• Journal of Inorganic Materials
  • Vol. 36, Issue 1, 101 (2021)
Dongqiang ZHANG, Huihui LU, Na SU, Guixian LI, Dong JI, and Xinhong ZHAO*
DOI: 10.15541/jim20200059 Cite this Article
Dongqiang ZHANG, Huihui LU, Na SU, Guixian LI, Dong JI, Xinhong ZHAO. Modulation of SAPO-34 Property with Activated Seeds and Its Enhanced Lifetime in Methanol to Olefins Reaction[J]. Journal of Inorganic Materials, 2021, 36(1): 101 Copy Citation Text show less
XRD patterns of SAPO-34 synthesized with different types of seeds
1. XRD patterns of SAPO-34 synthesized with different types of seeds
SEM images of samples in the presence of various types of seeds (a) SP34; (b) SP34-RS; (c) SP34-AS0.1; (d) SP34-AS0.01; (e) SP34-AS0.001; (f) SP34-AS0.0001
2. SEM images of samples in the presence of various types of seeds (a) SP34; (b) SP34-RS; (c) SP34-AS0.1; (d) SP34-AS0.01; (e) SP34-AS0.001; (f) SP34-AS0.0001
N2 adsorption/desorption isotherms of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001)
3. N2 adsorption/desorption isotherms of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001)
NH3-TPD profiles of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001)
4. NH3-TPD profiles of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001)
Methanol conversion over SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001) catalysts with time-on-stream in the MTO reaction
5. Methanol conversion over SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001) catalysts with time-on-stream in the MTO reaction
Relative crystallinity of SAPO-34 synthesized in the presence of various kinds of seed crystals
S1. Relative crystallinity of SAPO-34 synthesized in the presence of various kinds of seed crystals
Pore size distribution of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001 mol/L)
S2. Pore size distribution of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001 mol/L)
Deconvolution of NH3-TPD curves of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001 mol/L)
S3. Deconvolution of NH3-TPD curves of SP34, SP34-RS and SP34-ASX (X=0.1, 0.01, 0.001, 0.0001 mol/L)
SampleTextual propertiesAcid amount cLifetime/min
SBET/(m2·g-1)Smic/(m2·g-1)Sext/(m2·g-1)Vmica/(cm3·g-1)Vmesob/(cm3·g-1)WeakMediumand strongTotal
SP34250681820.0290.3422.775.378.1440
SP34-RS316291240.1360.0680.862.052.91100
SP34-AS0.1547530170.2470.0570.972.553.52480
SP34-AS0.01552532200.2490.0561.423.414.83300
SP34-AS0.001568553150.2540.0520.852.203.05420
SP34-AS0.0001568547210.2560.0491.273.154.42330
Table 1.

Textural properties, acid amount and catalytic lifetime of different samples in MTO reaction

Dongqiang ZHANG, Huihui LU, Na SU, Guixian LI, Dong JI, Xinhong ZHAO. Modulation of SAPO-34 Property with Activated Seeds and Its Enhanced Lifetime in Methanol to Olefins Reaction[J]. Journal of Inorganic Materials, 2021, 36(1): 101
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