• Laser & Optoelectronics Progress
  • Vol. 56, Issue 7, 073002 (2019)
Cheng Li, Guanxin Yao, Xinyan Yang, Zhengbo Qin, Xianfeng Zheng, and Zhifeng Cui*
Author Affiliations
  • Key Laboratory of Optoelectronic Materials Science and Technology of Anhui Province, Anhui Normal University, Wuhu, Anhui 241000, China
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    DOI: 10.3788/LOP56.073002 Cite this Article Set citation alerts
    Cheng Li, Guanxin Yao, Xinyan Yang, Zhengbo Qin, Xianfeng Zheng, Zhifeng Cui. Key Experimental Parameter Optimization for Laser Induced Breakdown Spectroscopy of Liquid Matrix[J]. Laser & Optoelectronics Progress, 2019, 56(7): 073002 Copy Citation Text show less
    Schematic of experimental apparatus
    Fig. 1. Schematic of experimental apparatus
    LIBS of each heavy metal element in mixed solution. (a) Al; (b)Mn, Pb; (c) Cr, Ca; (d) Cd
    Fig. 2. LIBS of each heavy metal element in mixed solution. (a) Al; (b)Mn, Pb; (c) Cr, Ca; (d) Cd
    LIBS versus laser pulse energy
    Fig. 3. LIBS versus laser pulse energy
    RSN versus laser pulse energy
    Fig. 4. RSN versus laser pulse energy
    LIBS versus ICCD gate delay
    Fig. 5. LIBS versus ICCD gate delay
    RSN versus ICCD gate delay
    Fig. 6. RSN versus ICCD gate delay
    RSN versus liquid flow rate
    Fig. 7. RSN versus liquid flow rate
    ElementChemicalformulaMolecularweight ofsoluteMassconcentration /10-6
    CrCrCl3·6H2O266.50200
    CdCdCl2·2.5H2O228.403000
    PbPb(NO3)2331.23500
    MnMnCl2125.84200
    CaCaCl2111.005
    AlAlCl3113.34100
    Table 1. Heavy metal elements and their mass concentrations in mixed solution
    ElementSpectral wavelength/nm
    Cr I302.156, 357.868, 359.348, 360.532, 425.433, 427.481, 428.973, 520.451, 520.602, 520.841, 540.978
    Cr II283.563, 284.324, 284.983,
    Cd I228.802, 326.105, 346.62, 346.766, 361.051, 361.287, 467.815, 479.991, 508.582, 643.847
    Pb I261.418, 280.2, 283.305, 363.957, 368.346, 405.781
    Mn I279.482, 279.827, 280.108, 403.076, 403.307, 403.449 475.404, 478.343, 482.352,
    Mn II257.61, 259.372, 260.568, 293.305, 293.931, 294.921
    Ca I422.673, 445.478, 612.222,
    Ca II393.366, 396.847,
    Al I309.271, 394.401, 396.152
    Table 2. Assignments of atom lines and their ion lines
    ElementAnalyticalspectral line /nmFirst ionizationenergy /eVExcitationdifficulty level
    Pb405.7814.375Medium
    Cr425.4332.913Easy
    CdMnCaAl508.582403.076422.673396.1526.3833.0752.9333.141Hardeasyeasyeasy
    Table 3. Analytical spectral lines, first ionization energies and excitation difficulty levels
    Cheng Li, Guanxin Yao, Xinyan Yang, Zhengbo Qin, Xianfeng Zheng, Zhifeng Cui. Key Experimental Parameter Optimization for Laser Induced Breakdown Spectroscopy of Liquid Matrix[J]. Laser & Optoelectronics Progress, 2019, 56(7): 073002
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