Author Affiliations
1School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China2Jiangsu Province Special Equipment Safety Supervision and Inspection Institute Branch, Wuxi 214071, Chinashow less
1. Schematic illustration of His-CDs/GA preparation
S1. Size distribution of His-CDs
S2. XRD pattern (a) and IR spectrum (b) of His-CDs
2. TEM image of His-CDs (Inset: HRTEM image)
3. SEM images of GA(a), His-CDs/GA-1(b), His-CDs/ GA-2(c), and His-CDs/GA-3(d), and TEM images of GA(e) and His-CDs/GA-2(f)
S3. Raman spectra of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
S4. N2 absorption-desorption isotherms (a) and pore size distributions (b) of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
4. XRD patterns of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
5. Total survey XPS spectra (a) of GA and His-CDs/GA-2 and N 1s spectrum (b) of His-CDs/GA-2
S5. C1s (a) and O1s (b) XPS spectra of His-CDs/GA-2
6. CV curves (a) at 10 mV·s-1 and GCD curves (b) at 1 A·g-1 of GA, His-CDs/GA-1, His-CDs/GA-2, and His-CDs/ GA-3
S6. AC impedance plots of 4 electrodes with inset showing the equivalent ciruit from the EIS measurements
S7. CV curves (a) at different scan rates and GCD curves (b) at different current densities of His-CDs/GA-2//His-CDs/ GA-2 symmetrical supercapacitor
7. CV curves at different scan rates (a) and GCD curves at different current densities (b) of His-CDs/GA-2; Rate capabilities of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3 (c); Cycling performances of GA and His-CDs/GA-2 at 10 A·g-1 (d)
S8. Cycling performance at 5 A·g-1 over 20000 cycles of His-CDs/GA-2//His-CDs/GA-2 symmetrical supercapacitor
8. Ragon plots of His-CDs/GA-2//His-CDs/GA-2
Electrode | Specific capacitance/ (F·g-1) | Current density/ (A·g-1) | Ref. |
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RGO/CD | 278 | 0.2 | [1] | N-OMCN@GN | 242.3 | 1 | [2] | N/S-rGAs | 180.5 | 1 | [3] | GQDs-3DG | 268 | 1.25 | [4] | GQD/3DG | 242 | 1.17 | [5] | 3D graphene layers | 231.2 | 1 | [6] | 3D bubble-like graphene frameworks | 277 | 1 | [7] | His-CDs/GA-2 | 304 | 1 | This work |
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Table 1. Comparison of the specific capacitance of His-CDs/GA-2 and other graphene-based electrodes