• Journal of Inorganic Materials
  • Vol. 37, Issue 9, 1001 (2022)
Hanxiang CHEN1, Min ZHOU1, Zhao MO2, Jianjian YI3, Huaming LI2, and Hui XU2、*
Author Affiliations
  • 11. School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China
  • 22. School of the Institute for Energy Research, Jiangsu University, Zhenjiang 212013, China
  • 33. College of Environmental Science and Engineering, Yangzhou University, Yangzhou 225127, China
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    DOI: 10.15541/jim20210806 Cite this Article
    Hanxiang CHEN, Min ZHOU, Zhao MO, Jianjian YI, Huaming LI, Hui XU. 0D/2D CoN/g-C3N4 Composites: Structure and Photocatalytic Performance for Hydrogen Production [J]. Journal of Inorganic Materials, 2022, 37(9): 1001 Copy Citation Text show less

    Abstract

    In the photocatalytic hydrogen production reaction, the introduction of cocatalyst to promote the rapid transfer of photogenerated electrons is an effective way to improve the photocatalytic activity. At present, the most efficient cocatalysts are mainly precious metals, greatly restricting the use of this method. In this study, influence of the close interface between non-noble metal cocatalyst CoN and g-C3N4 0D/2D on the performance of photocatalytic hydrogen production was explored. The results showed that the support of non-noble metal cocatalyst CoN can effectively improve the photocatalytic hydrogen production of 2D g-C3N4, and the support amount also has an positive effect on its activity. The compact 0D/2D interface is favorable for the rapid transmission of photogenerated electrons. Photocatalytic efficiency of 10% CoN/2D g-C3N4 composite reached 403.6 μmol·g-1·h-1, 20 times of that of 2D g-C3N4 monomer, which was comparable to that of noble metal cocatalyst. As a hydrogen evolution cocatalyst, loaded CoN can significantly promote the charge transfer process, thus greatly improving the activity of photocatalytic hydrogen evolution.
    Hanxiang CHEN, Min ZHOU, Zhao MO, Jianjian YI, Huaming LI, Hui XU. 0D/2D CoN/g-C3N4 Composites: Structure and Photocatalytic Performance for Hydrogen Production [J]. Journal of Inorganic Materials, 2022, 37(9): 1001
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