• Journal of Inorganic Materials
  • Vol. 36, Issue 11, 1163 (2021)
Yu GUO, Xiaoqing JIANG, Hongmei WU, Yu XIAO, Dafu WU, and Xin LIU
Author Affiliations
  • School of Chemical and Environmental Engineering, Institute of Interdisciplinary Research, Liaoning University of Technology, Jinzhou 121001, China
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    DOI: 10.15541/jim20210109 Cite this Article
    Yu GUO, Xiaoqing JIANG, Hongmei WU, Yu XIAO, Dafu WU, Xin LIU. Preparation of 2-hydroxy-1-naphthalene Functionalized SBA-15 Adsorbent for the Adsorption of Chromium(III) Ions from Aqueous Solution[J]. Journal of Inorganic Materials, 2021, 36(11): 1163 Copy Citation Text show less
    Schematic diagram of the synthetic process for Q-SBA-15
    1. Schematic diagram of the synthetic process for Q-SBA-15
    (a, b) SEM images, (c, d) EDX elemental analyses, (e) XRD patterns and (f) TG curves of (a, c) SBA-15 and (b, d) Q-SBA-15 samples
    2. (a, b) SEM images, (c, d) EDX elemental analyses, (e) XRD patterns and (f) TG curves of (a, c) SBA-15 and (b, d) Q-SBA-15 samples
    (a) N2 adsorption-desorption isotherms, (b) pore size distributions of SBA-15 and Q-SBA-15, (c, d) TEM images of Q-SBA-15
    3. (a) N2 adsorption-desorption isotherms, (b) pore size distributions of SBA-15 and Q-SBA-15, (c, d) TEM images of Q-SBA-15
    (a) FT-IR spectra of Q-SBA-15 and SBA-15, and (b) XPS survey spectrum of Q-SBA-15
    4. (a) FT-IR spectra of Q-SBA-15 and SBA-15, and (b) XPS survey spectrum of Q-SBA-15
    Effect of solution pH on the adsorption of Cr(III) with Q-SBA-15
    5. Effect of solution pH on the adsorption of Cr(III) with Q-SBA-15
    Effects of ionic strength on Cr(III) adsorption
    6. Effects of ionic strength on Cr(III) adsorption
    Linearized fitting curves of (a) Langmuir model and (b) Freundlich model for adsorption of Cr(III) on Q-SBA-15
    7. Linearized fitting curves of (a) Langmuir model and (b) Freundlich model for adsorption of Cr(III) on Q-SBA-15
    XPS spectra of Q-SBA-15
    8. XPS spectra of Q-SBA-15
    Regeneration property of Q-SBA-15
    9. Regeneration property of Q-SBA-15
    (a) Effect of contacting time on the adsorption capacity of Cr(III) by Q-SBA-15 and (b) EDX analyses of Q-SBA-15 after adsorption of Cr(III)
    S1. (a) Effect of contacting time on the adsorption capacity of Cr(III) by Q-SBA-15 and (b) EDX analyses of Q-SBA-15 after adsorption of Cr(III)
    Fitting curves for adsorption of Cr(III) by (a) pseudo-first-order model and (b) pseudo-first-order model
    S2. Fitting curves for adsorption of Cr(III) by (a) pseudo-first-order model and (b) pseudo-first-order model
    Plots of lnKcversus 1/T for the adsorption of Cr(III) by Q-SBA-15
    S3. Plots of lnKcversus 1/T for the adsorption of Cr(III) by Q-SBA-15
    SampleSBET/(cm2·g-1) Pore size/nm
    SBA-157579.6
    Q-SBA-152836.7
    Table 1. Textural properties of the synthesized samples
    Sampleqe,exp/(mg·g-1) Pseudo first-order modelPseudo second-order model
    K1/ min-1qe,cal/(mg·g-1) R2K2/(g·mg-1·min-1) qe,cal/(mg·g-1) R2
    Q-SBA-15102.30.064761.750.8574.26×10-4119.190.979
    Table 1. Kinetic parameters for Cr(III) adsorption onto Q-SBA-15
    Adsorbentqm/(mg·g-1) References
    Biomass-based hydrogel41.7[1]
    m-MCM-41-NH236.92[2]
    Graphene oxide13.3[3]
    Thiol-functionalized MCM-4115.34[4]
    TS-SBA-1595.68[5]
    NH2-SBA-15 24.88[6]
    Q-SBA-15102.3This work
    Table 2. Comparison of Cr(III) adsorption performance with different materials selected from literature
    Temperature /℃ LangmuirFreundlich
    qm/(g·mg-1) KLR2KFnR2
    30106.840.090.98824.593.120.836
    40108.230.250.99748.395.470.913
    50112.740.410.99742.724.270.697
    Table 2. Different model parameters for adsorption of Cr(III) by Q-SBA-15 at different temperatures
    SampleTempera- ture/K KcΔG/ (kJ·mol-1) ΔS/ (kJ·mol·K-1) ΔH/ (kJ·mol-1)
    Q-SBA-152931.846-4.3860.12833.118
    3032.095-5.666
    3132.650-6.946
    3182.780-7.586
    3233.088-8.226
    Table 3. Thermodynamic parameters of Cr(III) adsorption on Q-SBA-15
    Yu GUO, Xiaoqing JIANG, Hongmei WU, Yu XIAO, Dafu WU, Xin LIU. Preparation of 2-hydroxy-1-naphthalene Functionalized SBA-15 Adsorbent for the Adsorption of Chromium(III) Ions from Aqueous Solution[J]. Journal of Inorganic Materials, 2021, 36(11): 1163
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