• Laser & Optoelectronics Progress
  • Vol. 56, Issue 18, 183101 (2019)
Jingrong Meng1、**, Guolong Li1、*, Xinlei Suo1, Lilai Zhang1, Hang Su1, Wan Li1, and Hao Wang2
Author Affiliations
  • 1 Key Laboratory of Ningxia for Photovoltaic Materials, Ningxia University, Yinchuan, Ningxia 750021, China
  • 2 Ningxia Juyuan New Material Technology Co., Ltd, Yinchuan, Ningxia 750021, China
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    DOI: 10.3788/LOP56.183101 Cite this Article Set citation alerts
    Jingrong Meng, Guolong Li, Xinlei Suo, Lilai Zhang, Hang Su, Wan Li, Hao Wang. Property Optimization of Perovskite Solar Cells Enhanced by Spiro-OMeTAD Layer Oxidation[J]. Laser & Optoelectronics Progress, 2019, 56(18): 183101 Copy Citation Text show less
    Schematic of structure. (a) Perovskite solar cell; (b) Spiro-OMeTAD molecule[17]
    Fig. 1. Schematic of structure. (a) Perovskite solar cell; (b) Spiro-OMeTAD molecule[17]
    Schematics of optical absorptance. (a) Ultraviolet-visible (UV-Vis) absorption of Spiro-OMeTAD films before and after oxidation; (b) calculation of total layer absorptance
    Fig. 2. Schematics of optical absorptance. (a) Ultraviolet-visible (UV-Vis) absorption of Spiro-OMeTAD films before and after oxidation; (b) calculation of total layer absorptance
    AFM of Spiro-OMeTAD film. (a) Before oxidation; (b) after oxidation
    Fig. 3. AFM of Spiro-OMeTAD film. (a) Before oxidation; (b) after oxidation
    Distribution of energy flow density inside devices. (a) Planar device without pinhole; (b) device with pinhole
    Fig. 4. Distribution of energy flow density inside devices. (a) Planar device without pinhole; (b) device with pinhole
    UPS spectra of Sprio-OMeTAD film before and after oxidation. (a) Spectrum of work function before oxidation; (b) spectrum of valence band after oxidation; (c) spectrum of work function after oxidation; (d) spectrum of valence band after oxidation
    Fig. 5. UPS spectra of Sprio-OMeTAD film before and after oxidation. (a) Spectrum of work function before oxidation; (b) spectrum of valence band after oxidation; (c) spectrum of work function after oxidation; (d) spectrum of valence band after oxidation
    Cross-sectional SEM image of perovskite solar cell
    Fig. 6. Cross-sectional SEM image of perovskite solar cell
    EIS of four devices in dark state at 0.4-V bias voltage
    Fig. 7. EIS of four devices in dark state at 0.4-V bias voltage
    Devices obtained by four oxidation modes. (a) J-V curves; (b) EQE curves
    Fig. 8. Devices obtained by four oxidation modes. (a) J-V curves; (b) EQE curves
    Statistical chart of PCE distributions of devices obtained by four oxidation modes
    Fig. 9. Statistical chart of PCE distributions of devices obtained by four oxidation modes
    DeviceJsc /(mA·cm-2)Voc /VFFPCE /%
    A21.040.990.439.06
    B20.651.050.4710.13
    C20.521.060.5411.78
    D22.151.020.6314.19
    Table 1. Performance parameters corresponding to different devices
    Jingrong Meng, Guolong Li, Xinlei Suo, Lilai Zhang, Hang Su, Wan Li, Hao Wang. Property Optimization of Perovskite Solar Cells Enhanced by Spiro-OMeTAD Layer Oxidation[J]. Laser & Optoelectronics Progress, 2019, 56(18): 183101
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