• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 9, 2872 (2021)
Zhi-yuan LI1、*, Fan DENG1、1; *;, Jun-liang HE2、2;, and Wei WEI1、1;
Author Affiliations
  • 11. School of Geosciences, Yangtze University, Wuhan 430100, China
  • 22. College of Resources and Environment Sciences, Shijiazhuang University, Shijiazhuang 050035, China
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    DOI: 10.3964/j.issn.1000-0593(2021)09-2872-07 Cite this Article
    Zhi-yuan LI, Fan DENG, Jun-liang HE, Wei WEI. Hyperspectral Estimation Model of Heavy Metal Arsenic in Soil[J]. Spectroscopy and Spectral Analysis, 2021, 41(9): 2872 Copy Citation Text show less
    Study area and the distribution of the soil sampling points
    Fig. 1. Study area and the distribution of the soil sampling points
    Transformed soil reflectance spectra after
    Fig. 2. Transformed soil reflectance spectra after
    Smoothed reflectance spectra of soil samples
    Fig. 3. Smoothed reflectance spectra of soil samples
    Continuum removal correlation coefficient curve
    Fig. 4. Continuum removal correlation coefficient curve
    Scatter plots of fitting and testing sets for MLSR(a): Fitting set; (b): Testing set
    Fig. 5. Scatter plots of fitting and testing sets for MLSR
    (a): Fitting set; (b): Testing set
    Scatter plots of the two set of samples of fitting and testing for M-PLSR(a):Fitting samples; (b): Testing samples
    Fig. 6. Scatter plots of the two set of samples of fitting and testing for M-PLSR
    (a):Fitting samples; (b): Testing samples
    重金属最小值平均值最大值标准差河北省背景值
    As10.84413.23015.1251.00513.6
    Table 1. Descriptive statistics of the arsenic content (mg·kg-1) in soil
    元素最小值平均值最大值样点数
    0.7<Pi≤11<Pi≤2
    As/(mg·kg-1)0.7970.9731.1122919
    Table 2. Statistical results of single factor pollution index of the soil arsenic
    光谱指标最大相关波段/nm相关系数
    SR2 342-0.289*
    FD1 211-0.527**
    SD2 208-0.470**
    RT1 7400.357*
    RTFD1 359-0.249
    RTSD1 0650.485**
    AT1 7400.353*
    ATFD464-0.370**
    ATSD2 2080.372**
    CR6820.603**
    Table 3. Maximum correlation coefficients of heavy metal As content and spectral indexes
    参数建模样本验证样本
    r0.8140.776
    RMSE0.1590.318
    F29.4378.482
    Table 4. Results of MLSR model
    参数建模样本验证样本
    rRMSEFrRMSEF
    FD0.2600.7532.3740.3200.6871.194
    ATFD0.2000.8141.6890.0250.9940.239
    RTSD0.2130.8011.8260.2960.7220.939
    CR0.3650.6473.8720.3810.6492.465
    Table 5. Results of U-PLSR model
    参数建模样本验证样本
    r0.8520.812
    RMSE0.1470.312
    F32.3848.598
    Table 6. Results of M-PLSR model
    Zhi-yuan LI, Fan DENG, Jun-liang HE, Wei WEI. Hyperspectral Estimation Model of Heavy Metal Arsenic in Soil[J]. Spectroscopy and Spectral Analysis, 2021, 41(9): 2872
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