• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 2, 629 (2021)
Qian-yi ZHAO1、1、*, Chang XU1、1, and Xian-yu LIU1、1
Author Affiliations
  • 1[in Chinese]
  • 11. Geological Institute of China University of Geosciences, Wuhan 430074, China
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    DOI: 10.3964/j.issn.1000-0593(2021)02-0629-07 Cite this Article
    Qian-yi ZHAO, Chang XU, Xian-yu LIU. Spectral Characteristics of Dark-Blue Corundum From Fangshan Mine, Shandong, China and Le-Shuza-Kone Mine, Mogok, Burma[J]. Spectroscopy and Spectral Analysis, 2021, 41(2): 629 Copy Citation Text show less
    Corundum samples from Fangshan (a) and Le-shuza-kone (b) mines
    Fig. 1. Corundum samples from Fangshan (a) and Le-shuza-kone (b) mines
    Three sets of needle-like inclusions in CL-02(a) and BM-01(b) under optical microscope(50×)
    Fig. 2. Three sets of needle-like inclusions in CL-02(a) and BM-01(b) under optical microscope(50×)
    XRD spectra of CL-02 and BM-01□: Corundum; ○: Diaspore; ■: Boehmite
    Fig. 3. XRD spectra of CL-02 and BM-01
    □: Corundum; ○: Diaspore; ■: Boehmite
    Raman spectra of CL-02 and BM-01 hostcrystal
    Fig. 4. Raman spectra of CL-02 and BM-01 hostcrystal
    Raman spectra of zircon inclusion in CL-01
    Fig. 5. Raman spectra of zircon inclusion in CL-01
    Raman spectra of diaspore in BM-01
    Fig. 6. Raman spectra of diaspore in BM-01
    Micro-infrared spectra of CL-02 and BM-01(KBr pellet method)in the region of 400~3 500 cm-1
    Fig. 7. Micro-infrared spectra of CL-02 and BM-01(KBr pellet method)in the region of 400~3 500 cm-1
    Mossbauer spectra of CL-01 and CL-02(298 K)
    Fig. 8. Mossbauer spectra of CL-01 and CL-02(298 K)
    编号产地重量/g颜色透明度晶型描述底面方向特征包裹体
    CL-01方山矿区8.97暗蓝色微透明六方桶状晶粒大、 裂理发育, 六方角状色带//{0001}锆石
    CL-02方山矿区6.87暗蓝色微透明六方桶状晶型完整、 裂理发育, 六方角状色带//{0001}赤铁矿(针状)
    BM-01Le-shuza-kone矿区7.09暗蓝色半透明不规则粒状裂理发育//{0001}金红石(针状)、 水铝矿
    BM-02Le-shuza-kone矿区5.45暗蓝色半透明六方板状裂理发育//{0001}气液态包裹体
    Table 1. Mineralogical characteristic of CL-02 and BM-01
    CL-02(d1)和BM-01(d2)BM-01BM-01
    刚玉硬水铝石勃姆矿(一水软铝石)
    d1d2(hkl)2θd(hkl)2θd(hkl)2θ
    -------6.115 1(020)14.44
    ----3.981 5(110)22.31---
    3.408 83.477 0(012)25.65------
    2.551 82.549 9(104)35.032.549 9(130)35.22---
    2.380 72.378 1(110)37.772.378 1(101)37.82---
    ----2.314 9(111)38.97---
    2.086 62.084 9(113)43.332.084 9(140)43.50---
    1.741 11.739 8(024)52.511.739 8(041)52.52---
    1.602 61.601 4(116)57.471.601 4(240)57.62---
    1.548 21.547 0(211)59.71------
    1.512 21.511 4(018)61.23------
    Table 2. XRD characteristic of corundum, diaspore and boehmite
    样品号特征峰位/cm-1对应官
    能团
    样品厚
    度/μm
    CL-02451, 603, 640, 779, 1 088,
    1 622
    -100
    BM-01451, 603, 640, 779, 1 088,
    1 622, 1 980, 2 110, 3 310
    —OH100
    Table 3. The FTIR results of CL-02 and BM-01 (KBr pellet method)
    Wt%CL-01-1CL-01-2CL-01-3CL-02-1CL-02-2CL-02-3BM-01-1BM-01-2BM-01-3BM-02-1BM-02-1BM-02-3
    TiO2000.089000000.0080.0150.0080
    V2O300.00700.0150.0120.01200.01300.010.0090
    Cr2O300.021000.0010.00100.0200.0320.0340.01
    SiO20.006000.0070.0180.023000.0090.01500
    Al2O397.69599.23397.73198.85998.99598.516100.476100.546100.207100.114100.556100.748
    FeO*1.3711.2781.5971.2571.3861.2940.2720.2490.2490.2490.2490.249
    MnO0.0310.003000.020.0220000.020.010.005
    Table 4. EPMA results of CL-02 and BM-01
    CL-01-1CL-01-2CL-01-3CL-02-1CL-02-2CL-02-3BM-01-1BM-01-2BM-01-3BM-02-1BM-02-1BM-02-3
    Fe3+000.004 6000000.000 40.000 80.000 40
    Fe2+0.019 80.018 20.018 40.017 90.019 70.018 50.003 80.003 50.003 10.002 80.003 10.003 5
    Fe2O3000.355 7000000.032 00.060 00.032 00
    FeO1.371 01.278 01.276 81.257 01.386 01.294 00.272 00.249 00.220 20.195 00.220 20.249 0
    Table 5. The content of Fe3+ and Fe2+ in CL-02 and BM-01 calculated by electrovalence difference method
    温度/K谱峰IS/(mm·s-1)QS/(mm·s-1)LW/(mm·s-1)峰面积/%
    2981(CL-01)0.562 782.479 670.582 0032.01
    2982(CL-02)0.288 080.519 690.582 0067.99
    Table 6. Mossbauer results of CL-01 and CL-02
    Qian-yi ZHAO, Chang XU, Xian-yu LIU. Spectral Characteristics of Dark-Blue Corundum From Fangshan Mine, Shandong, China and Le-Shuza-Kone Mine, Mogok, Burma[J]. Spectroscopy and Spectral Analysis, 2021, 41(2): 629
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