• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 12, 3957 (2021)
Shuang-cheng JIANG1、*, Dan-yang FAN2、2;, Yue LIU2、2;, Jia-bin WANG3、3;, and Hai-xia LÜ2、2; *;
Author Affiliations
  • 11. Fisheries Research Institute of Fujian, Xiamen 361013, China
  • 22. College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • 33. College of Biological Science and Engineering, Fuzhou University, Fuzhou 350108, China
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    DOI: 10.3964/j.issn.1000-0593(2021)12-3957-06 Cite this Article
    Shuang-cheng JIANG, Dan-yang FAN, Yue LIU, Jia-bin WANG, Hai-xia LÜ. Modification of Ternary Layered Hydroxide and Removing for Orange Ⅱ With Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2021, 41(12): 3957 Copy Citation Text show less
    FTIR spectra
    Fig. 1. FTIR spectra
    The UV-Vis of (a) PA-LDH and (b) PA-LDO after adsorption under different time; (c) Influence of adsorption time on the extraction
    Fig. 2. The UV-Vis of (a) PA-LDH and (b) PA-LDO after adsorption under different time; (c) Influence of adsorption time on the extraction
    Influence of initial concentration on adsorption capacity
    Fig. 3. Influence of initial concentration on adsorption capacity
    (a) Pseudo-first-order kinetics; (b) Pseudo-second-order kineticsfor removing Orange Ⅱ by PA-LDH and PA-LDO
    Fig. 4. (a) Pseudo-first-order kinetics; (b) Pseudo-second-order kineticsfor removing Orange Ⅱ by PA-LDH and PA-LDO
    Adsorption isotherm of removing Orange Ⅱby PA-LDH and PA-LDOpH 7.0, 5 mg of PA-LDH, 5 mg of PA-LDO, 10 mL of Orange Ⅱ solution and 14 h of contact time
    Fig. 5. Adsorption isotherm of removing Orange Ⅱby PA-LDH and PA-LDO
    pH 7.0, 5 mg of PA-LDH, 5 mg of PA-LDO, 10 mL of Orange Ⅱ solution and 14 h of contact time
    AdsorbentsBET surface
    /(m2·g-1)
    Pore volume
    /(cm3·g-1)
    Average pore
    diameter/nm
    LDH13.592 50.008 324.3711
    PA-LDH15.934 10.011 328.483 8
    LDO90.712 40.175 077.171 5
    PA-LDO119.401 00.302 3101.270 5
    Table 1. Textual properties of different materials
    吸附剂Qmax/(mg·g-1)参考文献
    SA350[10]
    AC404[11]
    HT500328.94[12]
    NH2-MCM-41278.38[13]
    SBG30.5[14]
    AC-2389[15]
    PA-LDH561.322本工作
    PA-LDO1 401.639本工作
    Table 2. Qmax of different adsorbents on Orange Ⅱ
    样品Qexp/
    (mg·g-1)
    准一级动力学方程准二级动力学方程
    R2Qcal/
    (mg·g-1)
    k1/
    min-1
    R2Qcal/
    (mg·g-1)
    k2×104/
    [g·(mg·min)-1]
    PA-LDH150.9910.980 2119.6770.004 50.998 4169.4920.623
    PA-LDO181.4950.977123.2730.004 40.998192.3080.775
    Table 3. Parameters of kinetic models for orange Ⅱ adsorption
    吸附剂Qexp/(mg·g-1)Langmuir模型Freundlich模型
    Qcal/(mg·g-1)B/(L·mg-1)R2nKR2
    PA-LDH561.322588.2350.0180.997 82.50751.7130.921 4
    PA-LDO1 401.6391 428.5710.2410.998 53.4404.1100.842 6
    Table 4. Adsorption isotherm parameters
    吸附剂ΔH/(kJ·mol-1)ΔS/[J·(mol·K)-1]ΔG/(kJ·mol-1)
    293 K303 K313 K
    PA-LDH4.83222.476-1.754-1.979-2.203
    PA-LDO99.092371.06-9.628-10.252-17.050
    Table 5. Thermodynamic parameters
    Shuang-cheng JIANG, Dan-yang FAN, Yue LIU, Jia-bin WANG, Hai-xia LÜ. Modification of Ternary Layered Hydroxide and Removing for Orange Ⅱ With Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2021, 41(12): 3957
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