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    Journals >Journal of Inorganic Materials >Volume 37 >Issue 1 >Page 45 > Article
    • Journal of Inorganic Materials
    • Vol. 37, Issue 1, 45 (2022)
    Iron-doping Enhanced Basic Nickel Carbonate for Moisture Resistance and Catalytic Performance of Ozone Decomposition
    Bangxin LI*, Qian ZHANG, Jie XIAO, Wenyan XIAO, and Ying ZHOU
    DOI: 10.15541/jim20210127 Cite this Article
    Bangxin LI, Qian ZHANG, Jie XIAO, Wenyan XIAO, Ying ZHOU. Iron-doping Enhanced Basic Nickel Carbonate for Moisture Resistance and Catalytic Performance of Ozone Decomposition[J]. Journal of Inorganic Materials, 2022, 37(1): 45 Copy Citation Text show less
    XRD patterns of NiCH and NiCH-Fe
    . XRD patterns of NiCH and NiCH-Fe
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    (a) SEM image of NiCH-Fe5% and corresponding EDS mappings of (b) Ni and (c) Fe elements, TEM images of (d) NiCH and (e) NiCH-Fe5%, and (f) HRTEM image of NiCH-Fe5%
    . (a) SEM image of NiCH-Fe5% and corresponding EDS mappings of (b) Ni and (c) Fe elements, TEM images of (d) NiCH and (e) NiCH-Fe5%, and (f) HRTEM image of NiCH-Fe5%
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    (a) Nitrogen adsorption-desorption isotherms and (b) pore size distributions of NiCH, NiCH-Fe and FeCH
    . (a) Nitrogen adsorption-desorption isotherms and (b) pore size distributions of NiCH, NiCH-Fe and FeCH
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    Ozone removal rates of (a) NiCH-Fe with different Fe dopants at 60%RH and (b) NiCH-Fe5% at 60%, 70%, 80%RH
    . Ozone removal rates of (a) NiCH-Fe with different Fe dopants at 60%RH and (b) NiCH-Fe5% at 60%, 70%, 80%RH
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    Long time ozone removal tests of NiCH-Fe5% and MnO2
    . Long time ozone removal tests of NiCH-Fe5% and MnO2
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    XPS spectra of (a) Ni2p3/2 and (b) Fe2p of NiCH-Fe5% before and after reaction
    . XPS spectra of (a) Ni2p3/2 and (b) Fe2p of NiCH-Fe5% before and after reaction
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    Surface water adsorption curves of NiCH and NiCH- Fe5%
    . Surface water adsorption curves of NiCH and NiCH- Fe5%
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    Single-layer structure of NiCH-Fe
    . Single-layer structure of NiCH-Fe
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    MoleculeSiteNiCHNiCH-Fe
    O3Ni-0.36 eV-0.57 eV
    Fe(Ni)-0.02 eV(Ni)-1.93eV(Fe)
    O1-0.28 eV-0.61 eV
    O2-0.69 eV-0.46 eV
    H2O Ni-0.15 eV-0.41 eV
    Fe(Ni)-0.24 eV(Ni)-0.55 eV(Fe)
    Table 1. Adsorption energy of ozone and H2O on different sites of NiCH and NiCH-Fe5%
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    Abstract
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    Bangxin LI, Qian ZHANG, Jie XIAO, Wenyan XIAO, Ying ZHOU. Iron-doping Enhanced Basic Nickel Carbonate for Moisture Resistance and Catalytic Performance of Ozone Decomposition[J]. Journal of Inorganic Materials, 2022, 37(1): 45
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