• Journal of Inorganic Materials
  • Vol. 35, Issue 5, 511 (2020)
Hanxiang JIA1、2, Xun CAO1、*, and Pingshi JIN1
Author Affiliations
  • 1State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22.Chinese Academy of Sciences, Beijing 100049, China
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    DOI: 10.15541/jim20190305 Cite this Article
    Hanxiang JIA, Xun CAO, Pingshi JIN. Advances in Inorganic All-solid-state Electrochromic Materials and Devices[J]. Journal of Inorganic Materials, 2020, 35(5): 511 Copy Citation Text show less
    Schematic diagram of chromogenic system
    1. Schematic diagram of chromogenic system
    Schematic diagram (a) and photographs (b-e) of flexible electrochromic device of Ag/W18O49 nanowire co-assemble[17]
    2. Schematic diagram (a) and photographs (b-e) of flexible electrochromic device of Ag/W18O49 nanowire co-assemble[17]
    Schematic illustrations of functioning mechanisms for the bi-functional device[18]
    3. Schematic illustrations of functioning mechanisms for the bi-functional device[18]
    Performance index of the functional layers of inorganic all-solid-state electrochromic device
    4. Performance index of the functional layers of inorganic all-solid-state electrochromic device
    Schematic diagram of typical electrochromic device structure[10]
    5. Schematic diagram of typical electrochromic device structure[10]
    The key performance evaluation index of typical electrochromic device
    6. The key performance evaluation index of typical electrochromic device
    Schematic illustration of the preparation for electrochromic electrodes with and without a graphene interface layer[31]
    7. Schematic illustration of the preparation for electrochromic electrodes with and without a graphene interface layer[31]
    Pictures of gel films on FTO glass[32]
    8. Pictures of gel films on FTO glass[32]
    Schematic illustration for the formation of Co3O4 macro- bowl array films[33]
    9. Schematic illustration for the formation of Co3O4 macro- bowl array films[33]
    Synthesis of Nb2O5 thin films grown by single source precursor CVD[34]
    10. Synthesis of Nb2O5 thin films grown by single source precursor CVD[34]
    Ag/W18O49 nanowire co-assembles prepared by L-B technique[17]
    11. Ag/W18O49 nanowire co-assembles prepared by L-B technique[17]
    Schematic diagram of the fabrication process of the hybrid electrochromic electrode based on self-forming crackle pattern technology[35]
    12. Schematic diagram of the fabrication process of the hybrid electrochromic electrode based on self-forming crackle pattern technology[35]
    Ag grid/PEDOT hybrid flexible eletrode film[36]
    13. Ag grid/PEDOT hybrid flexible eletrode film[36]
    Scheme of a new ESS window device system (a) and schematic for the device preparation process (b)[16]
    14. Scheme of a new ESS window device system (a) and schematic for the device preparation process (b)[16]
    Transmittance and optical modulation changes of the WO3 on the silver grid/PEDOT:PSS hybrid film in the bleached and colored state[36]
    15. Transmittance and optical modulation changes of the WO3 on the silver grid/PEDOT:PSS hybrid film in the bleached and colored state[36]
    SEM cross-section image of ECD-fresh: Glass/ITO/ WO3/LiTaO3/NiO/ITO[52]
    16. SEM cross-section image of ECD-fresh: Glass/ITO/ WO3/LiTaO3/NiO/ITO[52]
    SEM cross-sectional images (a-b) of ECD-1 and ECD-2 with and without the embedment of Ta2O5 layers[53]
    17. SEM cross-sectional images (a-b) of ECD-1 and ECD-2 with and without the embedment of Ta2O5 layers[53]
    Electrochromic response of W18O49 nanowires under electrochemical insertion from one of the three different ions: Li+, Na+, and Al3+ in organic polycarbonate (PC) solvent using ClO4- as counter ion under ambient conditions[54]
    18. Electrochromic response of W18O49 nanowires under electrochemical insertion from one of the three different ions: Li+, Na+, and Al3+ in organic polycarbonate (PC) solvent using ClO4- as counter ion under ambient conditions[54]
    Electrochromic performance of WO3 films under various operations[58]
    19. Electrochromic performance of WO3 films under various operations[58]
    Electrochromic properties of NiO nanoparticles film with seed layer on ITO glass[61]
    20. Electrochromic properties of NiO nanoparticles film with seed layer on ITO glass[61]
    LixNiOy all-solid-state ECDs based on gradient Li+ distribution and its performance
    21. LixNiOy all-solid-state ECDs based on gradient Li+ distribution and its performance
    Schematic representation for the LBL fabrication of the multilayered (LDH/PB)n electrochromic film[63,64]
    22. Schematic representation for the LBL fabrication of the multilayered (LDH/PB)n electrochromic film[63,64]
    All-solid-state electrochromic devices developed by our research group
    23. All-solid-state electrochromic devices developed by our research group
    CategoryEC LayerPreparation method
    Cathod colorationWO3Magnetron sputtering[23], vacuum evaporation, Sol-Gel
    MoO3Magnetron sputtering[24], vacuum evaporation[25]
    Nb2O5Anodic oxidation[26]
    TiO2Hydrothermal[27]
    Anode coloringNiOxMagnetron sputtering
    IrO2Anodic oxidation[28]
    CoO2Hydrothermal[29]
    Prussian blueElectrochemical deposition[30]
    Table 1. Electrochromic materials and their deposition methods
    Hanxiang JIA, Xun CAO, Pingshi JIN. Advances in Inorganic All-solid-state Electrochromic Materials and Devices[J]. Journal of Inorganic Materials, 2020, 35(5): 511
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