• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 10, 3099 (2021)
Nian TANG1、*, Shu-kai HE3、3;, Xiao-zhe ZENG3、3; *;, Huan-xin WANG3、3; 4;, Dong-wei SUN1、1; 2;, Qian-qian WU3、3;, and Jing-wei LI3、3;
Author Affiliations
  • 11. Electric Power Research Institute of Guangdong Power Grid Co., Ltd., Guangzhou 510080, China
  • 33. Henan Relations Co., Ltd., Zhengzhou 450001, China
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    DOI: 10.3964/j.issn.1000-0593(2021)10-3099-07 Cite this Article
    Nian TANG, Shu-kai HE, Xiao-zhe ZENG, Huan-xin WANG, Dong-wei SUN, Qian-qian WU, Jing-wei LI. Research on Infrared Absorption Characteristics and Detection Technology of New Environmentally Friendly Insulating Gas Trans-1,1,1,4,4,4-Hexafluoro-2-Butene[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3099 Copy Citation Text show less
    Schematic diagram of the self-built experimental platform
    Fig. 1. Schematic diagram of the self-built experimental platform
    IR spectrum obtained by FTIR experiment and the simulated results of HFO-1336mzz(E)(a): Gas spectrum experimental test;(b): Gas spectral simulation and predictionThe concentration of the measured gas is 33 μL·L-1 at the temperature of 298 K and the pressure of 100 kPa
    Fig. 2. IR spectrum obtained by FTIR experiment and the simulated results of HFO-1336mzz(E)
    (a): Gas spectrum experimental test;(b): Gas spectral simulation and prediction
    The concentration of the measured gas is 33 μL·L-1 at the temperature of 298 K and the pressure of 100 kPa
    The main vibration forms of HFO-1336mzz(E) gas molecule at the corresponding strong absorption positions
    Fig. 3. The main vibration forms of HFO-1336mzz(E) gas molecule at the corresponding strong absorption positions
    IR absorption spectrum of HFO-1336mzz(E), CO2 and H2O in the band of 1 100~1 350 cm-1 (The illustration is a partial enlarged view)The concentration of the aboved gases is respectively 33, 400 and 20 μL·L-1 at the temperature of 298 K and the pressure of 100 kPa
    Fig. 4. IR absorption spectrum of HFO-1336mzz(E), CO2 and H2O in the band of 1 100~1 350 cm-1 (The illustration is a partial enlarged view)
    The concentration of the aboved gases is respectively 33, 400 and 20 μL·L-1 at the temperature of 298 K and the pressure of 100 kPa
    IR absorption spectra of HFO-1336mzz (E) at different pressure(a): Absorption lines at different pressures; (b): Peak absorption coefficients at different pressuresThe concentration of the measured gas is 33 μL·L-1 at the temperature of 298 K
    Fig. 5. IR absorption spectra of HFO-1336mzz (E) at different pressure
    (a): Absorption lines at different pressures; (b): Peak absorption coefficients at different pressures
    The concentration of the measured gas is 33 μL·L-1 at the temperature of 298 K
    IR absorption spectra of HFO-1336mzz(E) gas at different temperatures(a): Absorption lines at different temperature; (b): Peak absorption coefficients at different pressuresThe concentration of the measured gas is 33 μL·L-1 at the pressure of 100 kPa
    Fig. 6. IR absorption spectra of HFO-1336mzz(E) gas at different temperatures
    (a): Absorption lines at different temperature; (b): Peak absorption coefficients at different pressures
    The concentration of the measured gas is 33 μL·L-1 at the pressure of 100 kPa
    The absorption factor corresponding to the low concentration leakage of HFO-1336mzz(E) gas and the high concentration mixing ratio(a): The absorption rate corresponding to low concentration leakage of 0~4 000 ppm;(b): The absorption rate corresponding to the mixing ratio of 1%~20% high concentration
    Fig. 7. The absorption factor corresponding to the low concentration leakage of HFO-1336mzz(E) gas and the high concentration mixing ratio
    (a): The absorption rate corresponding to low concentration leakage of 0~4 000 ppm;(b): The absorption rate corresponding to the mixing ratio of 1%~20% high concentration
    Nian TANG, Shu-kai HE, Xiao-zhe ZENG, Huan-xin WANG, Dong-wei SUN, Qian-qian WU, Jing-wei LI. Research on Infrared Absorption Characteristics and Detection Technology of New Environmentally Friendly Insulating Gas Trans-1,1,1,4,4,4-Hexafluoro-2-Butene[J]. Spectroscopy and Spectral Analysis, 2021, 41(10): 3099
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