• Spectroscopy and Spectral Analysis
  • Vol. 40, Issue 11, 3499 (2020)
Hao-dan ZHANG1、1、*, Xiao-lin SUN1、1, Xiao-qing WANG1、1, and Hui-li WANG1、1
Author Affiliations
  • 1[in Chinese]
  • 11. Guangdong Provincial Key Laboratory of Urbanization and Geo-simulation, School of Geography and Planning, Sun Yat-sen University, Guangzhou 510275, China
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    DOI: 10.3964/j.issn.1000-0593(2020)11-3499-09 Cite this Article
    Hao-dan ZHANG, Xiao-lin SUN, Xiao-qing WANG, Hui-li WANG. Analyzing Errors due to Measurement Positions and Sampling Locations for In Situ Measurements of Soil Organic Matter Using Vis-NIR Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2020, 40(11): 3499 Copy Citation Text show less
    Distribution of sampling points in the study area
    Fig. 1. Distribution of sampling points in the study area
    Comparison of soil organic matter contents of two duplicate sets of samples
    Fig. 2. Comparison of soil organic matter contents of two duplicate sets of samples
    Soil spectral curves of soil horizons with different organic matter contents(a): Horizon with the lowest soil organic matter content; (b): Horizon with the organic matter content close to average value;(c): Horizon with the highasu soil organic matter content
    Fig. 3. Soil spectral curves of soil horizons with different organic matter contents
    (a): Horizon with the lowest soil organic matter content; (b): Horizon with the organic matter content close to average value;(c): Horizon with the highasu soil organic matter content
    Soil organic matter content and the differences between soil spectra(a): The angle between spectrum of each test point and spectrum of each sample; (b): The angle between spectrum of each sample and spectrum of each horizon
    Fig. 4. Soil organic matter content and the differences between soil spectra
    (a): The angle between spectrum of each test point and spectrum of each sample; (b): The angle between spectrum of each sample and spectrum of each horizon
    Correlogram of soil organic matter content to spectral reflectance of each sample
    Fig. 5. Correlogram of soil organic matter content to spectral reflectance of each sample
    Modeling results of PLSR(a): Validation: RMSEP (Cross-validated using 236 leave-one-out segments); (b): Training: % variance explained
    Fig. 6. Modeling results of PLSR
    (a): Validation: RMSEP (Cross-validated using 236 leave-one-out segments); (b): Training: % variance explained
    Statistics of the independent random validation in PLSR prediction modelThe red dotted line represents the evaluation result of LOOCV
    Fig. 7. Statistics of the independent random validation in PLSR prediction model
    The red dotted line represents the evaluation result of LOOCV
    Estimated soil organic matter content (black) by the spectrum of each test point (a) and sample (b), and their mean value (green), standard deviation (blue) against the measured. In (b), the estimated are compared with the measured soil organic matter contents, while the other values are compared with the average soil organic matter content of two samples in each horizon
    Fig. 8. Estimated soil organic matter content (black) by the spectrum of each test point (a) and sample (b), and their mean value (green), standard deviation (blue) against the measured. In (b), the estimated are compared with the measured soil organic matter contents, while the other values are compared with the average soil organic matter content of two samples in each horizon
    样本数均值最小值最大值中值标准差变异系数CV/%偏度峰度
    所有环刀样23620.251.2048.6419.1212.36610.31-1.15
    重复111820.682.3746.8718.9912.23590.29-1.22
    重复211819.811.2048.6419.1212.51630.34-1.09
    土层11820.251.7945.1020.3212.10600.20-1.36
    Table 1. Statistics of soil organic matter content(g·kg-1)
    θ参考谱线样本数均值最小值最大值中值标准差偏度峰度
    测试点光谱环刀样光谱4 2481.550.128.131.281.001.686.93
    环刀样光谱土层光谱2360.880.183.650.690.601.505.77
    Table 2. Statistics of differences in degree between the sample spectrum and reference spectrum
    样本数均值最小值最大值中值标准差变异系数CV/%偏度峰度
    测试点光谱的
    估测标准偏差
    2363.640.9214.663.112.09571.904.92
    测试点光谱的估测标准
    偏差占实测值百分比
    2360.310.0384.280.180.461495.9446.19
    环刀样光谱的
    估测标准偏差
    1182.270.005711.461.542.10921.543.19
    环刀样光谱的估测标准
    偏差占实测值百分比
    1180.150.000170.920.0930.181152.346.60
    Table 4. Statistics of the error of soil organic matter content estimated by in situ soil spectra (by standard deviation)
    Hao-dan ZHANG, Xiao-lin SUN, Xiao-qing WANG, Hui-li WANG. Analyzing Errors due to Measurement Positions and Sampling Locations for In Situ Measurements of Soil Organic Matter Using Vis-NIR Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2020, 40(11): 3499
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