Fine structure of the atomic neon transitions of 2Pt-4S1 and 2P3-4S1 were mesured by means of optogalvanic spectroscopy and the neon line at 5919.037 A. was identified to the transition of 2p7-4d3 for the first time. The obtained profile of spectral line has a typical and symmetrical shape of line. The line width (FWHM) was measured to be 3. 2 GHz.