• Laser & Optoelectronics Progress
  • Vol. 55, Issue 3, 033101 (2018)
Lin Lai, Yanghui Li*, Hui Zhou, Haosheng Xia, Xiaoyu Liu, Chengliang Xia, and Le Wang
Author Affiliations
  • College of Optical and Electronic Technology, China Jiliang University, Hangzhou, Zhejiang 310018, China
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    DOI: 10.3788/LOP55.033101 Cite this Article Set citation alerts
    Lin Lai, Yanghui Li, Hui Zhou, Haosheng Xia, Xiaoyu Liu, Chengliang Xia, Le Wang. Study of Film Uniformity on Large-Curvature Substrate Surface Based on Atomic Layer Deposition[J]. Laser & Optoelectronics Progress, 2018, 55(3): 033101 Copy Citation Text show less
    Internal structural diagram of 100-mm-diameter cylindrical reaction chamber. (a) Pedestal; (b) annular holes; (c) baffle; (d) wall of reaction chamber
    Fig. 1. Internal structural diagram of 100-mm-diameter cylindrical reaction chamber. (a) Pedestal; (b) annular holes; (c) baffle; (d) wall of reaction chamber
    Concentration distributions of TiCl4 gas on hemispheric substrate surface under different moments. (a) 100 ms; (b) 150 ms; (c) 200 ms; (d) 250 ms
    Fig. 2. Concentration distributions of TiCl4 gas on hemispheric substrate surface under different moments. (a) 100 ms; (b) 150 ms; (c) 200 ms; (d) 250 ms
    Concentration distributions of precusors at different moments in propagation process. (a) 50 ms; (b) 100 ms; (c) 150 ms; (d) 200 ms
    Fig. 3. Concentration distributions of precusors at different moments in propagation process. (a) 50 ms; (b) 100 ms; (c) 150 ms; (d) 200 ms
    Fitting curves of film thicknesses on substrate surface at different places. (a) TiO2 films; (b) Al2O3 films
    Fig. 4. Fitting curves of film thicknesses on substrate surface at different places. (a) TiO2 films; (b) Al2O3 films
    Fitting curves of film thicknesses on substrate surface under different heights. (a) TiO2 films; (b) Al2O3 films
    Fig. 5. Fitting curves of film thicknesses on substrate surface under different heights. (a) TiO2 films; (b) Al2O3 films
    Test results of hemispheric refectance spectra
    Fig. 6. Test results of hemispheric refectance spectra
    PrecursorH2OTMATiCl4
    Saturated vaporpressure /kPa2.331.121.33
    Viscosity /(Pa·s)9.55×10-65.00×10-68.42×10-6
    Relative molecular mass18.015372.0858189.729
    Table 1. Saturated vapor pressure, viscosity, and relative molecular mass of precursors
    Wavelength /nm400500600700
    Refraction index of Al2O31.6391.6301.6271.626
    Refraction index of TiO22.602.482.362.32
    Table 2. Refractive indexes of materials after ALD
    FilmPrecursorPulse time /sPurge time /s
    Al2O3TMA0.58
    H2O0.510
    TiO2TiCl40.4312
    H2O0.512
    Table 3. Process parameters for Al2O3 and TiO2 films
    Lin Lai, Yanghui Li, Hui Zhou, Haosheng Xia, Xiaoyu Liu, Chengliang Xia, Le Wang. Study of Film Uniformity on Large-Curvature Substrate Surface Based on Atomic Layer Deposition[J]. Laser & Optoelectronics Progress, 2018, 55(3): 033101
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