Measurements of polarized properties of atmospheric scattering radiation is one of an effective means of investigating the optical and physical parameters. Taking atmosphere of Hefei area as an example, using the field spectropolarimeter, a lot of polarized spectral measurement data of atmosphere have been obtained from the ground in different time and space. By calculating and analyzing, we obtained the distribution information of atmospheric polarization properties. This work can provide material in retrieving the parameter of atmospheric aerosol and modeling polarized properties of the atmospheric aerosol scattering radiation.