• Journal of Inorganic Materials
  • Vol. 36, Issue 3, 292 (2021)
Yanyan YANG1、2, Yongguo LI3, Xiaowen ZHU1, Xiao DU2, Xuli MA2, and Xiaogang HAO2、*
Author Affiliations
  • 11. School of Chemistry and Environmental Science, Shangrao Normal University, Shangrao 334001, China
  • 22. Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
  • 33. China Institute for Radiation Protection, Taiyuan 030006, China
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    DOI: 10.15541/jim20200340 Cite this Article
    Yanyan YANG, Yongguo LI, Xiaowen ZHU, Xiao DU, Xuli MA, Xiaogang HAO. Potential Induced Reversible Removal/Recovery of Phosphate Anions with High Selectivity Using an Electroactive NiCo-layered Double Oxide Film[J]. Journal of Inorganic Materials, 2021, 36(3): 292 Copy Citation Text show less
    SEM images of NiCo-LDH (a, c) and NiCo-LDO (b, d), TEM (e) and HRTEM (f) images of NiCo-LDO
    1. SEM images of NiCo-LDH (a, c) and NiCo-LDO (b, d), TEM (e) and HRTEM (f) images of NiCo-LDO
    XRD patterns of NiCo-LDH and NiCo-LDO (a), full XPS (b), high resolution Co2p (c), and Ni2p (d) spectra of NiCo-LDO
    2. XRD patterns of NiCo-LDH and NiCo-LDO (a), full XPS (b), high resolution Co2p (c), and Ni2p (d) spectra of NiCo-LDO
    Kinetic adsorption curves of PO43- on NiCo-LDO under ESIX or IX process (a), high resolution Co2p (b) and Ni2p (c) spectra of NiCo-LDO after oxidation
    3. Kinetic adsorption curves of PO43- on NiCo-LDO under ESIX or IX process (a), high resolution Co2p (b) and Ni2p (c) spectra of NiCo-LDO after oxidation
    Competitive adsorption kinetics curves of PO43-, SO42-, I-, and Cl- onto NiCo-LDO in 21.19 mg/L PO43-, 21.71 mg/L SO42-, 21.64 mg/L I-, and 22.85 mg/L Cl- mixed solution
    4. Competitive adsorption kinetics curves of PO43-, SO42-, I-, and Cl- onto NiCo-LDO in 21.19 mg/L PO43-, 21.71 mg/L SO42-, 21.64 mg/L I-, and 22.85 mg/L Cl- mixed solution
    Recyclability test of NiCo-LDO for the removal of PO43-
    5. Recyclability test of NiCo-LDO for the removal of PO43-
    High resolution P2p (A) and O1s (B) spectra of NiCo-LDO before (curves a) and after (curves b) oxidation
    6. High resolution P2p (A) and O1s (B) spectra of NiCo-LDO before (curves a) and after (curves b) oxidation
    Illustration of the ESIX mechanism of NiCo-LDO for removal/recovery of PO43-
    7. Illustration of the ESIX mechanism of NiCo-LDO for removal/recovery of PO43-
    Anion-LDHEcp/(kJ•mol-1)
    Cl--LDH-455.88
    I--LDH-345.20
    SO42--LDH-813.90
    PO43--LDH-868.36
    Table 1. Calculated binding energy between anion-and NiCo-LDH
    Ion adsorbentAdsorption quantity/(mg•g-1)Time/hRef.
    Aluminum oxide hydroxide36.274[6]
    Fe-Mn binary oxide33.224[29]
    Hydroxy-aluminum12.77[30]
    MgFe-Zr-LDH@magnetic particles3024[31]
    Am-ZrO267.298[32]
    Mg-Fe-Cl LDH9.86[10]
    Nano-La(III) (hydr)oxides~5510[33]
    La(OH)3/Fe3O483.55[5]
    NiCo-LDO159.366This work
    Table 2. Comparison of the ion adsorption quantity with those reported PO43- ion adsorbents
    Yanyan YANG, Yongguo LI, Xiaowen ZHU, Xiao DU, Xuli MA, Xiaogang HAO. Potential Induced Reversible Removal/Recovery of Phosphate Anions with High Selectivity Using an Electroactive NiCo-layered Double Oxide Film[J]. Journal of Inorganic Materials, 2021, 36(3): 292
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