• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 4, 1199 (2022)
Yan-ling YANG1、*, Hsitien Shen Andy1、1;, Yu-rong FAN2、2;, Wei-zhi HUANG1、1;, and Jing-cheng PEI1、1; *;
Author Affiliations
  • 11. Gemmological Institute, China University of Geosciences (Wuhan), Wuhan 430074, China
  • 22. College of Life Science and Technology, Huazhong Agricultural University, Wuhan 430072, China
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    DOI: 10.3964/j.issn.1000-0593(2022)04-1199-05 Cite this Article
    Yan-ling YANG, Hsitien Shen Andy, Yu-rong FAN, Wei-zhi HUANG, Jing-cheng PEI. UV-Vis-NIR Spectroscopic Characteristics of Vanadium-Rich Hydrothermal Synthetic Emeralds From Russia[J]. Spectroscopy and Spectral Analysis, 2022, 42(4): 1199 Copy Citation Text show less
    Synthetic emerald samples
    Fig. 1. Synthetic emerald samples
    UV-Vis-NIR absorption spectra of vanadium-rich synthetic emeralds
    Fig. 2. UV-Vis-NIR absorption spectra of vanadium-rich synthetic emeralds
    UV-Vis-NIR absorption spectra of synthetic iron-rich emeralds from Russia
    Fig. 3. UV-Vis-NIR absorption spectra of synthetic iron-rich emeralds from Russia
    样品号TiVCrMnFeCoNiCuMo
    S-EMRYS-019.03 705.96.81.721.40.13.10.10.0
    S-EMRYS-0213.93 707.32.51.73.00.11.31.00.1
    S-EMRYS-0314.62 263.33.90.60.00.11.10.70.1
    S-EMR1-0216.76 956.41.00.42.10.014.598.139.3
    S-EMR1-039.75 724.81.70.247.70.25.9286.843.1
    P-EMR-S046.87 161.25.00.089.10.21.6360.822.1
    P-EMR-S0510.47 256.10.31.485.50.21.7361.3106.3
    P-EMR-S0611.97 142.910.41.0106.40.60.4333.524.62
    S-EMR2-01157.61.05 739.2168.121 069.04.31 023.0125.60.1
    S-EMR2-02166.72.74 965.7240.621 175.44.91 286.8104.40.0
    Table 1. The contents of transition elements of synthetic emerald samples
    样品号LiNaKRbCs碱金属
    S-EMRYS-013.048.529.50.01.082.6
    S-EMEYS-023.048.521.50.00.075.1
    S-EMRYS-031.03.026.00.00.030.7
    S-EMR1-02864.545.036.50.00.01 046.1
    S-EMR1-03123.58.00.00.00.0131.9
    P-EMR-S04224.08.00.00.00.0232.6
    P-EMR-S05289.515.57.50.00.0313.71
    P-EMR-S06100.06.537.50.00.0144.3
    S-EMR2-01194.05.00.50.033.5234.1
    S-EMR2-02197.513.52.00.00.0213.37
    Table 2. The contents of alkali elements of synthetic emerald samples
    富钒型合成祖母绿富铬型合成祖母绿富铬型天然祖母绿富钒型天然祖母绿
    钒谱390, 430, 617, 680 nm[4]--390, 430, 617, 680 nm[5]
    铬谱-636, 683 nm[6,7]427, 608, 636, 683 nm[7, 10]683 nm[5]
    铁谱-373, 445 nm[6,7]373, 445, 810830 nm[7, 10]810830 nm[5]
    铜谱756 nm[1, 4]756 nm[1, 4]--
    水的类型Ⅰ型水
    1 402 nm(7 133 cm-1);
    1 467 nm(6 816 cm-1);
    1 895 (5 277cm-1)[12]
    同左Ⅰ型水
    1 789 nm(5 109 cm-1);
    1 957 nm(5 109 cm-1)[13]
    Ⅱ型水
    1 716 nm(5 827 cm-1),
    以Ⅱ型水为主[13]
    同左
    Table 3. UV-Vis-NIR spectral characteristics of different emeralds
    Yan-ling YANG, Hsitien Shen Andy, Yu-rong FAN, Wei-zhi HUANG, Jing-cheng PEI. UV-Vis-NIR Spectroscopic Characteristics of Vanadium-Rich Hydrothermal Synthetic Emeralds From Russia[J]. Spectroscopy and Spectral Analysis, 2022, 42(4): 1199
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