200161.6719.16
    CC-LIBS+ANN4800790.370.9991.200.9495.35
    6400373.116.72
    8200216.318.15
    Table 4. Prediction results of Ba element content in soil samples by multivariate analysis method
    Yekun Liu, Xiaojian Hao, Yanwei Yang, Peng Sun. Analysis of Ba Content in Soil Based on Cavity Confinement LIBS Combined with Multivariate Regression[J]. Laser & Optoelectronics Progress, 2022, 59(5): 0530005
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