• Journal of Inorganic Materials
  • Vol. 35, Issue 10, 1130 (2020)
Zhuofeng DING1, Yongqiang YANG2, and Zaijun LI1、*
Author Affiliations
  • 1School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
  • 2Jiangsu Province Special Equipment Safety Supervision and Inspection Institute Branch, Wuxi 214071, China
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    DOI: 10.15541/jim20190630 Cite this Article
    Zhuofeng DING, Yongqiang YANG, Zaijun LI. Synthesis and Supercapacitor Performance of Histidine-functionalized Carbon Dots/Graphene Aerogel[J]. Journal of Inorganic Materials, 2020, 35(10): 1130 Copy Citation Text show less
    Schematic illustration of His-CDs/GA preparation
    1. Schematic illustration of His-CDs/GA preparation
    Size distribution of His-CDs
    S1. Size distribution of His-CDs
    XRD pattern (a) and IR spectrum (b) of His-CDs
    S2. XRD pattern (a) and IR spectrum (b) of His-CDs
    TEM image of His-CDs (Inset: HRTEM image)
    2. TEM image of His-CDs (Inset: HRTEM image)
    SEM images of GA(a), His-CDs/GA-1(b), His-CDs/ GA-2(c), and His-CDs/GA-3(d), and TEM images of GA(e) and His-CDs/GA-2(f)
    3. SEM images of GA(a), His-CDs/GA-1(b), His-CDs/ GA-2(c), and His-CDs/GA-3(d), and TEM images of GA(e) and His-CDs/GA-2(f)
    Raman spectra of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
    S3. Raman spectra of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
    N2 absorption-desorption isotherms (a) and pore size distributions (b) of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
    S4. N2 absorption-desorption isotherms (a) and pore size distributions (b) of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
    XRD patterns of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
    4. XRD patterns of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3
    Total survey XPS spectra (a) of GA and His-CDs/GA-2 and N 1s spectrum (b) of His-CDs/GA-2
    5. Total survey XPS spectra (a) of GA and His-CDs/GA-2 and N 1s spectrum (b) of His-CDs/GA-2
    C1s (a) and O1s (b) XPS spectra of His-CDs/GA-2
    S5. C1s (a) and O1s (b) XPS spectra of His-CDs/GA-2
    CV curves (a) at 10 mV·s-1 and GCD curves (b) at 1 A·g-1 of GA, His-CDs/GA-1, His-CDs/GA-2, and His-CDs/ GA-3
    6. CV curves (a) at 10 mV·s-1 and GCD curves (b) at 1 A·g-1 of GA, His-CDs/GA-1, His-CDs/GA-2, and His-CDs/ GA-3
    AC impedance plots of 4 electrodes with inset showing the equivalent ciruit from the EIS measurements
    S6. AC impedance plots of 4 electrodes with inset showing the equivalent ciruit from the EIS measurements
    CV curves (a) at different scan rates and GCD curves (b) at different current densities of His-CDs/GA-2//His-CDs/ GA-2 symmetrical supercapacitor
    S7. CV curves (a) at different scan rates and GCD curves (b) at different current densities of His-CDs/GA-2//His-CDs/ GA-2 symmetrical supercapacitor
    CV curves at different scan rates (a) and GCD curves at different current densities (b) of His-CDs/GA-2; Rate capabilities of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3 (c); Cycling performances of GA and His-CDs/GA-2 at 10 A·g-1 (d)
    7. CV curves at different scan rates (a) and GCD curves at different current densities (b) of His-CDs/GA-2; Rate capabilities of GA, His-CDs/GA-1, His-CDs/GA-2 and His-CDs/GA-3 (c); Cycling performances of GA and His-CDs/GA-2 at 10 A·g-1 (d)
    Cycling performance at 5 A·g-1 over 20000 cycles of His-CDs/GA-2//His-CDs/GA-2 symmetrical supercapacitor
    S8. Cycling performance at 5 A·g-1 over 20000 cycles of His-CDs/GA-2//His-CDs/GA-2 symmetrical supercapacitor
    Ragon plots of His-CDs/GA-2//His-CDs/GA-2
    8. Ragon plots of His-CDs/GA-2//His-CDs/GA-2
    ElectrodeSpecific
    capacitance/
    (F·g-1)
    Current
    density/
    (A·g-1)
    Ref.
    RGO/CD2780.2[1]
    N-OMCN@GN242.31[2]
    N/S-rGAs180.51[3]
    GQDs-3DG2681.25[4]
    GQD/3DG2421.17[5]
    3D graphene layers231.21[6]
    3D bubble-like
    graphene frameworks
    2771[7]
    His-CDs/GA-23041This work
    Table 1. Comparison of the specific capacitance of His-CDs/GA-2 and other graphene-based electrodes
    Zhuofeng DING, Yongqiang YANG, Zaijun LI. Synthesis and Supercapacitor Performance of Histidine-functionalized Carbon Dots/Graphene Aerogel[J]. Journal of Inorganic Materials, 2020, 35(10): 1130
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