• Journal of Inorganic Materials
  • Vol. 35, Issue 2, 217 (2020)
Jun CHEN1, Pei-Hua MA2, Cheng ZHANG1, RUHLMANN Laurent3, and Yao-Kang LYU1、*
Author Affiliations
  • 1School of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  • 2Shaoxing Jinye Environmental Protection Technology Co., Ltd., Shaoxing 312073, China
  • 3Institut de Chimie, Université de Strasbourg, Strasbourg 67081, France;
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    DOI: 10.15541/jim20190157 Cite this Article
    Jun CHEN, Pei-Hua MA, Cheng ZHANG, RUHLMANN Laurent, Yao-Kang LYU. Preparation and Electrochemical Property of New Multifunctional Inorganic/Organic Composite Film[J]. Journal of Inorganic Materials, 2020, 35(2): 217 Copy Citation Text show less
    Schematic illustration of preparation of PEDOT:Ce@TiO2 film
    1. Schematic illustration of preparation of PEDOT:Ce@TiO2 film
    (a) SEM image, (b) AFM height sensor image (2D), (c) AFM tapping phase image (2D) of PEDOT film, and (d) SEM image, (e) AFM height sensor image (2D), (f) AFM tapping phase image (2D) of PEDOT:Ce@TiO2 film
    2. (a) SEM image, (b) AFM height sensor image (2D), (c) AFM tapping phase image (2D) of PEDOT film, and (d) SEM image, (e) AFM height sensor image (2D), (f) AFM tapping phase image (2D) of PEDOT:Ce@TiO2 film
    SEM-mapping images of PEDOT:Ce@TiO2 film
    3. SEM-mapping images of PEDOT:Ce@TiO2 film
    Images of water droplets on the surfaces of PEDOT film (a) and PEDOT:Ce@TiO2 film (c), and images of ACN droplets on the surfaces of PEDOT film (b) and PEDOT: Ce@TiO2 film (d)
    4. Images of water droplets on the surfaces of PEDOT film (a) and PEDOT:Ce@TiO2 film (c), and images of ACN droplets on the surfaces of PEDOT film (b) and PEDOT: Ce@TiO2 film (d)
    CV curves of (a) PEDOT and (b) PEDOT:Ce@TiO2; Galvanostatic charge/discharge curves of (c) PEDOT and (d) PEDOT:Ce@TiO2
    5. CV curves of (a) PEDOT and (b) PEDOT:Ce@TiO2; Galvanostatic charge/discharge curves of (c) PEDOT and (d) PEDOT:Ce@TiO2
    (a) Schematic, (b) galvanostatic charge/discharge curves of electrochromic supercapacitor, and optical photos under the completing of charging and discharging.
    6. (a) Schematic, (b) galvanostatic charge/discharge curves of electrochromic supercapacitor, and optical photos under the completing of charging and discharging.
    Relative molecular mass distribution with run time from 12.0 to 28 min
    S1. Relative molecular mass distribution with run time from 12.0 to 28 min
    Photographs of solution of PEDOT oligomer in DCM, (b) solution of polyoxotitanate cluster [Ti8O7(HOEt)(OEt)21Ce] in DCM, (c) mixture solution of PEDOT and polyoxotitanate cluster [Ti8O7(HOEt)(OEt)21Ce] in DCM, (d) PEDOT film (e) PEDOT: Ce@TiO2 film.
    S2. Photographs of solution of PEDOT oligomer in DCM, (b) solution of polyoxotitanate cluster [Ti8O7(HOEt)(OEt)21Ce] in DCM, (c) mixture solution of PEDOT and polyoxotitanate cluster [Ti8O7(HOEt)(OEt)21Ce] in DCM, (d) PEDOT film (e) PEDOT: Ce@TiO2 film.
    FT-IR spectra of PEDOT and PEDOT:Ce@TiO2
    S3. FT-IR spectra of PEDOT and PEDOT:Ce@TiO2
    XRD patterns of (a) PEDOT:Ce@TiO2 powder; (b) Ce@TiO2 powder and (c) PEDOT powder
    S4. XRD patterns of (a) PEDOT:Ce@TiO2 powder; (b) Ce@TiO2 powder and (c) PEDOT powder
    EDS spectrum of film PEDOT
    S5. EDS spectrum of film PEDOT
    EDS spectrum of film PEDOT:Ce@TiO2
    S6. EDS spectrum of film PEDOT:Ce@TiO2
    (a) AFM height sensor image (2D), (b) AFM height sensor image (3D) of PEDOT film; (c) AFM height sensor image (2D), (d) AFM height sensor image (3D) of PEDOT:Ce@TiO2 film
    S7. (a) AFM height sensor image (2D), (b) AFM height sensor image (3D) of PEDOT film; (c) AFM height sensor image (2D), (d) AFM height sensor image (3D) of PEDOT:Ce@TiO2 film
    Cyclic voltammetry curves of PEDOT and PEDOT:Ce@TiO2 films in 0.1 mol/L LiClO4/ACN at scan rate of 100 mV/s
    S8. Cyclic voltammetry curves of PEDOT and PEDOT:Ce@TiO2 films in 0.1 mol/L LiClO4/ACN at scan rate of 100 mV/s
    UV-Vis spectra and optical photos (inserts) of films under different potentialaption
    S9. UV-Vis spectra and optical photos (inserts) of films under different potentialaption
    (a) Nyquist plots of the impedance spectra of PEDOT and PEDOT: Ce@TiO2; (b) Specific capacitance calculated from discharge curves of PEDOT and PEDOT: Ce@TiO2 films
    S10. (a) Nyquist plots of the impedance spectra of PEDOT and PEDOT: Ce@TiO2; (b) Specific capacitance calculated from discharge curves of PEDOT and PEDOT: Ce@TiO2 films
    Cycling performance of PEDOT (a) and PEDOT:Ce@TiO2 (b) film measured by charging and discharging it at 1 A/g
    S11. Cycling performance of PEDOT (a) and PEDOT:Ce@TiO2 (b) film measured by charging and discharging it at 1 A/g
    Electro-polymerization route for PTBPTA
    S12. Electro-polymerization route for PTBPTA
    CV curves of electrochromic supercapacitor
    S13. CV curves of electrochromic supercapacitor
    Specific capacitance calculated from discharge curves of electrochromic supercapacitor
    S14. Specific capacitance calculated from discharge curves of electrochromic supercapacitor
    FilmC/wt%O/wt%S/wt%Ti/wt%Ce/wt%
    PEDOT62.3820.1317.49
    PEDOT: Ce@TiO260.0118.2615.913.182.01
    Table 1. Mass percentages of the carbon, oxygen, sulfur, titanium and cerium atoms in PEDOT and PEDOT: Ce@TiO2 film
    Jun CHEN, Pei-Hua MA, Cheng ZHANG, RUHLMANN Laurent, Yao-Kang LYU. Preparation and Electrochemical Property of New Multifunctional Inorganic/Organic Composite Film[J]. Journal of Inorganic Materials, 2020, 35(2): 217
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