• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 12, 3776 (2021)
Tie-zhu ZHANG1、*, Yu-xuan ZHANG2、2; 3;, Sai-yu LIU2、2; 4;, Hang-ren LI2、2;, Wen-ce XU1、1; 2;, Jin-shan ZHANG1、1; *;, Shun-li OUYANG2、2; *;, and Nan-nan WU4、4;
Author Affiliations
  • 11. Mining Research Institute of Inner Mongolia University of Science and Technology, Baotou 014010, China
  • 22. Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China
  • 44. College of Science, Inner Mongolia University of Science and Technology, Baotou 014010, China
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    DOI: 10.3964/j.issn.1000-0593(2021)12-3776-06 Cite this Article
    Tie-zhu ZHANG, Yu-xuan ZHANG, Sai-yu LIU, Hang-ren LI, Wen-ce XU, Jin-shan ZHANG, Shun-li OUYANG, Nan-nan WU. The Occurrence and Distribution of REE Minerals in Fluorite-Type Ores in Bayan Obo: Constraints From Raman Mapping[J]. Spectroscopy and Spectral Analysis, 2021, 41(12): 3776 Copy Citation Text show less
    Sample of banded fluorite type of Bayan Obo MineMnz: Monazite; Fl: Fluorite; Ap: Apatite; Brt: Barite; Py: Pyrite
    Fig. 1. Sample of banded fluorite type of Bayan Obo Mine
    Mnz: Monazite; Fl: Fluorite; Ap: Apatite; Brt: Barite; Py: Pyrite
    EDS images and single point energy spectrum elemental distribution of fluorite type
    Fig. 2. EDS images and single point energy spectrum elemental distribution of fluorite type
    Raman spectrogram and Mapping mineral distribution map of fluorite type X50 objective microscopic confocal map(b): Fluorite; (c): Barite; (d): Apatite; (e): Monazite
    Fig. 3. Raman spectrogram and Mapping mineral distribution map of fluorite type X50 objective microscopic confocal map
    (b): Fluorite; (c): Barite; (d): Apatite; (e): Monazite
    ElementContentElementContentElementContent
    TFe31.30SiO20.12MnO0.46
    ERO7.58CaO27.8Nb2O50.33
    Na2O0.05TiO20.43BaO0.19
    MgO0.12P0.09LOI5.51
    Al2O30.10S0.09
    K2O0.04F19.75
    Table 1. Multi element content analysis results of fluorite rare earth sample (Wt%)
    ElementCOPSFCaFeBaLaCeNdTotal
    Content3.3232.13.772.3620.7521.380.4611.331.322.440.77100
    Table 2. Regional energy spectrum analysis value and element content calculation of fluorite type sample surface scanning (Wt%)
    ElementCeLaNdPOTotal
    point 130.4714.989.6712.9229.5397.57
    point 229.5116.077.611.8928.9694.03
    point 331.4816.488.1712.4928.1296.74
    point 429.4515.377.4912.1229.4493.87
    point 529.4616.027.2911.7729.1993.73
    Average30.07415.7848.04412.23829.04895.188
    Table 3. The point energy spectrum element average content calculation of monazite (Wt%)
    矿物名称化学式拉曼特征峰位/ cm-1
    萤石CaF2320228457642
    ν1ν2ν3ν4
    重晶石BaSO49874514591 0831 1031 1411 167616646
    磷灰石Ca5[PO4]3F9634294591 0131 0531 124591601651
    独居石(Ce, La, Nd)PO49703954144669901 0251 0551 072537570589619
    Table 4. Mineralogical characteristics and Raman vibration peaks of fluorite type
    Tie-zhu ZHANG, Yu-xuan ZHANG, Sai-yu LIU, Hang-ren LI, Wen-ce XU, Jin-shan ZHANG, Shun-li OUYANG, Nan-nan WU. The Occurrence and Distribution of REE Minerals in Fluorite-Type Ores in Bayan Obo: Constraints From Raman Mapping[J]. Spectroscopy and Spectral Analysis, 2021, 41(12): 3776
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