1. XRD patterns of SAPO-34 synthesized with different types of seeds
2. SEM images of samples in the presence of various types of seeds (a) SP34; (b) SP34-RS; (c) SP34-AS0.1; (d) SP34-AS0.01; (e) SP34-AS0.001; (f) SP34-AS0.0001
3. N2 adsorption/desorption isotherms of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001)
4. NH3-TPD profiles of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001)
5. Methanol conversion over SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001) catalysts with time-on-stream in the MTO reaction
S1. Relative crystallinity of SAPO-34 synthesized in the presence of various kinds of seed crystals
S2. Pore size distribution of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001 mol/L)
S3. Deconvolution of NH3-TPD curves of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001 mol/L)
Sample | Textual properties | Acid amount c | Lifetime/min |
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SBET/(m2·g-1) | Smic/(m2·g-1) | Sext/(m2·g-1) | Vmica/(cm3·g-1) | Vmesob/(cm3·g-1) | Weak | Mediumand strong | Total |
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SP34 | 250 | 68 | 182 | 0.029 | 0.342 | 2.77 | 5.37 | 8.14 | 40 | SP34-RS | 316 | 291 | 24 | 0.136 | 0.068 | 0.86 | 2.05 | 2.91 | 100 | SP34-AS0.1 | 547 | 530 | 17 | 0.247 | 0.057 | 0.97 | 2.55 | 3.52 | 480 | SP34-AS0.01 | 552 | 532 | 20 | 0.249 | 0.056 | 1.42 | 3.41 | 4.83 | 300 | SP34-AS0.001 | 568 | 553 | 15 | 0.254 | 0.052 | 0.85 | 2.20 | 3.05 | 420 | SP34-AS0.0001 | 568 | 547 | 21 | 0.256 | 0.049 | 1.27 | 3.15 | 4.42 | 330 |
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Table 1. Textural properties, acid amount and catalytic lifetime of different samples in MTO reaction