• Journal of Inorganic Materials
  • Vol. 39, Issue 9, 979 (2024)
Xin YANG1,2,3, Chunqiu HAN2,4, Yuehan CAO2,*, Zhen HE2, and Ying ZHOU1,2,*
Author Affiliations
  • 11. National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, China
  • 22. School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China
  • 33. Tianfu Yongxing Laboratory, Chengdu 610213, China
  • 44. College of Materials and Chemical Engineering, Three Gorges University, Yichang 443002, China
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    DOI: 10.15541/jim20240102 Cite this Article
    Xin YANG, Chunqiu HAN, Yuehan CAO, Zhen HE, Ying ZHOU. Recent Advances in Electrocatalytic Nitrate Reduction to Ammonia Using Metal Oxides[J]. Journal of Inorganic Materials, 2024, 39(9): 979 Copy Citation Text show less
    References

    [1] X FU, J ZHANG, Y KANG. Recent advances and challenges of electrochemical ammonia synthesis. Chem Catalysis, 2590(2022).

    [2] G QING, R GHAZFAR, S T JACKOWSKI et al. Recent advances and challenges of electrocatalytic N2 reduction to ammonia. Chemical Reviews, 5437(2020).

    [3] Q J BRUCH, G P CONNOR, N D MCMILLION et al. Considering electrocatalytic ammonia synthesis via bimetallic dinitrogen cleavage. ACS Catalysis, 10826(2020).

    [4] D R MACFARLANE, P V CHEREPANOV, J CHOI et al. A roadmap to the ammonia economy. Joule, 1186(2020).

    [5] L JIANG, X FU. An ammonia-hydrogen energy roadmap for carbon neutrality: opportunity and challenges in China. Engineering, 1688(2021).

    [6] J ZHENG, L JIANG, Y LYU et al. Green synthesis of nitrogen-to- ammonia fixation: past, present, and future. Energy & Environmental Materials, 452(2022).

    [7] L OUYANG, J LIANG, Y LUO et al. Recent advances in electrocatalytic ammonia synthesis. Chinese Journal of Catalysis, 6(2023).

    [8] W CHEN, Y XU, J LIU et al. Recent developments in Ti-based nanocatalysts for electrochemical nitrate-to-ammonia conversion. Inorganic Chemistry Frontiers, 4901(2023).

    [9] W CHEN, X YANG, Z CHEN et al. Emerging applications, developments, prospects, and challenges of electrochemical nitrate-to-ammonia conversion. Advanced Functional Materials, 2300512(2023).

    [10] X FU, J B PEDERSEN, Y ZHOU et al. Continuous-flow electrosynthesis of ammonia by nitrogen reduction and hydrogen oxidation. Science, 707(2023).

    [11] W SONG, L YUE, X FAN et al. Recent progress and strategies on the design of catalysts for electrochemical ammonia synthesis from nitrate reduction. Inorganic Chemistry Frontiers, 3489(2023).

    [12] H GUO, P YANG, Y YANG et al. Vacancy-mediated control of local electronic structure for high-efficiency electrocatalytic conversion of N2 to NH3. Small, 2309007(2023).

    [13] S REICHLE, M FELDERHOFF, F SCHÜTH. Mechanocatalytic room-temperature synthesis of ammonia from its elements down to atmospheric pressure. Angewandte Chemie International Edition, 26385(2021).

    [14] X ZOU, J XIE, C WANG et al. Electrochemical nitrate reduction to produce ammonia integrated into wastewater treatment: investigations and challenges. Chinese Chemical Letters, 107908(2023).

    [15] G F CHEN, Y YUAN, H JIANG et al. Electrochemical reduction of nitrate to ammonia via direct eight-electron transfer using a copper-molecular solid catalyst. Nature Energy, 605(2020).

    [16] J Z HE, H W HU, L M ZHANG. Current insights into the autotrophic thaumarchaeal ammonia oxidation in acidic soils. Soil Biology and Biochemistry, 146(2012).

    [17] H XU, Y MA, J CHEN et al. Electrocatalytic reduction of nitrate a step towards a sustainable nitrogen cycle. Chemical Society Reviews, 2710(2022).

    [18] W GAO, K XIE, J XIE et al. Alloying of Cu with Ru enabling the relay catalysis for reduction of nitrate to ammonia. Advanced Materials, 2202952(2023).

    [19] Z Y WU, M KARAMAD, X YONG et al. Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst. Nature Communications, 2870(2021).

    [20] W ZHENG, L ZHU, Z YAN et al. Self-activated Ni cathode for electrocatalytic nitrate reduction to ammonia: from fundamentals to scale-up for treatment of industrial wastewater. Environmental Science & Technology, 13231(2021).

    [21] X ZHANG, Y WANG, C LIU et al. Recent advances in non-noble metal electrocatalysts for nitrate reduction. Chemical Engineering Journal, 126269(2021).

    [22] H DU, H LUO, M JIANG et al. A review of activating lattice oxygen of metal oxides for catalytic reactions: reaction mechanisms, modulation strategies of activity and their practical applications. Applied Catalysis A: General, 119348(2023).

    [23] T LING, T ZHANG, B GE et al. Well-dispersed nickel- and zinc-tailored electronic structure of a transition metal oxide for highly active alkaline hydrogen evolution reaction. Advanced Materials, 1807771(2019).

    [24] Y XU, H YANG, X CHANG et al. Introduction to electrocatalytic kinetics. Acta Physico-Chimica Sinica, 2210025(2023).

    [25] M TANG, Q TONG, Y LI et al. Effective and selective electrocatalytic nitrate reduction to ammonia on urchin-like and defect-enriched titanium oxide microparticles. Chinese Chemical Letters, 108410(2023).

    [26] S HAN, H LI, T LI et al. Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism. Nature Catalysis, 402(2023).

    [27] P LIAO, J KANG, R XIANG et al. Electrocatalytic systems for NOx valorization in organonitrogen synthesis. Angewandte Chemie International Edition, e202311752(2024).

    [28] H YIN, Z CHEN, S XIONG et al. Alloying effect-induced electron polarization drives nitrate electroreduction to ammonia. Chem Catalysis, 1088(2021).

    [29] X DU, J HUANG, J ZHANG et al. Modulating electronic structures of inorganic nanomaterials for efficient electrocatalytic water splitting. Angewandte Chemie International Edition, 4484(2019).

    [30] Z ZHANG, C FENG, D WANG et al. Selectively anchoring single atoms on specific sites of supports for improved oxygen evolution. Nature Communications, 2473(2022).

    [31] C FENG, Z ZHANG, D WANG et al. Tuning the electronic and steric interaction at the atomic interface for enhanced oxygen evolution. Journal of the American Chemical Society, 9271(2022).

    [32] Y ZHANG, H ZHENG, K ZHOU et al. Conjugated coordination polymer as a new platform for efficient and selective electroreduction of nitrate into ammonia. Advanced Materials, 2209855(2023).

    [33] J T REN, L CHEN, H Y WANG et al. Water electrolysis for hydrogen production: from hybrid systems to self-powered/catalyzed devices. Energy & Environmental Science, 49(2024).

    [34] N OGAWA, S IKEDA. On the electrochemical reduction of nitrate ion in the presence of various metal ions. Analytical Sciences, 1681(1991).

    [35] S W BOESE, V S ARCHER. Electrochemical reduction of nitrate in the presence of ytterbium(III). Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 273(1982).

    [36] J YU, X YONG, A CAO et al. Bi-layer single atom catalysts boosted nitrate-to-ammonia electroreduction with high activity and selectivity. Acta Physico-Chimica Sinica, 2307015(2024).

    [37] Q JING, Z MEI, X SHENG et al. 3d orbital electron engineering in oxygen electrocatalyst for zinc-air batteries. Chemical Engineering Journal, 142321(2023).

    [38] H CHEN, Q WU, Y WANG et al. d-sp orbital hybridization: a strategy for activity improvement of transition metal catalysts. Chemical Communications, 7730(2022).

    [39] K A MOLTVED, K P KEPP. The chemical bond between transition metals and oxygen: electronegativity, d-orbital effects, and oxophilicity as descriptors of metal-oxygen interactions. Journal of Physical Chemistry C, 18432(2019).

    [40] R JIA, Y WANG, C WANG et al. Boosting selective nitrate electroreduction to ammonium by constructing oxygen vacancies in TiO2. ACS Catalysis, 3533(2020).

    [41] W QIU, M XIE, P WANG et al. Size-defined Ru nanoclusters supported by TiO2 nanotubes enable low-concentration nitrate electroreduction to ammonia with suppressed hydrogen evolution. Small, 2300437(2023).

    [42] Y GUO, R ZHANG, S ZHANG et al. Pd doping-weakened intermediate adsorption to promote electrocatalytic nitrate reduction on TiO2 nanoarrays for ammonia production and energy supply with zinc-nitrate batteries. Energy & Environmental Science, 3938(2021).

    [43] H WU, H GUO, F ZHANG et al. Enhanced localized electron density from PdCu nanoparticle loading on a defective TiO2 support for selective nitrate electroreduction to ammonia. Journal of Materials Chemistry A, 22466(2023).

    [44] D ZHAO, C MA, J LI et al. Direct eight-electron NO3- to NH3 conversion: using a Co-doped TiO2 nanoribbon array as a high- efficiency electrocatalyst. Inorganic Chemistry Frontiers, 6412(2022).

    [45] H DU, H GUO, K WANG et al. Durable electrocatalytic reduction of nitrate to ammonia over defective pseudobrookite Fe2TiO5 nanofibers with abundant oxygen vacancies. Angewandte Chemie International Edition, e202215782(2023).

    [46] S DONG, A NIU, K WANG et al. Modulation of oxygen vacancy and zero-valent zinc in ZnCr2O4 nanofibers by enriching zinc for efficient nitrate reduction. Applied Catalysis B: Environmental, 122772(2023).

    [47] T LI, C TANG, H GUO et al. In situ growth of Fe2O3 nanorod arrays on carbon cloth with rapid charge transfer for efficient nitrate electroreduction to ammonia. ACS Applied Materials & Interfaces, 49765(2022).

    [48] X FAN, L XIE, J LIANG et al. In situ grown Fe3O4 particle on stainless steel: a highly efficient electrocatalyst for nitrate reduction to ammonia. Nano Research, 3050(2022).

    [49] J WANG, Y WANG, C CAI et al. Cu-doped iron oxide for the efficient electrocatalytic nitrate reduction reaction. Nano Letters, 1897(2023).

    [50] Y WANG, C LIU, B ZHANG et al. Self-template synthesis of hierarchically structured Co3O4@NiO bifunctional electrodes for selective nitrate reduction and tetrahydroisoquinolines semi- dehydrogenation. Science China Materials, 2530(2020).

    [51] N ZHOU, Z WANG, N ZHANG et al. Potential-induced synthesis and structural identification of oxide-derived Cu electrocatalysts for selective nitrate reduction to ammonia. ACS Catalysis, 7529(2023).

    [52] L XIAO, W DAI, S MOU et al. Coupling electrocatalytic cathodic nitrate reduction with anodic formaldehyde oxidation at ultra-low potential over Cu2O. Energy & Environmental Science, 2696(2023).

    [53] N C KANI, N H L NGUYEN, K MARKEL et al. Electrochemical reduction of nitrates on CoO nanoclusters-functionalized graphene with highest mass activity and nearly 100% selectivity to ammonia. Advanced Energy Materials, 2204236(2023).

    [54] W CHEN, Z CHEN, Z HUANG et al. Modulating the valence electronic structure of Co3O4 to improve catalytic activity of electrochemical nitrate-to-ammonia conversion. Science China Materials, 3901(2023).

    [55] Z NIU, S FAN, X LI et al. Tailored electronic structure by sulfur filling oxygen vacancies boosts electrocatalytic nitrogen oxyanions reduction to ammonia. Chemical Engineering Journal, 138890(2023).

    [56] Y CUI, A DONG, Y ZHOU et al. Interfacially engineered nanoporous Cu/MnOx hybrids for highly efficient electrochemical ammonia synthesis via nitrate reduction. Small, 2207661(2023).

    [57] Y XU, Y SHENG, M WANG et al. Interface coupling induced built-in electric fields boost electrochemical nitrate reduction to ammonia over CuO@MnO2 core-shell hierarchical nanoarrays. Journal of Materials Chemistry A, 16883(2022).

    [58] Y CAO, R GUO, M MA et al. Effects of electron density variation of active sites in CO2 activation and photoreduction: a review. Acta Physico-Chimica Sinica, 2303029(2024).

    [59] Z ZHANG, L BIAN, H TIAN et al. Tailoring the surface and interface structures of copper-based catalysts for electrochemical reduction of CO2 to ethylene and ethanol. Small, 2107450(2022).

    [60] Y WANG, Y QIN, W LI et al. Controllable NO release for catheter antibacteria from nitrite electroreduction over the Cu-MOF. Transactions of Tianjin University, 275(2023).

    [61] F POLO-GARZON, Z BAO, X ZHANG et al. Surface reconstructions of metal oxides and the consequences on catalytic chemistry. ACS Catalysis, 5692(2019).

    [62] C WANG, Z LIU, C LI et al. Progress on electrocatalytic reduction of nitrate on copper-based catalysts. Chinese Science Bulletin, 4411(2021).

    [63] Y WANG, W ZHOU, R JIA et al. Unveiling the activity origin of a copper-based electrocatalyst for selective nitrate reduction to ammonia. Angewandte Chemie International Edition, 5350(2020).

    [64] S ZHANG, M LI, J LI et al. High-ammonia selective metal- organic framework-derived Co-doped Fe/Fe2O3 catalysts for electrochemical nitrate reduction. Proceedings of the National Academy of Sciences, e2115504119(2022).

    [65] Z WANG, B WEN, Q HAO et al. Localized excitation of Ti3+ ions in the photoabsorption and photocatalytic activity of reduced rutile TiO2. Journal of the American Chemical Society, 9146(2015).

    [66] X JIA, J Y LI, S H DING et al. Synergy effect of Pd nanoparticles and oxygen vacancies for enhancing TiO2 photocatalytic CO2 reduction. Journal of Inorganic Materials, 1301(2023).

    [67] J WAN, W CHEN, C JIA et al. Defect effects on TiO2 nanosheets: stabilizing single atomic site Au and promoting catalytic properties. Advanced Materials, 1705369(2018).

    [68] T FENG, F LI, X HU et al. Selective electroreduction of nitrate to ammonia via NbWO6 perovskite nanosheets with oxygen vacancy. Chinese Chemical Letters, 107862(2023).

    [69] X FAN, D ZHAO, Z DENG et al. Constructing Co@TiO2 nanoarray heterostructure with Schottky contact for selective electrocatalytic nitrate reduction to ammonia. Small, 2208036(2023).

    [70] X E ZHAO, Z LI, S GAO et al. CoS2@TiO2 nanoarray: a heterostructured electrocatalyst for high-efficiency nitrate reduction to ammonia. Chemical Communications, 12995(2022).

    [71] X HE, J LI, R LI et al. Ambient ammonia synthesis via nitrate electroreduction in neutral media on Fe3O4 nanoparticles-decorated TiO2 nanoribbon array. Inorganic Chemistry, 25(2023).

    [72] Q ZHAO, A SONG, S DING et al. Preintercalation strategy in manganese oxides for electrochemical energy storage: review and prospects. Advanced Materials, 2002450(2020).

    [73] P WANG, Z JIN, N CHEN et al. Theoretical investigation of Mo doped α-MnO2 electrocatalytic oxygen evolution reaction. Journal of Inorganic Materials, 541(2022).

    [74] X ZHANG, D WU, X LIU et al. Efficient electrocatalytic chlorine evolution under neutral seawater conditions enabled by highly dispersed Co3O4 catalysts on porous carbon. Applied Catalysis B: Environmental, 122594(2023).

    [75] J WU, X WANG, W ZHENG et al. Identifying and interpreting geometric configuration-dependent activity of spinel catalysts for water reduction. Journal of the American Chemical Society, 19163(2022).

    [76] Z HU, L HAO, F QUAN et al. Recent developments of Co3O4-based materials as catalysts for the oxygen evolution reaction. Catalysis Science & Technology, 436(2022).

    [77] D LU, T LIU, J HAN et al. Yolk-shell composite oxides with binuclear Co(II) sites toward low-overpotential nitrate reduction to ammonia. Chemical Engineering Journal, 146896(2023).

    [78] A PARASHTEKAR, L BOURGEOIS, S S V TATIPARTI. Grain boundary segregation of nickel vacancies and space charge zone formation in NiO through interactions among Ni2+, O2-, and Ni3+. Materials Letters, 134743(2023).

    [79] B LI, Q ZHANG, J XIAO et al. Iron-doping enhanced basic nickel carbonate for moisture resistance and catalytic performance of ozone decomposition. Journal of Inorganic Materials, 45(2022).

    [80] R ZHANG, Y WANG, B OU et al. α-Ni(OH)2 surface hydroxyls synergize Ni3+ sites for catalytic formaldehyde oxidation. Journal of Inorganic Materials, 1216(2023).

    [81] H ZHU, Y TANG, J J WANG et al. Accelerating electrosynthesis of ammonia from nitrates using coupled NiO/Cu nanocomposites. Chemical Communications, 2184(2024).

    [82] Y WANG, H LI, W ZHOU et al. Structurally disordered RuO2 nanosheets with rich oxygen vacancies for enhanced nitrate electroreduction to ammonia. Angewandte Chemie International Edition, e202202604(2022).

    Xin YANG, Chunqiu HAN, Yuehan CAO, Zhen HE, Ying ZHOU. Recent Advances in Electrocatalytic Nitrate Reduction to Ammonia Using Metal Oxides[J]. Journal of Inorganic Materials, 2024, 39(9): 979
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