Author Affiliations
11. Chemical Engineering and Biotechnology, Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China22. Technical Center for Industrial Product and Raw Material Inspection and Testing, Shanghai Customs, Shanghai 200135, Chinashow less
Fig. 1. Near-infrared spectra of different coals
Fig. 2. (a) The near-infrared spectroscopy of lignite (YNH, FH), bituminous coal (AY, MY) and anthracite (EWY, CWY); (b) The relationship between the absorbance at 10 001 cm-1 and the fixed carbon content
Fig. 3. (a) The XRD spectra of lignite (YNH, FH), bituminous coal (AY, MY) and anthracite (EWY, CWY); (b) Gaussian fitting curve of γ peak and 002 peak of EWY coal sample in 2θ range of 10°~35°
Fig. 4. (a) The relationship between the fa and the H/C; (b) The relationship between the spectral slope and the fa
Fig. 5. (a) Cumulative contribution rate of PCs; Loading plot of (b) PC1 (98.11%), (c) PC2 (1.708%)
Fig. 6. (a) Discriminant function (F1, F2) decentralized point map; (b) Correlation coefficient of each variable in the discriminant function (F1, F2)
煤种 | 国别 | 样品数 | 建模集 | 测试集 | 总计 |
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烟煤 | 俄罗斯 | 72 | 173 | 74 | 247 | 澳大利亚 | 95 | 印度尼西亚 | 29 | 蒙古 | 30 | 加拿大 | 15 | 哈萨克斯坦 | 6 | 褐煤 | 印度尼西亚 | 126 | 94 | 40 | 134 | 菲律宾 | 8 | 无烟煤 | 俄罗斯 | 15 | 21 | 8 | 29 | 越南 | 9 | 朝鲜 | 5 |
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Table 1. Summary of the number of experimental samples
| 近似分析 (db, Wt%) | 最终分析 (daf, Wt%) | H/C |
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水分 | 挥发分 | 固定碳 | C | H |
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YNH | 19.35 | 38.28 | 24.34 | 67.12 | 3.19 | 0.570 | FH | 10.12 | 35.27 | 24.14 | 61.37 | 3.94 | 0.770 | AY | 6.94 | 23.69 | 39.07 | 62.45 | 2.89 | 0.555 | MY | 1.15 | 14.56 | 65.36 | 75.45 | 3.56 | 0.566 | EWY | 6.07 | 2.71 | 84.99 | 76.18 | 3.33 | 0.525 | CWY | 2.77 | 5.38 | 61.60 | 82.45 | 3.19 | 0.464 |
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Table 2. Proximate analyse and ultimate analyses of lignite (YNH, FH), bituminous coal (AY, MY) and anthracite (EWY, CWY)
样品 | γ峰 | 002峰 | fa |
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峰位 | 峰面积 | 半峰 全宽 | 峰位 | 峰面积 | 半峰 全宽 |
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YNH | 18.33 | 5 150.66 | 9.52 | 24.04 | 5 116.69 | 7.58 | 0.498 | FH | 19.16 | 7 480.88 | 8.66 | 24.71 | 2 672.72 | 5.9 | 0.263 | AY | 21.58 | 3 524.84 | 5.92 | 25.73 | 6 763.85 | 4.24 | 0.657 | MY | 20.28 | 1 056.22 | 3.93 | 25.01 | 8 302.36 | 4.68 | 0.887 | EWY | 19.38 | 1 102.79 | 4.73 | 25.56 | 10 095.72 | 4.73 | 0.902 | CWY | 19.57 | 1 923.67 | 5.17 | 25.86 | 18 423.64 | 5.17 | 0.905 |
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Table 3. Structure parameters of XRD
| 建模样品集 | 交叉验证 | 测试样品集 |
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烟煤 | 98.3 | 97.7 | 97.3 | 褐煤 | 95.7 | 95.7 | 100 | 无烟煤 | 100 | 100 | 100 | 总 | 98 | 97.8 | 99.1 |
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Table 4. Discrimination accuracy (%)