• Laser & Optoelectronics Progress
  • Vol. 60, Issue 1, 0130002 (2023)
Dengshan Li, Lina Li*, and Rencheng Zhang
Author Affiliations
  • College of Mechanical Engineering and Automation, Huaqiao University, Xiamen 361021, Fujian , China
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    DOI: 10.3788/LOP212915 Cite this Article Set citation alerts
    Dengshan Li, Lina Li, Rencheng Zhang. Water Quality pH Value Determination for Visible-Near Infrared Spectroscopy Based on SPA and PSO-LSSVM[J]. Laser & Optoelectronics Progress, 2023, 60(1): 0130002 Copy Citation Text show less
    Experimental spectra of samples with different pH values. (a) Original spectra; (b) spectra of distilled water
    Fig. 1. Experimental spectra of samples with different pH values. (a) Original spectra; (b) spectra of distilled water
    Spectral preprocessing results based on S-G smoothing and SNV
    Fig. 2. Spectral preprocessing results based on S-G smoothing and SNV
    Feature wavelength screening based on SPA. (a) RMSEP of the validation set; (b) characteristic wavelength distribution
    Fig. 3. Feature wavelength screening based on SPA. (a) RMSEP of the validation set; (b) characteristic wavelength distribution
    Variation curve of RMSEP with the number of principal components
    Fig. 4. Variation curve of RMSEP with the number of principal components
    Process of PSO optimizing LSSVM parameters. (a) PSO-LSSVM; (b) SPA-PSO-LSSVM
    Fig. 5. Process of PSO optimizing LSSVM parameters. (a) PSO-LSSVM; (b) SPA-PSO-LSSVM
    Scatter plot of the predicted values of the SPA-PSO-LSSVM model for the validation set
    Fig. 6. Scatter plot of the predicted values of the SPA-PSO-LSSVM model for the validation set
    SampleSample numberMax valueMin valueMean valueStandard deviation
    Calibration set4012.222.717.562.52
    Validation set2010.282.885.562.08
    Table 1. Statistical results of pH value for the samples
    ModeNumber of wavelengthsComponents numberγδ2RMSEPR2RPD
    PLS286080.910.822.28
    SPA-PLS840.740.872.81
    SPA-MLR80.770.882.70
    PSO-LSSVM286030033.602256.180.880.832.36
    SPA-PSO-LSSVM811059.351324.380.670.913.10
    Table 2. Parameters and results of different modeling methods
    Dengshan Li, Lina Li, Rencheng Zhang. Water Quality pH Value Determination for Visible-Near Infrared Spectroscopy Based on SPA and PSO-LSSVM[J]. Laser & Optoelectronics Progress, 2023, 60(1): 0130002
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