• Infrared and Laser Engineering
  • Vol. 51, Issue 12, 20220275 (2022)
Xin Liu, Zhenhui Du, Xiaoyu Wang, Liming Yuan..., Lu Huang and Yongjian Li|Show fewer author(s)
Author Affiliations
  • School of Precision Instrument and Opto-Electronics Engineering, Tianjin University, Tianjin 300072, China
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    DOI: 10.3788/IRLA20220275 Cite this Article
    Xin Liu, Zhenhui Du, Xiaoyu Wang, Liming Yuan, Lu Huang, Yongjian Li. Stand-off detection of ethanol by laser absorption spectrometry with interference-based internal standard[J]. Infrared and Laser Engineering, 2022, 51(12): 20220275 Copy Citation Text show less
    Absorption spectrum of ethanol (Data from PNNL)
    Fig. 1. Absorption spectrum of ethanol (Data from PNNL)
    Interference analysis about the absorption of IAO and the components
    Fig. 2. Interference analysis about the absorption of IAO and the components
    Flow chart of data processing
    Fig. 3. Flow chart of data processing
    Schematic diagram of experimental setup
    Fig. 4. Schematic diagram of experimental setup
    Physical drawings of the experimental setup
    Fig. 5. Physical drawings of the experimental setup
    Signal comparison before and after baseline reconstruction
    Fig. 6. Signal comparison before and after baseline reconstruction
    Signal comparison of reference path and analysis path
    Fig. 7. Signal comparison of reference path and analysis path
    Ethanol absorption spectrum
    Fig. 8. Ethanol absorption spectrum
    Allan variance
    Fig. 9. Allan variance
    No.Theoretical absorbanceMeasured absorbanceAbsolute deviationRelative deviation
    12.483442.4834400
    20.149140.150870.001741.164%
    30.105720.10415−0.00157−1.482%
    40.033090.034900.001815.46%
    Table 1. Absorbance deviation of peaks
    Volume/µL0.501.001.502.002.50
    Theoretical concentration/ppm8.979517.95926.938535.91844.8975
    Measured concentration/ppm12.46219.02225.57534.93945.514
    Absolute error/ppm3.48251.063−1.3635−0.9790.6165
    Relative error38.783%5.919%5.062%2.726%1.373%
    Table 2. Measurement results of ethanol standard gas with different concentrations
    Xin Liu, Zhenhui Du, Xiaoyu Wang, Liming Yuan, Lu Huang, Yongjian Li. Stand-off detection of ethanol by laser absorption spectrometry with interference-based internal standard[J]. Infrared and Laser Engineering, 2022, 51(12): 20220275
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