Femtosecond laser filamentation has attracted significant attention due to its applications in remote sensing of atmospheric pollutants and artificial weather intervention. Nitrogen is the most abundant gas in the atmosphere, and its stimulated ultraviolet emission is remarkably clean, distinctly different from the fluorescence obtained through electron impact or laser breakdown. While numerous experiments and mechanism analyses have been conducted on its characteristic fluorescence excited by laser filamentation, they predominantly focused on short-distance filamentation (less than 1 m). Contrary to previous reports, we find that at long distances (30 m), the fluorescence intensity of neutral nitrogen molecules excited by linearly polarized laser pulses is approximately 7 times that excited by circularly polarized pulses with the same energy. This enhancement is caused by the enhanced tunneling ionization rate, 3.7 times that under circular polarization, and the elongated filament length, 1.85 times that under circular polarization, when using linear polarization. Additionally, after comparing existing theories for ${\mathrm{N}}_2({\mathrm{C}}^3{\mathrm{\Pi }}_{\mathrm{u}})$) excitation, the dissociation-recombination model is found to be more appropriate for explaining the formation of ${\mathrm{N}}_2({\mathrm{C}}^3{\mathrm{\Pi }}_{\mathrm{u}})$) excited states during long-distance filamentation.