• Journal of Inorganic Materials
  • Vol. 37, Issue 6, 676 (2022)
Xufeng GUAN, Guifang LI*, and Yunge WEI
Author Affiliations
  • School of Advanced Materials and Nano Technology, Xidian University, Xi'an 710071, China
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    DOI: 10.15541/jim20210426 Cite this Article
    Xufeng GUAN, Guifang LI, Yunge WEI. Microstructure and Thermal Quenching Characteristics of Na1-xMxCaEu(WO4)3 (M=Li, K) Red Phosphor [J]. Journal of Inorganic Materials, 2022, 37(6): 676 Copy Citation Text show less
    XRD patterns of phosphors
    1. XRD patterns of phosphors
    Rietveld refinement XRD patterns of phosphors
    2. Rietveld refinement XRD patterns of phosphors
    Excitation spectra of LiCaEu(WO4)3, NaCaEu(WO4)3 and KCaEu(WO4)3 phosphors monitored at 617 nm
    3. Excitation spectra of LiCaEu(WO4)3, NaCaEu(WO4)3 and KCaEu(WO4)3 phosphors monitored at 617 nm
    Emission spectra of phosphors and intensity contrast diagram of phosphors
    4. Emission spectra of phosphors and intensity contrast diagram of phosphors
    CIE chromaticity diagram of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors
    5. CIE chromaticity diagram of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors
    Decay curves of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors (λex=395 nm, λem=617 nm)
    6. Decay curves of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors (λex=395 nm, λem=617 nm)
    Emission spectra of phosphors at different temperatures (λex=395 nm) (a-c), plot of ln(I0/IT-1) versus 1/(kT) (d) and schematic illustration of a configuration coordinate diagram of the thermal quenching process (e)
    7. Emission spectra of phosphors at different temperatures (λex=395 nm) (a-c), plot of ln(I0/IT-1) versus 1/(kT) (d) and schematic illustration of a configuration coordinate diagram of the thermal quenching process (e)
    MaterialsCrystal systemSpace groupa=b/nm c/nm V/nm3α=β=γRwp/% R/%pχ2
    LiCaEu(WO4)3TetragonalI41/a 0.5230570(26)1.1319686(43)0.309694(8)90°8.617.662.438
    NaCaEu(WO4)3TetragonalI41/a 0.5255477(32)1.1393990(48)0.314702(5)90°7.685.951.468
    KCaEu(WO4)3TetragonalI41/a 0.5273337(35)1.1479226(52)0.319357(6)90°7.946.171.315
    Table 1. Structure parameters of LiCaEu(WO4)3, NaCaEu(WO4)3 and KCaEu(WO4)3
    MaterialCIE chromaticity coordinateColor purity/%
    xy
    NaCaEu(WO4)30.65800.34196.07
    Na0.7K0.3CaEu(WO4)30.6610.33896.83
    LiCaEu(WO4)30.6650.33497.87
    Table 2. CIE chromaticity coordinates and color purities of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors
    Xufeng GUAN, Guifang LI, Yunge WEI. Microstructure and Thermal Quenching Characteristics of Na1-xMxCaEu(WO4)3 (M=Li, K) Red Phosphor [J]. Journal of Inorganic Materials, 2022, 37(6): 676
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