• Spectroscopy and Spectral Analysis
  • Vol. 41, Issue 1, 292 (2021)
Lu-lu DAI1、1、*, Yan JIANG1、1, and Ming-xing YANG1、1
Author Affiliations
  • 1[in Chinese]
  • 11. Gemmological Institue, China University of Geosciences, Wuhan 430074, China
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    DOI: 10.3964/j.issn.1000-0593(2021)01-0292-07 Cite this Article
    Lu-lu DAI, Yan JIANG, Ming-xing YANG. Study on the Spectral Identification Characteristics of “Heiqing” and “Heibi”[J]. Spectroscopy and Spectral Analysis, 2021, 41(1): 292 Copy Citation Text show less
    Comparison of chemical composition between “Heiqing” and “Heibi” samples
    Fig. 1. Comparison of chemical composition between “Heiqing” and “Heibi” samples
    Histogram of Cr, Co, Ni content of “Heiqing” and “Heibi” samples(μg·g-1)
    Fig. 2. Histogram of Cr, Co, Ni content of “Heiqing” and “Heibi” samples(μg·g-1)
    Raman spectrum of “Heiqing” (a) and “Heibi”samples (b)
    Fig. 3. Raman spectrum of “Heiqing” (a) and “Heibi”samples (b)
    Visible-near infrared absorption spectrum of “Heiqing” (a) and “Heibi” (b) samples
    Fig. 4. Visible-near infrared absorption spectrum of “Heiqing” (a) and “Heibi” (b) samples
    Mid-infrared absorption spectra of “Heiqing” (a) and “Heibi” (b) samples
    Fig. 5. Mid-infrared absorption spectra of “Heiqing” (a) and “Heibi” (b) samples
    Near-infrared absorption spectra of “Heiqing” (a) ane “Heibi” (b) samples
    Fig. 6. Near-infrared absorption spectra of “Heiqing” (a) ane “Heibi” (b) samples
    编号颜色光泽折射率(点测)相对密度产地照片
    HQ-1近黑色油脂光泽1.612.99新疆和田
    HQ-2近黑色油脂光泽1.613.00新疆和田
    XQ近黑色油脂光泽1.613.01青海小灶火
    DQ-1近黑色油脂光泽1.613.01新疆大同
    DQ-2近黑色油脂光泽1.613.01新疆大同
    MB近黑色油脂光泽1.612.97新疆玛纳斯
    Table 1. The information of the samples
    样品HQ-1HQ-2XQDQ-1DQ-2MB
    Al2O30.720.680.470.620.675.47
    SiO257.4557.2557.8857.4957.2653.14
    K2O0.050.060.040.070.060.02
    CaO12.1012.3412.6712.6512.4211.39
    NiO0.010.010.020.0200.06
    Cr2O30000.0100.04
    Na2O0.070.060.050.080.070.34
    MgO23.7523.1023.3222.5322.9215.39
    FeOT2.742.842.212.982.688.12
    MnO0.060.080.040.090.080.09
    TiO20.030.020.020.020.020.14
    P2O50.010.010.01000.02
    Total9796.4696.7396.5596.1894.22
    Mg/(Fe+
    Mg)
    94%94%95%93%94%77%
    Table 2. Chemical composition of “Heiqing” and “Heibi” samples(Wt/%)
    样品CrTiMnCoNiV
    HQ-17.69249.48727.349.3016.237.23
    HQ-22.50264.72723.659.5915.257.35
    XQ1.71200.63557.956.347.923.88
    DQ-10.52221.781 502.8212.914.9314.26
    DQ-20236.271 520.5612.774.6814.60
    MB420.06582.23955.1334.23120.24203.68
    Table 3. Partial transition metal ion content of “Heiqing” and “Heibi” samples (μg·g-1)
    样品M—OH伸缩振动Si—O伸缩振动Si—O—Si
    伸缩振动
    Si—O
    弯曲振动
    晶格振动
    HQ-13 678, 3 665, 3 6481 058, 1 028, 930674528436, 414, 393, 369, 223, 177, 159, 121
    HQ-23 678, 3 664, 3 6481 058, 1 028, 930674528436, 414, 393, 369, 223, 177, 159, 121
    XQ3 678, 3 665, 3 6471 059, 1 029, 930674529436, 414, 393, 369, 223, 177, 159, 121
    DQ-13 678, 3 664, 3 6481 058, 1 028, 930674528436, 414, 393, 369, 223, 177, 159, 121
    DQ-23 678.1, 3 664.6, 3 648.71 058, 1 028, 930674528436, 414, 393, 369, 223, 177, 159, 121
    MB3 677.6, 3 663.7, 3 647.91 051, 1 032, 926669529435, 412, 389, 368, 348, 219, 192, 177, 157, 118
    Table 4. Assignments of Raman peaks of “Heiqing” and “Heibi” samples/cm-1
    样品OH的
    倍频、
    合频
    H2O弯曲振
    动与伸缩振
    动组合频
    Fe—OHMg—OH
    “黑青”1 3791 9152 2102 310, 2 387, 2 466
    “黑碧”1 400--2 313, 2 394
    Table 5. Assignments of near-Infrared absorption bands of “Heiqing” and “Heibi” samples/nm
    样品Si—O伸缩振动Si—O—Si伸缩振动Si—O弯曲振动, M—O伸缩振动及OH平动
    HQ-11 104, 1 061, 1 017, 1 000, 953, 923757, 686, 662, 644510, 468, 419
    HQ-21 105, 1 063, 1 017, 999, 953, 924757, 686, 662, 644509, 470, 420
    XQ1 104, 1 062, 1 017, 1 000, 953, 922756, 686, 662, 644509, 466, 419
    DQ-11 104, 1 061, 1 017, 1 000, 953, 923757, 686, 662, 644510, 468, 419
    MB1 095, 1 044, 1 000, 960, 922757, 687, 632509, 472
    Table 6. Assignments of Infrared absorption bands of “Heiqing” and “Heibi” samples/cm-1
    样品显微紫外-可见光谱/cm-1红外光谱/cm-1
    5 225附近4 800~4 6004 350~4 3005 225附近4 800~4 6004 350~4 300
    “黑青”5 2224 7174 3925 2254 738, 4 6924 349, 4 317
    “黑碧”--4 323-4 7084 307
    Table 7. Comparison of the results of microscopic ultraviolet-visible spectrum and infrared spectrum analysis
    Lu-lu DAI, Yan JIANG, Ming-xing YANG. Study on the Spectral Identification Characteristics of “Heiqing” and “Heibi”[J]. Spectroscopy and Spectral Analysis, 2021, 41(1): 292
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