This paper reports the analysis results of 11 decorated silicate beads samples excavated from Ma Jia-yuan Warring State Cemetery, Gan Su Province with the portable X-ray fluorescence spectrometer, laser Raman spectrometer and X-ray diffraction spectrometer. It is includes 3 types among these samples on the basis of their chemical composition, NaO-CaO-SiO2, PbO-BaO-SiO2 glass system, and glassy faience. The blue part of the NaO-CaO-SiO2 glass sample was colored by Co2+, and Sb2O5 was discovered as opacifier. The results of Laser Raman analysis shows in some circle beads exits Chinese blue and Chinese purple. Combined with the existing research results the early cultural factors and technical exchange reflected from these samples are discussed. It shows that the material and craftsmanship of the beads contained Chinese blue and Chinese purple were affected by Qin Culture. But the composition of the Na-Ca-SiO2 glass eye bead is similar with those excavated from Xin Jiang area. It infers the technology of glass manufacture of the Xi Ron nationality was influenced by the Qin Culture and the grassland nationalities’ culture simultaneously. The faience bead composed with the inner core and the outer glassy layer is possible a kind of transitional type between the faience and the real glass. This information offers a new reference for the research of the origin of the glass technology in the ancient China.